Transition of stoichiometricSr2VO3FeAs to a superconducting state at 37.2 K

The superconductor Sr4V2O6Fe2As2 with transition temperature at 37.2 K has been fabricated. It has a layered structure with the space group of p4/nmm, and with the lattice constants a = 3.9296Aand c = 15.6732A. The observed large diamagnetization signal and zero-resistance demonstrated the bulk superconductivity. The broadening of resistive transition was measured under different magnetic fields leading to the discovery of a rather high upper critical field. The results also suggest a large vortex liquid region which reflects high anisotropy of the system. The Hall effect measurements revealed dominantly electron-like charge carriers in this material. The superconductivity in the present system may be induced by oxygen deficiency or the multiple valence states of vanadium.Comment: 5 pages, 4 figure

Superconductivity at 15.6 K in Calcium-doped Tb_{1-x}Ca_xFeAsO: the structure requirement for achieving superconductivity in the hole-doped 1111 phase

Superconductivity at about 15.6 K was achieved in Tb_{1-x}Ca_xFeAsO by partially substituting Tb^{3+} with Ca^{2+} in the nominal doping region x = 0.40 \sim 0.50. A detailed investigation was carried out in a typical sample with doping level of x = 0.44. The upper critical field of this sample was estimated to be 77 Tesla from the magnetic field dependent resistivity data. The domination of hole-like charge carriers in the low-temperature region was confirmed by Hall effect measurements. The comparison between the calcium-doped sample Pr_{1-x}Ca_xFeAsO (non-superconductive) and the Strontium-doped sample Pr_{1-x}Sr_xFeAsO (superconductive) suggests that a lager ion radius of the doped alkaline-earth element compared with that of the rare-earth element may be a necessary requirement for achieving superconductivity in the hole-doped 1111 phase.Comment: 7 pages, 7 figure

Design of Joint Spatial and Power Domain Multiplexing Scheme for Massive MIMO Systems

Massive Multiple-Input Multiple-Output (MIMO) is one of the key techniques in 5th generation wireless systems (5G) due to its potential ability to improve spectral efficiency. Most of the existing works on massive MIMO only consider Time Division Duplex (TDD) operation that relies on channel reciprocity between uplink and downlink channels. For Frequency Division Duplex (FDD) systems, with continued efforts, some downlink multiuser MIMO scheme was recently proposed in order to enable “massive MIMO” gains and simplified system operations with limited number of radio frequency (RF) chains in FDD system. However these schemes, such as Joint Spatial Division and Multiplexing (JSDM) scheme and hybrid precoding scheme, only focus on multiuser transmission in spatial domain. Different from most of the existing works, this paper proposes Joint Spatial and Power Multiplexing (JSPM) scheme in FDD systems. It extends existing FDD schemes from spatial division and multiplexing to joint spatial and power domain to achieve more multiplexing gain. The user grouping and scheduling scheme of JSPM is studied and the asymptotic expression for the sum capacity is derived as well. Finally, simulations are conducted to illustrate the effectiveness of the proposed scheme

Dichloridobis(5-heptyl-1,3,4-thia­diazol-2-amine-κN 3)zinc(II)

In the title compound, [ZnCl2(C9H17N3S)2], the ZnII atom is four-coordinated by two N atoms from two 5-heptyl-1,3,4-thia­diazol-2-amine ligands and two Cl atoms in a distorted tetra­hedral geometry. The thia­diazole rings are oriented at a dihedral angle of 84.87 (4)°. Intra­molecular N—H⋯Cl inter­actions result in the formation of two six-membered rings having envelope and planar conformations. In the crystal structure, inter­molecular N—H⋯N and N—H⋯Cl inter­actions link the mol­ecules into a three-dimensional network. π–π contacts between thia­diazole rings [centroid–centroid distance = 3.602 (1) Å] may further stabilize the structure

The ultra-low-frequency shear modes of 2-4 layer graphenes observed in their scroll structures at edges

The in-plane shear modes between neighbor-layers of 2-4 layer graphenes (LGs) and the corresponding graphene scrolls rolled up by 2-4LGs were investigated by Raman scattering. In contrast to that just one shear mode was observed in 3-4LGs, all the shear modes of 3-4LGs were observed in 3-4 layer scrolls (LSs), whose frequencies agree well with the theoretical predication by both a force-constant model and a linear chain model. In comparison to the broad width (about 12cm$^{-1}$) for the G band in graphite, all the shear modes exhibit an intrinsic line width of about 1.0 cm$^{-1}$. The local electronic structures dependent on the local staking configurations enhance the intensity of the shear modes in corresponding 2-4LSs zones, which makes it possible to observe all the shear modes. It provides a direct evidence that how the band structures of FLGs can be sensitive to local staking configurations. This result can be extended to n layer graphene (n > 4) for the understanding of the basic phonon properties of multi-layer graphenes. This observation of all-scale shear modes can be foreseen in other 2D materials with similar scroll structures.Comment: 14 pages, 5 figure

(Sr_3Sc_2O_5)Fe_2As_2 as a possible parent compound for FeAs-based superconductors

A new compound with the FeAs-layers, namely (Sr_3Sc_2O_5)Fe_2As_2 (abbreviated as FeAs-32522), was successfully fabricated. It has a layered structure with the space group of I4/mmm, and with the lattice constants a = 4.069 $\AA$ and c = 26.876 $\AA$. The in-plane Fe ions construct a square lattice which is close to that of other FeAs-based superconductors, such as REFeAsO (RE = rare earth elements) and (Ba,Sr)Fe_2As_2. However the inter FeAs-layer spacing in the new compound is greatly enlarged. The temperature dependence of resistivity exhibits a weak upturn in the low temperature region, but a metallic behavior was observed above about 60 K. The magnetic susceptibility shows also a non-monotonic behavior. Interestingly, the well-known resistivity anomaly which was discovered in all other parent compounds, such as REFeAsO, (Ba,Sr)Fe_2As_2 and (Sr,Ca,Eu)FeAsF and associated with the Spin-Density-Wave (SDW)/structural transition has not been found in the new system either on the resistivity data or the magnetization data. This could be induced by the large spacing distance between the FeAs-planes, therefore the antiferromagnetic correlation between the moments of Fe ions in neighboring FeAs-layers cannot be established. Alternatively it can also be attributed to the self-doping effect between Fe and Sc ions. The Hall coefficient R_H is negative but strongly temperature dependent in wide temperature region, which indicates the dominance of electrical conduction by electron-like charge carriers and probably a multi-band effect or a spin related scattering effect. It is found that the magnetoresistance cannot be described by the Kohler's rule, which gives further support to above arguments.Comment: 5 pages, 5 figures, some contents added, and one figure adde

A Phase Change Storage Material that May be Used in the Fire Resistance of Building Structure

AbstractThis study prepared polyethylene glycol/silicon dioxide composite, a kind of form-stable phase change material. The composites can be made into mortar which is able to adhere to the surface of building structure and absorb the fire heat. This paper aims to study the effect of the composites on the fire resistance of building structure. Scanning electronic microscope and differential scanning calorimeter were adopted to investigate the structural and thermal properties of the composites. It was found that the polyethylene glycol was well dispersed into the network of solid SiO2. And the latent heat of PEG/SiO2 increased with the decrease of SiO2 content. The required weight percentage of SiO2 was found to be 15% at least if the composites remain solid without leakage. It was also found that a phase change of pure PEG6000 happened with an enthalpy of 158J/g while the 80 wt% PEG composite is 133J/g. In conclusion, the phase change storage material may be used for fire resistance of building structure