5,147 research outputs found
Effect of Particle Shape and Charge on Bulk Rheology of Nanoparticle Suspensions
The rheology of nanoparticle suspensions for nanoparticles of various shapes
with equal mass is studied using molecular dynamics simulations. The
equilibrium structure and the response to imposed shear are analyzed for
suspensions of spheres, rods, plates, and jacks in an explicit solvent for both
charged and uncharged nanoparticles. For the volume fraction studied,
?, the uncharged systems are all in their isotropic phase and
the viscosity is only weakly dependent on shape for spheres, rods, and plate
whereas for the jacks the viscosity is an order of magnitude larger than for
the other three shapes. The introduction of charge increases the viscosity for
all four nanoparticle shapes with the increase being the largest for rods and
plates. The presence of a repulsive charge between the particles decreases the
amount of stress reduction that can be achieved by particle reorientation.Comment: 15 pages, 9 figures, in pres
Why do gallium clusters have a higher melting point than the bulk?
Density functional molecular dynamical simulations have been performed on
Ga and Ga clusters to understand the recently observed
higher-than-bulk melting temperatures in small gallium clusters [Breaux {\em et
al.}, Phys. Rev. Lett. {\bf 91}, 215508 (2003)]. The specific-heat curve,
calculated with the multiple-histogram technique, shows the melting temperature
to be well above the bulk melting point of 303 K, viz. around 650 K and 1400 K
for Ga and Ga, respectively. The higher-than-bulk melting
temperatures are attributed mainly to the covalent bonding in these clusters,
in contrast with the covalent-metallic bonding in the bulk.Comment: 4 pages, including 6 figures. accepted for publication in Phys. Rev.
Let
Derivation of Source-Free Maxwell and Gravitational Radiation Equations by Group Theoretical Methods
We derive source-free Maxwell-like equations in flat spacetime for any
helicity "j" by comparing the transformation properties of the 2(2j+1) states
that carry the manifestly covariant representations of the inhomogeneous
Lorentz group with the transformation properties of the two helicity "j" states
that carry the irreducible representations of this group. The set of
constraints so derived involves a pair of curl equations and a pair of
divergence equations. These reduce to the free-field Maxwell equations for j=1
and the analogous equations coupling the gravito-electric and the
gravito-magnetic fields for j=2.Comment: 15 pages, no figures, to appear in Int. J. Mod. Phys.
The Structure of Barium in the hcp Phase Under High Pressure
Recent experimental results on two hcp phases of barium under high pressure
show interesting variation of the lattice parameters. They are here interpreted
in terms of electronic structure calculation by using the LMTO method and
generalized pseudopotential theory (GPT) with a NFE-TBB approach. In phase II
the dramatic drop in c/a is an instability analogous to that in the group II
metals but with the transfer of s to d electrons playing a crucial role in Ba.
Meanwhile in phase V, the instability decrease a lot due to the core repulsion
at very high pressure. PACS numbers: 62.50+p, 61.66Bi, 71.15.Ap, 71.15Hx,
71.15LaComment: 29 pages, 8 figure
Unilaterally removing implicit subsidies for maritime fuels
Many academics and policymakers agree that implicit tax subsidies for maritime fuels — which are currently granted around the world — are inefficient, but that their abolishment requires a unanimous international agreement. Such an agreement is deemed indispensable because any unilateral action would be impossible due to massive tax competition in this industry, competitiveness effects and the legal limits on regulating an industry operating mostly in international waters, thus outside of any state’s jurisdiction. However, an international agreement to solve these problems has proven impossible to reach, thus resulting in the conservation of the status quo. To break this dead
Inelastic neutron scattering in random binary alloys : an augmented space approach
Combining the augmented space representation for phonons with a generalized
version of Yonezawa-Matsubara diagrammatic technique, we have set up a
formalism to seperate the coherent and incoherent part of the total intensity
of thermal neutron scattering from disordered alloys. This is done exacly
without taking any recourse to mean-field like approximation (as done
previously). The formalism includes disorder in masses, force constants and
scattering lengths. Implementation of the formalism to realistic situations is
performed by an augmented space Block recursion which calculates entire Green
matrix and self energy matrix which in turn is needed to evaluate the coherent
and incoherent intensities. we apply the formalism to NiPd and NiPt alloys.
Numerical results on coherent and incoherent scattering cross sections are
presented along the highest symmetry directions. Finally the incoherent
intensities are compared with the CPA and also with experiments.Comment: 18 pages, 13 figure
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