Experimental characterization of defect-induced Raman spectroscopy in graphene with BN, ZnO, Al2O3, and TiO2 dopants

The introduction of boron nitride (BN), zinc oxide (ZnO), aluminum oxide (Al2O3), and titanium oxide (TiO2) as dopants in pristine graphene leads to the modification of its transport properties, resulting in the production of graphene semiconductors and alteration of its semiconductive characteristics. The achievement of high-quality electronic devices necessitates considering doping and producing a broader energy bandgap in graphene. The optical determination of charge density in intrinsic graphene may be achieved by utilizing the D Raman peak, where an increased charge density is associated with a decreasing peak split. Strong connections have been seen between the energy bandgap (Eg) and the locations of the G and D peaks. Various doping materials exhibit distinct variations and effects on the doping process of graphene. The determination of doping levels in graphene may be achieved with far greater accuracy by observing the ID/IG ratios, compared to the traditional method of measuring the G-band shift with charge. The determination of average crystallite size, as well as the observation of the parameter La, is crucial in comprehending the doping and flaws present in graphene materials that have been manufactured

Novel energy bandgap formation of organic solution doped graphene membrane for semiconductor applications

In this work, the electrolyte nano fibrous solution is prepared using corn husk through a chemical process. This study explores the new aspect of producing sizeable and tunable bandgap in graphene by doping organic nanoporous solution as a membrane. The energy bandgap of organic doped graphene membrane varies from 2.313 eV to 2.502 eV.  It is noted that the organic nanoporous solution as a membrane also has a bandgap under with (2.665 eV) and without PVA (3.761 eV).  The membrane is produced by the phase inversion process. The incorporation of graphene in green solution also exhibits conductive properties like organic nanoporous solution which in terns used as electrolytes to produce electricity. It is the first successful attempt to create a direct graphene bandgap with organic doping but it still requires more research for a better understanding of the properties for future applications. This concept can also be used where bandgap is a very concerning issue. The physical properties of with and without a graphene-based organic membrane are examined by Scanning Electron Microscope Test (SEM), Fourier Transform Infrared Spectroscopy Test (FTIR), and Ultra Violate Test (UV). Sample 4 has a superior surface morphology, which means the particle dispersion is more homogeneous than the others. There are porosities in all the samples

Enhancement of microbial fuel cell performance using pure magnesium anode

MFCs (Microbial Fuel Cell) are bio-electrochemical devices that use microorganisms as biocatalysts to transform the chemical energy found in organic or inorganic compounds into electric currents. However, one of the limitations of this technology in terms of practical application is its lower electric efficiency, which greatly depends on the selection of anode material and the types of waste water used. In this work, organically rich wastewater and pure magnesium anode materials were utilized. Also, to investigate the effect of electrode size on power generation, five different sizes of coin-shaped anodes were employed for the variation in anode size, whose diameter and thickness were (15 mm × 2 mm), (20 mm × 2 mm), (20 mm × 3 mm), (20 mm × 4 mm), and (25 mm × 2 mm) with corresponding surface areas [2πr(r+h)] are 448 mm 2, 754 mm 2, 817 mm 2, 880 mm 2 and 1139 mm 2, respectively. The maximum obtained current density, power density, and energy densities were 4734.26 mA/m2, 37400.625 mW/m2 and 81.59 kW-h/kg respectively, by the smallest anode of size (15 mm × 2 mm). This investigation showed that a reduction in the size of the anode decreases the loss in the activation zone. As a result, from the smallest anode, maximum power and energy output were obtained. Finally, this analysis outlines the process and approaches for MFC to produce more power at a potentially lower cost. It is noted that same waste water has been used throughout the study where surface area of the samples vary from lowest to highest level

Synthesis and characterization of novel banana-graphene nanofibrous membrane from viscous liquid for bandgap formation

Organic semiconductors with wide bandgaps have potential applications in organic light-emitting diode displays, organic photovoltaic devices, organic field-effect transistors and solar cells. However, organic semiconductors are not good conductors of electricity. This study synthesizes the banana-graphene nanofibrous membrane using an electric spin process to form a tunable bandgap to enhance conductivity. The chemical process was followed to prepare liquid viscous from banana stalks. Different percentages of graphene (1.2 wt.%, 2.4 wt.% and 3.6 wt.%) were used with the liquid viscous to form sizeable and tunable bandgaps in the composites and enhance the conductivity of the materials. The results showed 5.67 %, 24.5 %, and 27.8 % lower bandgap for 1.2 wt.%, 2.4 %, and 3.6 wt.% graphene-contained samples, respectively, as compared to the polyvinyl alcohol (PVA) viscous fibre (3.35 eV). With the addition of graphene with PVA viscous fibre, the properties of electrospun nanofibrous graphene were changed from insulator to semiconductor. The band gap property was controlled by incorporating graphene with various percentages. The morphology of the surfaces showed that nanofibers are bonded with each other, and graphene nanoparticles are uniformly distributed. The results of this work can be considered to further progress in manufacturing nanocomposites for organic semiconductor applications