19,054 research outputs found
Synthesis of neutral nickel catalysts for ethylene polymerization – the influence of ligand size on catalyst stability
A facile synthesis of nickel salicylaldimine complexes with labile dissociating ligands is described. In addition to producing highly active ethylene polymerization catalysts, important insights into the effect of ligand size on catalyst stability and information on the mechanism of polymerization are provided
Phase behavior of a confined nano-droplet in the grand-canonical ensemble: the reverse liquid-vapor transition
The equilibrium density distribution and thermodynamic properties of a
Lennard-Jones fluid confined to nano-sized spherical cavities at constant
chemical potential was determined using Monte Carlo simulations. The results
describe both a single cavity with semipermeable walls as well as a collection
of closed cavities formed at constant chemical potential. The results are
compared to calculations using classical Density Functional Theory (DFT). It is
found that the DFT calculations give a quantitatively accurate description of
the pressure and structure of the fluid. Both theory and simulation show the
presence of a ``reverse'' liquid-vapor transition whereby the equilibrium state
is a liquid at large volumes but becomes a vapor at small volumes.Comment: 13 pages, 8 figures, to appear in J. Phys. : Cond. Mat
Quantum turbulence at finite temperature: the two-fluids cascade
To model isotropic homogeneous quantum turbulence in superfluid helium, we
have performed Direct Numerical Simulations (DNS) of two fluids (the normal
fluid and the superfluid) coupled by mutual friction. We have found evidence of
strong locking of superfluid and normal fluid along the turbulent cascade, from
the large scale structures where only one fluid is forced down to the vorticity
structures at small scales. We have determined the residual slip velocity
between the two fluids, and, for each fluid, the relative balance of inertial,
viscous and friction forces along the scales. Our calculations show that the
classical relation between energy injection and dissipation scale is not valid
in quantum turbulence, but we have been able to derive a temperature--dependent
superfluid analogous relation. Finally, we discuss our DNS results in terms of
the current understanding of quantum turbulence, including the value of the
effective kinematic viscosity
Fusion-Fission of 16O+197Au at Sub-Barrier Energies
The recent discovery of heavy-ion fusion hindrance at far sub-barrier
energies has focused much attention on both experimental and theoretical
studies of this phenomenon. Most of the experimental evidence comes from
medium-heavy systems such as Ni+Ni to Zr+Zr, for which the compound system
decays primarily by charged-particle evaporation. In order to study heavier
systems, it is, however, necessary to measure also the fraction of the decay
that goes into fission fragments. In the present work we have, therefore,
measured the fission cross section of 16O+197Au down to unprecedented far
sub-barrier energies using a large position sensitive PPAC placed at backward
angles. The preliminary cross sections will be discussed and compared to
earlier studies at near-barrier energies. No conclusive evidence for
sub-barrier hindrance was found, probably because the measurements were not
extended to sufficiently low energies.Comment: Fusion06 - Intl. Conf. on Reaction Mechanisms and Nuclear Structure
at the Coulomb Barrier, San Servolo, Venezia, Italy, March 19-223, 2006 5
pages, 4 figure
Flow Induced Organization and Memory of a Vortex Lattice
We report on experiments probing the evolution of a vortex state in response
to a driving current in 2H-NbSe crystals. By following the vortex motion
with fast transport measurements we find that the current enables the system to
reorganize and access new configurations. During this process the system
exhibits a long-term memory: if the current is turned off the vortices freeze
in place remembering their prior motion. When the current is restored the
motion resumes where it stopped. The experiments provide evidence for a
dynamically driven structural change of the vortex lattice and a corresponding
dynamic phase diagram that contains a previously unknown regime where the
critical current can be either or by applying an
appropriate driving current.Comment: 5 pages, 4figure
Variation with mass of \boldmath{B(E3; 0_1^+ \to 3_1^-)} transition rates in even-mass xenon nuclei
transition matrix elements have been measured for
even-mass Xe nuclei using sub-barrier Coulomb excitation in inverse
kinematics. The trends in energy and
excitation strengths are well reproduced using phenomenological models based on
a strong coupling picture with a soft quadrupole mode and an increasing
occupation of the intruder orbital.Comment: 5 pages, 4 figures, PRC in pres
Order in driven vortex lattices in superconducting Nb films with nanostructured pinning potentials
Driven vortex lattices have been studied in a material with strong pinning,
such as Nb films. Samples in which natural random pinning coexists with
artificial ordered arrays of defects (submicrometric Ni dots) have been
fabricated with different geometries (square, triangular and rectangular).
Three different dynamic regimes are found: for low vortex velocities, there is
a plastic regime in which random defects frustrate the effect of the ordered
array; then, for vortex velocities in the range 1-100 m/s, there is a sudden
increase in the interaction between the vortex lattice and the ordered dot
array, independent on the geometry. This effect is associated to the onset of
quasi long range order in the vortex lattice leading to an increase in the
overlap between the vortex lattice and the magnetic dots array. Finally, at
larger velocities the ordered array-vortex lattice interaction is suppresed
again, in agreement with the behavior found in numerical simulations.Comment: 8 text pages + 4 figure
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