Numerical analysis of the cyclic mechanical damage of Li-ion battery electrode and experimental validation

Evidences have accumulated that the cyclic diffusion-induced stress within lithiation-delithiation process will result in the cyclically evolutive mechanical damage of battery electrode, which adversely affects the mechanical integrity as well as the performance of the Li-ion battery. In this work, the mechanical degradation of electrode under electrochemical-mechanical condition is innovatively evaluated as a fatigue damage process, governed by the interaction between diffusion behaviour and stress generation, and accumulated fatigue damage affected stress–strain response. Structural configuration of a layered electrode plate is modeled in finite element software ABAQUS and a set of user subroutines are developed to implement the proposed fatigue evaluation approach for battery electrode. The constructed approach is proved to be able to simulate multifarious categories of fatigue damage accumulation trends of battery electrode. The strategy to correlate the electrochemistry represented damage with mechanical fatigue damage are proposed. Experimental performance tests are conducted to parameterize the fatigue damage model within the assessment approach for electrode material LiNi0.5Mn0.3Co0.2O2 (NMC532). After parameterization, further circulating charging-discharging experiments and fatigue damage simulations with respect to different C-rate conditions are carried out to study the applicability of the proposed evaluation model as well as the assumption between electrochemical and mechanical deterioration. It is observed that the electrode surface adhering to electrolyte is more prone to fracture in the cycling operation. The present research work shows that it is available to apply the fatigue damage method to study the gradually mechanical failure of battery electrode under electrochemical-mechanical condition

An Elastic-Viscoplastic Model for Time-Dependent Behavior of Soft Clay and Its Application on Rheological Consolidation

To describe the time-dependent behavior of soft clay, this paper extended one-dimensional Nishihara model to three-dimensional stress state based on the framework of Perzyna’s overstress theory and modified cam-clay model. The yield criterion of modified cam-clay model was used to describe the plastic properties of soft clay, and the overstress theory was used to describe the strain rate effect. Triaxial rheological tests were carried out on Ningbo soft clay and the rheological characteristics were studied. Based on laboratory results, the parameters of proposed model were determined by curve fitting, which show that this model is suitable for the rheological characteristics of Ningbo soft clay. The analysis of parameters shows that, the value of parameters changes slightly with different deviatoric stress when the confining pressure was constant, but changes notably with the increase of confining pressure. A user material subroutine of the proposed constitutive mode was coded on the platform of the FEM software ABAQUS and verified by triaxial compression of soil column. A plain strain problem was computed to analyze the rheological consolidation properties of soft clay, in which the rheological effect and the finite strain effect were considered

Effect of Ni/Si Mass Ratio and Thermomechanical Treatment on the Microstructure and Properties of Cu-Ni-Si Alloys

The effect of the Ni/Si mass ratio and combined thermomechanical treatment on the microstructure and properties of ternary Cu-Ni-Si alloys is discussed systematically. The Cu-Ni-Si alloy with a Ni/Si mass ratio of 4–5 showed good comprehensive properties. Precipitates with disc-like shapes were confirmed as the Ni2Si phase with orthorhombic structure through transmission electron microscopy, high-resolution transmission electron microscopy, and 3D atom probe characterization. After the appropriate thermomechanical treatment, the studied alloy with a Ni/Si mass ratio of 4.2 exhibited excellent mechanical properties: a hardness of 290 HV, tensile strength of 855 MPa, yield strength of 782 MPa, and elongation of 4.5%. Compared with other approaches, the thermomechanical treatment increased the hardness and strength without sacrificing electrical conductivity. Theoretical calculations indicated that the high strength was primarily attributed to the Orowan precipitation strengthening and secondarily ascribed to the work hardening, which were highly consistent with the experimental results. The appropriate Ni/Si mass ratio with a low content of Ni and Si atoms shows high strength and excellent electrical conductivity through combined thermomechanical treatment. This work provides a guideline for the design and preparation of multicomponent Cu-Ni-Si-X alloys with ultrahigh strength and excellent electrical conductivity

Comparative study on the properties and microscopic mechanism of Ti coating and W coating diamond-copper composites

Interface plays a decisive role in metal matrix composites, and the effects of Ti coating and W coating on the properties and microscopic mechanism of diamond-copper composites are compared in this paper. Ti-coated diamond with 50 nm, 100 nm and 150 nm plating thickness and W-coated diamond with 50 nm plating thickness are prepared by using magnetron sputtering. Then infiltration method is carried out to prepare diamond copper composites. SEM, EDS and XRD are used to material microstructure. Three-point bending experiment and flash method are used to test the bending strength and thermal conductivity of the composite material. The study found that, as the thickness of the Ti coating increases, the bending strength of the composites gradually increases, but the thermal conductivity first increases and then decreases. The thermal conductivity of W coated diamond copper composites is higher than that of Ti coated diamond copper composites with the same coating thickness. But bonding strength shows the opposite law. The reason for the above phenomenon is that the mechanism of action between the Ti coating and the W coating and the copper substrate is different at the micro interface of the composites. The research work has important reference value for the interface modification of diamond copper composites

Microstructure Comparison for AlSn20Cu Antifriction Alloys Prepared by Semi-Continuous Casting, Semi-Solid Die Casting, and Spray Forming

Antifriction alloys such as AlSn20Cu are key material options for sliding bearings used in machinery. Uniform distribution and a near-equiaxed granularity tin phase are generally considered to be ideal characteristics of an AlSn20Cu antifriction alloy, although these properties vary by fabrication method. In this study, to analyze the variation of the microstructure with the fabrication method, AlSn20Cu alloys are prepared by three methods: semi-continuous casting, semi-solid die casting, and spray forming. Bearing blanks are subsequently prepared from the fabricated alloys using different processes. Morphological information, such as the total area ratio and average particle diameter of the tin phase, are quantitatively characterized. For the tin phase of the AlSn20Cu alloy, the deformation and annealing involved in semi-continuous casting leads to a prolate particle shape. The average particle diameter of the tin phase is 12.6 µm, and the overall distribution state is related to the deformation direction. The tin phase of AlSn20Cu alloys prepared by semi-solid die casting presents both nearly spherical and strip shapes, with an average particle diameter of 9.6 µm. The tin phase of AlSn20Cu alloys prepared by spray forming and blocking hot extrusion presents a nearly equilateral shape, with an average particle diameter of 6.2 µm. These results indicate that, of the three preparation methods analyzed in this study, semi-solid die casting provides the shortest process flow time, whereas a finer and more uniform tin-phase structure may be obtained using the spray-forming process. The semi-solid die casting method presents the greatest potential for industrial application, and this method therefore presents a promising possibility for further optimization

Effect of Cold Working on the Properties and Microstructure of Cu-3.5 wt% Ti Alloy

Cu-Ti alloys were strengthened by β’-Cu4Ti metastable precipitation during aging. With the extension of the aging time, the β’-Cu4Ti metastable phase transformed into the equilibrium β-Cu4Ti phase. The Cu-3.5 wt% Ti(Cu-4.6 at% Ti) alloys with different processing were aged at different temperatures for various times after solution treatment at 880 °C for 1 h. The electrical conductivity of samples under different heat treatments had shown an upward trend as time increased during aging, but the hardness reached the peak value and then decreased. The hardness and electrical conductivity of the samples with 70% deformation after aging are higher tha n the samples without deformation. Deformation after aging would cause the metastable phase to dissolve into a matrix. The best combination value of conductivity and hardness is 13.88% IACS and 340.78 Hv, and the optimal heat treatment is 500 °C for 2 h + 70% deformation + 450 °C for 2 h

Effect of Annealing on the Interface and Properties of Pd/Al Composite Wires

This paper investigates the changes in the interface organization and properties of 0.10 mm Pd/Al composite wires annealed at different temperatures. The optimum comprehensive performance of the material was obtained after annealing at 300 °C for 120 s. Its tensile strength, conductivity and elongation are 140.61 MPa, 46.82%IACS and 14.89%, respectively. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were used to observe the intermetallic compounds on the interface. The annealing temperature and the formation heat of intermetallic compounds determine the categories and evolution of intermetallic compounds. When the thickness of the intermetallic layer is more than 1 μm, it has a serious effect on the electrical conductivity and elongation of the materials

Optimal Nitrogen Rate Increases Water and Nitrogen Use Efficiencies of Maize under Fully Mulched Ridge–Furrow System on the Loess Plateau

Increasing water and nitrogen use efficiencies (i.e., WUE and NUE) in dryland agroecosystems to maintain high agricultural output with lower environmental costs, such as minimal soil water depletion and nitrate-N residue, are key responsibilities to assure food security for a growing global population. The impact of N rate on soil water balance, soil nitrate N residue, grain yield, WUE, crop N recovery efficiency (REN), agronomic use efficiency of N fertilizer (AE), and net economic return were examined on maize production on the rainfed Loess Plateau during 2011–2018. Field treatments included four N application rates (N0, no N fertilizer applied; N100, 100 kg N ha−1; N200, 200 kg N ha−1; N300, 300 kg N ha−1). Results showed that compared with N0, grain yield increased by 56, 110, and 115% under N100, N200, and N300, respectively, with corresponding improvements in net economic return of 5497, 10,878, and 11,088 RMB ha−1 yr−1, respectively; no significant difference was detected between N200 and N300. Compared to N0, N fertilization significantly increased WUE through improving photosynthetic WUE (i.e., transpiration efficiency), but there was no significant difference between N200 and N300. Compared to N100, the REN was gradually decreased as N rates increased, AE was not significantly changed under N200 and significantly decreased under N300 due to a decreased leaf photosynthetic NUE. Compared to original soil water storage at 0–300 cm soil depths, after seven years of continuous experiments, treatment of N0 enhanced soil water storage by 52 mm and treatment of N100 had no effect on soil water storage, but treatments of N200 and N300 depleted soil water storage by 73 and 109 mm, respectively. Our findings showed that 200 kg N ha−1 improves WUE and NUE with less environmental cost and should be regarded as the economically optimal N rate on the semiarid western Loess Plateau of China for sustainable maize production