Scanning Electron Microscopic Examination of Archaeological Wood Microstructure Altered by Consolidation Treatments

The scanning electron microscope was used in a study of consolidative treatments for archaeological wooden objects. The surfaces of specimens taken from ancient Egyptian wood artifacts (Dynasty XII, ca. 1991-1786 B.C.) were examined for evidence of microstructural deterioration prior to consolidation with paraffin wax, a typical field treatment. The microstructural appearance of wood subjected to treatments used in conservation was investigated. The distribution of a wax and an acrylic resin used in consolidation was studied, as well as the success of consolidant removal by solvent extraction, and the effects of further treatment with an acrylic resin. SEM examination revealed significant mechanical, microbiological, and structural damage prior to consolidation. After wax consolidation, microstructure was obscured and surface appearance was significantly altered. Solvent extraction of wax was found to be incomplete. Acrylic resin treatment allowed handling of samples without apparent damage, while maintaining the visibility of wood structure and satisfactory surface appearance. Damage to wood microstructure was observed when solvent alone was used

Carbonyl compounds indoors in a changing climate

<p>Abstract</p> <p>Background</p> <p>Formic acid, acetic acid and formaldehyde are important compounds in the indoor environment because of the potential for these acids to degrade calcareous materials (shells, eggs, tiles and geological specimens), paper and corrode or tarnish metals, especially copper and lead. Carbonyl sulfide tarnishes both silver and copper encouraging the formation of surface sulfides.</p> <p>Results</p> <p>Carbonyls are evolved more quickly at higher temperatures likely in the Cartoon Gallery at Knole, an important historic house near Sevenoaks in Kent, England where the study is focused. There is a potential for higher concentrations to accumulate. However, it may well be that in warmer climates they will be depleted more rapidly if ventilation increases.</p> <p>Conclusions</p> <p>Carbonyls are likely to have a greater impact in the future.</p

ALMA uncovers highly filamentary structure towards the Sgr E region

We report on the discovery of linear filaments observed in CO(1-0) emission for a $\sim2'$ field of view toward the Sgr E star forming region centered at (l,b)=(358.720$^\circ$, 0.011$^\circ$). The Sgr E region is thought to be at the turbulent intersection of the ''far dust lane'' associated with the Galactic bar and the Central Molecular Zone (CMZ). This region is subject to strong accelerations which are generally thought to inhibit star formation, yet Sgr E contains a large number of HII regions. We present $^{12}$CO(1-0), $^{13}$CO(1-0), and C$^{18}$O(1-0) spectral line observations from ALMA and provide measurements of the physical and kinematic properties for two of the brightest filaments. These filaments have widths (FWHM) of $\sim0.1$ pc and are oriented nearly parallel to the Galactic plane, with angles from the Galactic plane of $\sim2^\circ$. The filaments are elongated, with lower limit aspect ratios of $\sim$5:1. For both filaments we detect two distinct velocity components that are separated by about 15 km s$^{-1}$. In the C$^{18}$O spectral line data with $\sim$0.09 pc spatial resolution, we find that these velocity components have relatively narrow ($\sim$1-2 km s$^{-1}$) FWHM linewidths when compared to other sources towards the Galactic center. The properties of these filaments suggest that the gas in the Sgr E complex is being ''stretched'' as it is rapidly accelerated by the gravitational field of the Galactic bar while falling towards the CMZ, a result that could provide insight into the extreme environment surrounding this region and the large-scale processes which fuel this environment.Comment: 20 pages, 17 figures, accepted for publication in Ap

Effects of NO2 and acetic acid on the stability of historic paper

This research investigates degradation of historic paper in polluted environments during long-term dark storage. In an innovative experiment, degradation rates at realistic pollution levels are compared with degradation rates in the absence of pollution, using a set of real historic papers. The most abundant pollutants in repositories in post-industrial environments are taken into account: acetic acid and nitrogen dioxide. Their action was assessed in terms of reduction of ‘handling’ (as defined by decrease in degree of polymerisation) and ‘display’ (as defined by discolouration) lifetimes. Extrapolations to room conditions enabled lifetime predictions in conditions that are comparable to a real archival or library repository environments while prediction uncertainties were analytically evaluated to assess the significance of conclusions. While 10 ppb of NO2 does reduce the handling lifetime of almost all types of paper, their predicted lifetimes were still assessed to be several millennia, with the exception of acidic paper. Acetic acid at concentrations that are typical for archival and library repositories (<100 ppb) has significantly less effect than NO2 while it does not affect display lifetimes. From a conservation management perspective, it needs to be addressed whether the predicted reductions in otherwise significant handling lifetimes are of real concern and whether air filtration in archival and library repositories is justified

Application of surface science techniques to study a gilded Egyptian funerary mask: A multi-analytical approach

A wide range of analytical techniques has been used to study an Egyptian funerary mask of the Ptolemaic period (305-30 bc). Secondary electron (SE) and back-scattering (BS) images, recorded by a scanning electron microscope (SEM), provided a detailed representation of the metallurgical techniques used to construct the gilded mask. It is confirmed, that the golden leaf used to cover the mask is the product of an antique refinery practice, so called, cementation process of naturally occurring alloy of gold and silver, namely electrum. Complementary results of SEM-electron dispersion spectroscopy (EDS) and electron probe microanalysis (EPMA)–wavelength dispersion spectroscopy (WDS) provided chemical compositions of the golden leaf as well as in the plaster base of the mask. X-ray photoemission spectroscopy (XPS) revealed the presence of Au, Ag, Si, S, Cl, Ca, and N, in addition to O and C. Relative concentration of Au/Ag at the surface has been measured by XPS to be 70% to 30%. XPS depth profiling verified silver-enrichment at the surface, as ratio of gold to silver is measured to be 80% to 20% at the depth of 15 nm. XPS chemical mapping images of gold and silver confirmed a rather inhomogeneous character of Au/Ag relative concentration at the surface. The main diffraction peaks in the X-ray diffraction (XRD) spectrum coincide with diffraction peaks of pure gold, silver metals, and magnesium calcite Mg0.03Ca0.97CO3. Whereas, Raman spectroscopy results implied the existence of Ag2S, a tarnishing compound, on the golden area of the mask.Fil: Gard, Faramarz Sahra. Comisión Nacional de Energía Atómica. Gerencia del Área de Investigaciones y Aplicaciones no Nucleares. Gerencia de Física (Centro Atómico Constituyentes); ArgentinaFil: Daizo, María Belén. Universidad de Buenos Aires. Facultad de Filosofía y Letras; Argentina. Universidad Pedagógica Nacional. Departamento de Humanidades y Artes; ArgentinaFil: Santos, Diego Maximiliano. Universidad Pedagogica Nacional. Departamento de Humanidades y Artes.; ArgentinaFil: Halac, Emilia Betty. Comisión Nacional de Energía Atómica. Gerencia del Área de Investigaciones y Aplicaciones no Nucleares. Gerencia de Física (Centro Atómico Constituyentes); Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; ArgentinaFil: Freire Espeleta, Eleonora. Comisión Nacional de Energía Atómica. Gerencia del Área de Investigaciones y Aplicaciones no Nucleares. Gerencia de Física (Centro Atómico Constituyentes); Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Reinoso, Maria Elba. Comisión Nacional de Energía Atómica. Gerencia del Área de Investigaciones y Aplicaciones no Nucleares. Gerencia de Física (Centro Atómico Constituyentes); Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Bozzano, Patricia Beatriz. Comisión Nacional de Energía Atómica. Gerencia del Área de Investigaciones y Aplicaciones no Nucleares. Gerencia de Física (Centro Atómico Constituyentes); Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; ArgentinaFil: Dominguez, Silvia Adriana. Comisión Nacional de Energía Atómica. Gerencia del Área de Investigaciones y Aplicaciones no Nucleares. Gerencia de Física (Centro Atómico Constituyentes); Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; ArgentinaFil: Montero, Ricardo Jesús. Comisión Nacional de Energía Atómica. Gerencia del Área de Investigaciones y Aplicaciones no Nucleares. Gerencia de Física (Centro Atómico Constituyentes); Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentin