104 research outputs found
Influence of confinement on the orientational phase transitions in the lamellar phase of a block copolymer melt under shear flow
In this work we incorporate some real-system effects into the theory of
orientational phase transitions under shear flow (M. E. Cates and S. T. Milner,
Phys. Rev. Lett. v.62, p.1856 (1989) and G. H. Fredrickson, J. Rheol. v.38,
p.1045 (1994)). In particular, we study the influence of the shear-cell
boundaries on the orientation of the lamellar phase. We predict that at low
shear rates the parallel orientation appears to be stable. We show that there
is a critical value of the shear rate at which the parallel orientation loses
its stability and the perpendicular one appears immediately below the spinodal.
We associate this transition with a crossover from the fluctuation to the
mean-field behaviour. At lower temperatures the stability of the parallel
orientation is restored. We find that the region of stability of the
perpendicular orientation rapidly decreases as shear rate increases. This
behaviour might be misinterpreted as an additional perpendicular to parallel
transition recently discussed in literature.Comment: 25 pages, 4 figures, submitted to Phys. Rev.
Weak Segregation Theory and Non-Conventional Morphologies in the Ternary ABC Triblock Copolymers
The Leibler weak segregation theory in molten diblock copolymers is
generalized with due regard for the 2nd shell harmonics contributions defined
in the paper and the phase diagrams are built for the linear and miktoarm
ternary ABC triblock copolymers. The symmetric linear copolymers with the
middle block non-selective with respect to the side ones are shown to undergo
the continuous ODT not only into the lamellar phase but also into various
non-conventional cubic phases (depending on the middle block composition it
could be the simple cubic, face-centered cubic or non-centrosymmetric phase
revealing the symmetry of space group No.214 first predicted to appear in
molten block copolymers). For asymmetric linear ABC copolymers a region of
compositions is found where the weakly segregated gyroid (double gyroid) phase
exists between the planar hexagonal and lamellar or one of the non-conventional
cubic phases up to the very critical point. In contrast, the miktoarm ABC block
copolymers with one of its arm non-selective with respect to the two others are
shown to reveal a pronounced tendency towards strong segregation, which is
preceded by increase of stability of the conventional BCC phase and a peculiar
weakly segregated BCC phase (BCC3), where the dominant harmonics belong to the
3rd co-ordination sphere of the reciprocal lattice. The validity region of the
developed theory is discussed and outlined in the composition triangles both
for linear and miktoarm copolymers.Comment: 61 pages, 12 figure
Kinetics of phase transitions in weakly segregated block copolymers: Pseudostable and transient states
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Nanoshells and nanotubes from block copolymers
Recent work exploring the use of block copolymer vesicles and tubules is reviewed. The stability and toughness of block copolymer vesicles are enhanced compared to those formed by low molar mass amphiphiles. Functionality can also readily be introduced through the polymer chemistry or by incorporating additional components (for example pore-forming membrane proteins). This design flexibility leads to numerous potential applications in encapsulation, in targeted drug delivery, templating of inorganic materials and many others
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Ordering in thin films of block copolymers: fundamentals to potential applications
The ordering of block copolymers in thin films is reviewed, starting, from the fundamental principles and extending to recent promising developments as templates for nanolithography which may find important applications in the semiconductor industry. Ordering in supported thin films of symmetric and asymmetric AB diblock and ABA triblock copolymers is discussed, along with that of more complex materials such as ABC triblocks and liquid crystalline block copolymers Techniques to prepare thin films, and to characterise ordering within them, are summarized. Several methods to align Hock copolymer nanostructures, important in several applications are outlined A number of potential applications in nanolithography, production of porous materials, templating. and patterning of organic and inorganic materials are then presented. The influence of crystallization on the morphology of a block copolymer film is briefly discussed, as are structures in grafted block copolymer films. (C) 2009 Elsevier Ltd All rights reserved
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Multiple morphologies of gold nano-plates by high-temperature polyol syntheses
High-temperature polyol methods were used to fabricate micro- or nano-sized gold plates. 1,2propanediol served as both medium and reducing agent. Triangular plates and polygonal plate shapes derived from triangular prisms as well as pentagonal structured gold particles have been synthesized. Poly(vinylpyrrolidone) (PVP) plays an important role, but is not necessary, for the formation of these structures. These gold plates may have applications in the characterisation of adsorbed proteins or peptides. (C) 2008 Elsevier B. V. All rights reserved
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Capillary flow behavior of worm-like micelles studied by small-angle X-ray scattering and small angle light scattering
A novel capillary flow device has been developed and applied to study the orientation of worm-like micelles, among other systems. Small-angle X-ray scattering (SAXS) data from micelles formed by a Pluronic block copolymer in aqueous salt solution provides evidence for the formation of worm-like micelles, which align under flow. A transition from a rod-like form factor to a less persistent conformation is observed under flow. Flow alignment of worm-like micelles formed by the low molar mass amphiphile system cetyl pyridinium chloride+sodium salicylate is studied for comparative purposes. Here, inhomogenous flow at the micron scale is revealed by streaks in the small-angle light scattering pattern perpendicular to the flow direction. Copyright (c) 2006 John Wiley & Sons, Ltd
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Beta-lactoglobulin fibers under capillary flow
We describe the capillary flow behavior of gels of beta-lactoglobulin (beta-lg) containing droplets of fibrils and the shear flow alignment of beta-lg fibers in dilute aqueous solutions. Polarized optical microscopy and laser scanning confocal microscopy are used to show that capillary shear flow does not affect the fibril droplet sizes in the beta-lg gels, the system behaving in this respect as a solution of compact colloidal particles under shear flow. Small-angle X-ray scattering (SAXS) on dilute aqueous solutions indicates that the fibers can be initially aligned under capillary shear, but this alignment is lost after 18 min of shear. Transmission electron microscopy experiments on the samples studied by SAXS suggest that the loss of orientation is due to a shear-induced breakup of the swollen fibril network. Dynamic and static light scattering on dilute beta-lg fibril aqueous solutions are used to show that before shear beta-lg fibrils behave as strongly interacting semiflexible polymers, while they behave as weakly interacting rods after 18 min of capillary shear
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