Nonequilibrium wet–dry cycling acts as a catalyst for chemical reactions

Recent experimental studies suggest that wet–dry cycles and coexisting phases can each strongly alter chemical processes. The mechanisms of why and to what degree chemical processes are altered when subjected to evaporation and condensation are unclear. To close this gap, we developed a theoretical framework for nondilute chemical reactions subject to nonequilibrium conditions of evaporation and condensation. We find that such conditions can change the half-time of the product’s yield by more than an order of magnitude, depending on the substrate–solvent interaction. We show that the cycle frequency strongly affects the chemical turnover when the system is maintained out of equilibrium by wet–dry cycles. There exists a resonance behavior in the cycle frequency where the turnover is maximal. This resonance behavior enables wet–dry cycles to select specific chemical reactions, suggesting a potential mechanism for chemical evolution in prebiotic soups at early Earth

Detail design of the MPU Heavy Lifter

This paper gives insight into detail design of the MPU Heavy Lifter. The innovative structure is developed for offshore heavy lifting operations like removing or installing platforms. Its hull is composed of highly reinforced and prestressed lightweight concrete forming slabs and walls with thicknesses between 0.3m and 0.9 m. Information is provided on the design procedure, on the basis of design and on the design of B- and D-regions. Structural analysis is based on finite element analysis using shell elements. For design and verification of concrete sections the results are post-processed with specially developed software. For D-regions, truss and stress-field modelling supported by specialised finite element analysis is applied. The applicability of these design methods is verified with a series of small and large scale tests

Electrical Resistivity Anisotropy from Self-Organized One-Dimensionality in High-Temperature Superconductors

We investigate the manifestation of the stripes in the in-plane resistivity anisotropy in untwinned single crystals of La_{2-x}Sr_{x}CuO_{4} (x = 0.02 - 0.04) and YBa_{2}Cu_{3}O_{y} (y = 6.35 - 7.0). It is found that both systems show strongly temperature-dependent in-plane anisotropy in the lightly hole-doped region and that the anisotropy in YBa_{2}Cu_{3}O_{y} grows with decreasing y below about 6.60 despite the decreasing orthorhombicity, which gives most direct evidence that electrons self-organize into a macroscopically anisotropic state. The transport is found to be easier along the direction of the spin stripes already reported, demonstrating that the stripes are intrinsically conducting in cuprates.Comment: 5 pages, 4 figures (including one color figure), final version accepted for publication in Phys. Rev. Let

Geologic Map of the Greater Portland Metropolitan Area and Surrounding Region, Oregon and Washington

This geologic map encompasses the greater Portland metropolitan area (the metro area), an urbanized region astride the confluence of the Willamette and Columbia Rivers in Oregon and Washington. The metro area includes the Portland-VancouverHillsboro metropolitan area, defined by the U.S. Census as the 23rd largest such area in the U.S., having a population of more than 2.2 million people (https://www.census.gov/dataviz/visualizations/026/508.php). The map area extends beyond the urbanized core to include outlying towns and cities and the bounding fault zones that separate the metro area from the adjacent Coast Range and Cascade Range (or Cascades; figs. 1, 2, and 3). The metro area is an area of great scenic, natural, and cultural resources and is the major economic hub of Oregon, containing nearly half of the state’s population and generating 75 percent of its gross domestic product (http://oregoneconomicanalysis.com)

On the stability of 2 \sqrt{2} x 2 \sqrt{2} oxygen ordered superstructures in YBa2Cu3O6+x

We have compared the ground-state energy of several observed or proposed " 2 \sqrt{2} x 2 \sqrt{2} oxygen (O) ordered superstructures " (from now on HS), with those of "chain superstructures" (CS) (in which the O atoms of the basal plane are ordered in chains), for different compositions x in YBa2Cu3O6+x. The model Hamiltonian contains i) the Madelung energy, ii) a term linear in the difference between Cu and O hole occupancies which controls charge transfer, and iii) covalency effects based on known results for $t-J$ models in one and two dimensions. The optimum distribution of charge is determined minimizing the total energy, and depends on two parameters which are determined from known results for x=1 and x=0.5. We obtain that on the O lean side, only CS are stable, while for x=7/8, a HS with regularly spaced O vacancies added to the x=1 structure is more stable than the corresponding CS for the same x. We find that the detailed positions of the atoms in the structure, and long-range Coulomb interactions, are crucial for the electronic structure, the mechanism of charge transfer, the stability of the different phases, and the possibility of phase separation.Comment: 24 text pages, Latex, one fig. included as ps file, to be publisheb in Phys. Rev.

Confined Harmonically Interacting Spin-Polarized Fermions in a Magnetic Field: Thermodynamics

We investigate the combined influence of a magnetic field and a harmonic interparticle interaction on the thermodynamic properties of a finite number of spin polarized fermions in a confiment potential. This study is an extension using our path integral approach of symmetrized density matrices for identical particles. The thermodynamical properties are calculated for a three dimensional model of N harmonically interacting spin polarized fermions in a parabolic potential well in the presence of a magnetic field. The free energy and the internal energy are obtained for a limited number of particles. Deviations from the thermodynamical limit become negligible for about 100 or more particles, but even for a smaller number of fermions present in the well, scaling relations similar to those of the continuum approximation to the density of states are already satisfied.Comment: 7 pages REVTEX and 8 postscript figures, accepted in Phys. Rev.

Correlations in a Confined gas of Harmonically Interacting Spin-Polarized Fermions

For a fermion gas with equally spaced energy levels, the density and the pair correlation function are obtained. The derivation is based on the path integral approach for identical particles and the inversion of the generating functions for both static responses. The density and the pair correlation function are evaluated explicitly in the ground state of a confined fermion system with a number of particles ranging from 1 to 220 and filling the Fermi level completely.Comment: 11 REVTEX pages, 3 postscript figures. Accepted for publication in Phys. Rev. E, Vol. 58 (August 1, 1998

Bose-Einstein condensation in arbitrarily shaped cavities

We discuss the phenomenon of Bose-Einstein condensation of an ideal non-relativistic Bose gas in an arbitrarily shaped cavity. The influence of the finite extension of the cavity on all thermodynamical quantities, especially on the critical temperature of the system, is considered. We use two main methods which are shown to be equivalent. The first deals with the partition function as a sum over energy levels and uses a Mellin-Barnes integral representation to extract an asymptotic formula. The second method converts the sum over the energy levels to an integral with a suitable density of states factor obtained from spectral analysis. The application to some simple cavities is discussed.Comment: 10 pages, LaTeX, to appear in Physical Review