COLA II - Radio and Spectroscopic Diagnostics of Nuclear Activity in Galaxies

We present optical spectroscopic observations of 93 galaxies taken from the infra-red selected COLA (Compact Objects in Low Power AGN) sample. The sample spans the range of far-IR luminosities from normal galaxies to LIRGs. Of the galaxies observed, 78 (84%) exhibit emission lines. Using a theoretically-based optical emission-line scheme we classify 15% of the emission-line galaxies as Seyferts, 77% as starbursts, and the rest are either borderline AGN/starburst or show ambiguous characteristics. We find little evidence for an increase in the fraction of AGN in the sample as a function of far-IR luminosity but our sample covers only a small range in infrared luminosity and thus a weak trend may be masked. As a whole the Seyfert galaxies exhibit a small, but significant, radio excess on the radio-FIR correlation compared to the galaxies classified as starbursts. Compact (<0.05'') radio cores are detected in 55% of the Seyfert galaxies, and these galaxies exhibit a significantly larger radio excess than the Seyfert galaxies in which cores were not detected. Our results indicate that there may be two distinct populations of Seyferts, ``radio-excess'' Seyferts, which exhibit extended radio structures and compact radio cores, and ``radio-quiet'' Seyferts, in which the majority of the radio emission can be attributed to star-formation in the host galaxy. No significant difference is seen between the IR and optical spectroscopic properties of Seyferts with and without radio cores. (Abridged)Comment: 24 pages, 4 figures, 6 tables. Accepted for publication in ApJ, February 200

Control of surface plasmon resonance in out-diffused silver nanoislands for surface-enhanced Raman scattering

Abstract We present the studies of self-assembled silver nanoislands on the surface of silver ion-exchanged glasses. The nanoislands were formed by out-diffusion of reduced silver atoms from the bulk of the glass to its surface. Control of silver ions distribution in the glass by thermal poling after the ion exchange allowed formation of relatively big, up to 250 nm, isolated silver nanoislands while without the poling an ensemble of silver nanoislands with average size from several to tens of nanometers with random size distribution was formed. The nanoislands were characterized using atomic force microscopy and spectral measurements. We used optical absorption spectroscopy for “random” nanoislands and dark field scattering spectroscopy for isolated ones, corresponding spectra showed peaks in the vicinity of 450 nm and 600 nm, respectively. The “random” nanoislands significantly enhanced Raman scattering from Rhodamine 6G, also the modification of Raman signal from deposited on the surface of the samples bacteriorhodopsin in purple membranes was registered

Impact of a Dyadic Intervention on Family Supporter Involvement in Helping Adults Manage Type 2 Diabetes

Background: Family support for adults’ diabetes care is associated with improved self-management and outcomes, but healthcare providers lack structured ways to engage those supporters. Objective: Assess the impact of a patient-supporter diabetes management intervention on supporters’ engagement in patients’ diabetes care, support techniques, and caregiving experience. Design: Multivariate regression models examined between-group differences in support-related measures observed as part of a larger trial randomizing participants to a dyadic intervention versus usual care. Participants: A total of 239 adults with type 2 diabetes and either A1c \u3e8% or systolic blood pressure \u3e160mmHg enrolled with a family supporter. Intervention: Health coaches provided training on positive support techniques and facilitated self-management information sharing and goal-setting. Main Measures: Patient and supporter reports at baseline and 12 months of supporter roles in diabetes care and caregiving experience. Results: At 12 months, intervention-assigned patients had higher odds of reporting increased supporter involvement in remembering medical appointments (AOR 2.74, 95% CI 1.44, 5.21), performing home testing (AOR 2.40, 95% CI 1.29, 4.46), accessing online portals (AOR 2.34, 95% CI 1.29, 4.30), deciding when to contact healthcare providers (AOR 2.12, 95% CI 1.15, 3.91), and refilling medications (AOR 2.10, 95% CI 1.14, 3.89), but not with attending medical appointments or with healthy eating and exercise. Intervention-assigned patients reported increased supporter use of autonomy supportive communication (+0.27 points on a 7-point scale, p=0.02) and goal-setting techniques (+0.30 points on a 5-point scale, p=0.01). There were no differences at 12 months in change scores measuring supporter distress about patients’ diabetes or caregiving burden. Intervention-assigned supporters had significantly larger increases in satisfaction with health system support for their role (+0.88 points on a 10-point scale, p=0.01). Conclusions: A dyadic patient-supporter intervention led to increased family supporter involvement in diabetes self-management and increased use of positive support techniques, without increasing caregiver stress

Dark-field spectroscopy of plasmon resonance in metal nanoislands: effect of shape and light polarization

Abstract We present the experimental dark-field scattering studies and the simulation of plasmonic properties of isolated silver nanoislands. The nanoislands were fabricated on a soda- lime glass substrate using silver-sodium ion exchange, subsequent thermal poling and annealing of the processed glass substrate in hydrogen. The morphology of the nanoislands was characterized with atomic force microscopy and scanning electron microscopy; the dimensions were 100-180 nm in base and 80-160 nm in height. We measured and modeled dark-field scattering spectra of the silver hemiellipsoidal nanoparticles differing in size and shape. The SPR position varied from 450 nm to 730 nm depending on the particle shape and dimensions. Both experiments and simulation showed a red shift of the SPR for bigger nanoislands of the same shape. Losing the axial symmetry in nanoislands resulted in the resonance splitting, while their elongation led to an increase in the scattering of p-polarized light

Two-Dimensional Electronic Spectroscopy of Chlorophyll a: Solvent Dependent Spectral Evolution

The interaction of the monomeric chlorophyll Q-band electronic transition with solvents of differing physical-chemical properties is investigated through two-dimensional electronic spectroscopy (2DES). Chlorophyll constitutes the key chromophore molecule in light harvesting complexes. It is well-known that the surrounding protein in the light harvesting complex fine-tunes chlorophyll electronic transitions to optimize energy transfer. Therefore, an understanding of the influence of the environment on the monomeric chlorophyll electronic transitions is important. The Q-band 2DES is inhomogeneous at early times, particularly in hydrogen bonding polar solvents, but also in nonpolar solvents like cyclohexane. Interestingly this inhomogeneity persists for long times, even up to the nanosecond time scale in some solvents. The reshaping of the 2DES occurs over multiple time scales and was assigned mainly to spectral diffusion. At early times the reshaping is Gaussian-like, hinting at a strong solvent reorganization effect. The temporal evolution of the 2DES response was analyzed in terms of a Brownian oscillator model. The spectral densities underpinning the Brownian oscillator fitting were recovered for the different solvents. The absorption spectra and Stokes shift were also properly described by this model. The extent and nature of inhomogeneous broadening was a strong function of solvent, being larger in H-bonding and viscous media and smaller in nonpolar solvents. The fastest spectral reshaping components were assigned to solvent dynamics, modified by interactions with the solute

The BeppoSAX X-ray view of reflection-dominated Seyfert Galaxies

We present new results from BeppoSAX observations of reflection-dominated Seyfert galaxies, and namely: 1) the Compton-thick Seyfert 2s NGC1068 and Circinus Galaxy; 2) the Seyfert 1 NGC4051, whose nucleus was observed on May 1998 to have switched off, leaving only a residual reflection component as an echo of its past activity. Our main focus in this paper is on the soft X-ray continuum properties and on the X-ray line spectroscopy.Comment: 6 Latex pages, 5 figures, Accepted for publication in Advances in Space Research, Proceedings of 32nd Sci. Ass. of COSPA

Merging of globular clusters within inner galactic regions. I. Do they survive the tidal interaction?

The main topic of this paper is the investigation of the modes of interaction of globular clusters (GCs) moving in the inner part of a galaxy. This is tackled by means of high-resolution N-body simulations, whose first results are presented in this article. Our simulations dealt with primordial very massive (order of 10^7 solar masses) GCs that were able to decay, because of dynamical friction, into the inner regions of triaxial galaxies on a time much shorter than their internal relaxation time. To check the disruptive role of both tidal forces and GC-GC collisions, we maximised the tidal interaction considering GCs on quasi-radial orbits. The available CPU resources allowed us to follow 8 oscillations of the GCs along their orbits and the main findings are: i) clusters with an initial high enough King concentration parameter (c>=1.2), preserve up to 50% of their initial mass; ii) the inner density distribution of the survived clusters keep a King model profile; iii) GC-GC collisions have a negligible effect with respect to that caused by the passage through the galactic center; iv) the orbital energy dissipation due to the tidal interaction is of the same order of that caused by dynamical friction; v) complex sub-structures like "ripples" and "clumps" formed, as observed around real clusters. These findings support the validity of the hypothesis of merging of GCs in the galactic central region, with modes that deserve further careful investigations.Comment: LaTeX 2e, AASTeX v5.x, 23 pages with 14 figures. Accepted for publication on the Astrophysical Journal. Final version with major change

Full characterization of vibrational coherence in a porphyrin chromophore by two-dimensional electronic spectroscopy

In this work we present experimental and calculated two-dimensional electronic spectra for a 5,15-bisalkynyl porphyrin chromophore. The lowest energy electronic Qy transition couples mainly to a single 380 cm–1 vibrational mode. The two-dimensional electronic spectra reveal diagonal and cross peaks which oscillate as a function of population time. We analyze both the amplitude and phase distribution of this main vibronic transition as a function of excitation and detection frequencies. Even though Feynman diagrams provide a good indication of where the amplitude of the oscillating components are located in the excitation-detection plane, other factors also affect this distribution. Specifically, the oscillation corresponding to each Feynman diagram is expected to have a phase that is a function of excitation and detection frequencies. Therefore, the overall phase of the experimentally observed oscillation will reflect this phase dependence. Another consequence is that the overall oscillation amplitude can show interference patterns resulting from overlapping contributions from neighboring Feynman diagrams. These observations are consistently reproduced through simulations based on third order perturbation theory coupled to a spectral density described by a Brownian oscillator model

Hard X-ray Luminosities of Multinuclei Infrared Luminous Galaxies Showing a Radio/Far-Infrared Excess

We report the results of hard X-ray observations of four multinuclei merging infrared luminous galaxies (IRLGs). We selected these four sources for their excess of radio to far-infrared luminosity ratio compared with starburst galaxies. This excess suggests that activity associated with a supermassive black hole (SMBH) contributes strongly to the IRLGs' bolometric luminosities. Although we expect strong hard X-ray emission from the SMBH-driven activity, the radio-excess multinuclei merging IRLGs show considerably smaller hard X-ray luminosities relative to far-infrared (40$-$500 $\mu$m) and infrared (8$-$1000 $\mu$m) luminosities than active galactic nuclei (AGNs) showing a similar radio-excess. This result may demonstrate that emission in the hard X-ray region from SMBH-driven activity in the multinuclei merging IRLGs is severely suppressed compared to a typical spectral energy distribution of SMBH-driven activity in AGNs. If this is a common property of merging IRLGs, without its correction, hard X-ray observations underestimate the contribution of SMBH-driven activity to the bolometric luminosities of merging IRLGs.Comment: 25 pages of text, 4 figures, aaspp4.sty, Astrophysical Journal, in press (1999, Volume 527

Intake, digestibility, energy and nitrogen utilisation, and enteric methane emission in Holstein and Girolando-F1 cows during the transition period.

This study aimed to evaluate intake, energy and nitrogen balance as well as methane emission in Holstein and ½ Holstein ½ Gyr (Girolando-F1) cows during the transition period. Twenty-four cows (12 Holstein and 12 Girolando-F1) were used to evaluate feed intake, apparent digestibility, heat production and methane emission, carried out in two periods: from 28 to 19 days pre-calving and from 15 to 23 days post-calving. A completely randomised design was used and data were analysed by ANOVA within periods (pre- and post-calving) considering the main effect of genetic groups. Girolando-F1cows presented greater body condition score (BCS) compared with Holstein. During pre-calving, there were no differences between genetic groups, except for highest heat production per kilogram of metabolic body weight for Holstein cows. After calving, Holstein cows had greater intake of DM, nitrogen, NDF per kg of BW and produced more heat per kg of metabolic body weight. Holstein cows yielded more milk and fat-corrected milk (FCM4%) compared with Girolando-F1 cows. Holstein cows presented higher methane emission per unit of BW and of metabolic weight. Emissions of enteric methane per kilogram of milk and per kilogram of FCM4% tended to be lower for Holstein compared with Girolando-F1 cows. Nitrogen and energy retention were similar for both Holstein and Girolando-F1 at pre- and post-calving. Despite differences in BCS, DMI, and milk yield, Girolando-F1 and Holstein cows present overall similar energy efficiency, albeit Holstein cows tended to present less methane emission per kg of eligible product (milk)