Precise Re–Os ages of organic-rich mudrocks and the Os isotope composition of Jurassic seawater

Rhenium and osmium isotope and abundance data have been obtained on precisely-located samples from three suites of immature, organic-rich mudrocks from Jurassic coastal outcrops in England, The data provide accurate whole-rode ages of 207 +/- 12 Ma, 181 +/- 13 Ma and 155 +/- 4.3 Ma for suites of Hettangian, Toarcian (exaratum Subzone) and Kimmeridgian (sensu anglico, wheatleyensis Subzone) samples. These new Re-Os ages are indistinguishable, within the assigned analytical uncertainties, from interpolated depositional ages estimated from published geological timescales, and establish the importance of the Re-Os dating technique for chronostratigraphic studies. Early-diagenetic pyrite nodules possess levels of Re and Os which are similar to 1-2 orders of magnitude lower than in the enclosing organic-rich mudrocks, indicating that these elements had already been removed from sediment pore waters at the time of nodule formation. Thus the Re-Os isotope system in these organic-rich mudrocks has been closed since, or from very soon after, the time of sediment deposition. Because most of the Re (98+%) and Os (95-99.8+%) in the mudrocks is shown to be hydrogenous, the Os-187/Os-188((i)) of the samples is interpreted to be that of contemporaneous seawater. The data thereby provide the first estimates of the Os isotope composition of Jurassic seawater. During the earliest Jurassic (Hettangian), the seawater Os-187/Os-188 ratio was extremely unradiogenic (similar to 0.15); it had increased to similar to 0.8 at the end of the Early Jurassic (Toarcian) similar to 20 Ma later, while in the Late Jurassic (Kimmeridgian) the seawater Os-187/Os-188 ratio was similar to 0.59. The most likely explanation for the unradiogenic Os isotope composition of Hettangian seawater is that the contribution of unradiogenic Os to the oceans from the hydrothermal alteration of oceanic crust greatly exceeded the input of radiogenic Os from the continents at that time. This interpretation is in Line with observations suggesting that global weathering rates were low in the Hettangian, and that increased hydrothermal and volcanic activity preceded the break-up of Pangea. The Re/Os ratios of Hettangian mudrocks (and by inference, of contemporaneous seawater) are similar to those of mudrocks deposited at later times during the Jurassic, and argues against the unradiogenic Os in Hettangian seawater being derived from extraterrestrial meteoritic sources

Stalagmite luminescence and peat humification records of palaeomoisture for the last 2500 years

Recent research has suggested that both raised and blanket bogs can provide proxy climate signals from variations in peat humification. In particular, oceanic margin sites have provided sensitive records that demonstrate century scale variations in humification. However, previous research has not compared records of peat humification with other terrestrial palaeoclimate proxies. Here, two records of climate change from an oceanic marginal site in NW Scotland are analysed. One, from a blanket bog, is derived from peat humification and covers the period 2100–100 BP. A second, from two stalagmites in a cave overlain by the bog, is derived from stalagmite luminescence wavelength variations for the samples deposited over 2500–0 BP. Both peat humification and stalagmite luminescence records demonstrate 90–100 year oscillations in bog wetness, that are attributed to variations in rainfall intensity or totals over this time period. It is argued that this is probably generated by a southward shift of the path of northern hemisphere depression tracks, possibly linked to variations in solar output

A Non-local Source of Irish Chalcolithic and Early Bronze Age Gold

Lead isotope analyses of 50 Irish Chalcolithic and Early Bronze Age gold artefacts favour a gold source in southern Ireland. However when combined with major element analysis, the artefacts are not consistent with any Irish gold deposit analysed to date. Understanding the lead isotope signatures of ore deposits within a study region allows informed inferences to be drawn regarding the likelihood that an unanalysed ore deposit was exploited in the past. If an Irish gold source is assumed, then the gold is most likely to have originated from deposits hosted by Old Red Sandstone in the Variscan ore field of south-west Ireland. However, based on our current understanding of mineralisation in the region, this scenario is considered unlikely. A non-Irish source for the gold is therefore preferred – a scenario that may favour cosmologically-driven acquisition, ie, the deliberate procurement of a material from distant or esoteric sources. Available geochemical data, combined with current archaeological evidence, favour the alluvial deposits of south-west Britain as the most likely source of the gold.</jats:p

Late Quaternary speleothem pollen in the British isles

As with many terrestrial areas, the British Quaternary sequence is characterised by incomplete, fragmentary records, whose correlation is based on stratigraphic or biostratigraphic techniques due to the lack of radiometric ages beyond the similar to 40 kyr limit of C-14 dating. Speleothems (secondary cave calcite deposits) offer a significant advantage over many sources of palaeoenvironmental information; they can be dated to a high precision and accuracy by uranium-thorium (U-238-Th-230) thermal ionisation and inductively coupled plasma (ICP) mass spectrometry in the time period back to 500 kyr. They may also contain sufficient well-preserved pollen representative of contemporary vegetation above the cave to allow palaeoenvironmental reconstruction. This study adopts the novel approach of combining pollen and thermal ionisation mass spectrometric (TIMS) U-Th dating of British speleothems to produce well-constrained palaeoenvironmental records. We report for the first time precisely dated records of pollen assemblages from speleothems suggesting the presence of thermophilous arboreal species in phases previously considered to have been consistently cool or cold and devoid of trees. Copyright (C) 2007 John Wiley &amp; Sons, Ltd.</p