2,464 research outputs found
Superadiabatic transitions in quantum molecular dynamics
We study the dynamics of a moleculeâs nuclear wave function near an avoided crossing of two electronic energy levels for one nuclear degree of freedom. We derive the general form of the Schrödinger equation in the nth superadiabatic representation for all n Ń N. Using these results, we obtain closed formulas for the time development of the component of the wave function in an initially unoccupied energy subspace when a wave packet travels through the transition region. In the optimal superadiabatic representation, which we define, this component builds up monotonically. Finally, we give an explicit formula for the transition wave function away from the avoided crossing, which is in excellent agreement with high-precision numerical calculations
Determination of Non-Adiabatic Scattering Wave Functions in a Born-Oppenheimer Model
We study non--adiabatic transitions in scattering theory for the time
dependent molecular Schroedinger equation in the Born--Oppenheimer limit. We
assume the electron Hamiltonian has finitely many levels and consider the
propagation of coherent states with high enough total energy. When two of the
electronic levels are isolated from the rest of the electron Hamiltonian's
spectrum and display an avoided crossing, we compute the component of the
nuclear wave function associated with the non--adiabatic transition that is
generated by propagation through the avoided crossing. This component is shown
to be exponentially small in the square of the Born--Oppenheimer parameter, due
to the Landau-Zener mechanism. It propagates asymptotically as a free Gaussian
in the nuclear variables, and its momentum is shifted. The total transition
probability for this transition and the momentum shift are both larger than
what one would expect from a naive approximation and energy conservation
Avoided crossings in mesoscopic systems: electron propagation on a non-uniform magnetic cylinder
We consider an electron constrained to move on a surface with revolution
symmetry in the presence of a constant magnetic field parallel to the
surface axis. Depending on and the surface geometry the transverse part of
the spectrum typically exhibits many crossings which change to avoided
crossings if a weak symmetry breaking interaction is introduced. We study the
effect of such perturbations on the quantum propagation. This problem admits a
natural reformulation to which tools from molecular dynamics can be applied. In
turn, this leads to the study of a perturbation theory for the time dependent
Born-Oppenheimer approximation
Large Nc Continuum Reduction and the Thermodynamics of QCD
It is noted that if large Nc continuum reduction applies to an observable,
then that observable is independent of temperature for all temperatures below
some critical value. This fact, plus the fact that mesons and glueballs are
weakly interacting at large Nc is used as the basis for a derivation of large
Nc continuum reduction for the chiral condensate. The structure of this
derivation is quite general and can be extended to a wide class of observables
The Hagedorn temperature Revisited
The Hagedorn temperature, T_H is determined from the number of hadronic
resonances including all mesons and baryons. This leads to a stable result T_H
= 174 MeV consistent with the critical and the chemical freeze-out temperatures
at zero chemical potential. We use this result to calculate the speed of sound
and other thermodynamic quantities in the resonance hadron gas model for a wide
range of baryon chemical potentials following the chemical freeze-out curve. We
compare some of our results to those obtained previously in other papers.Comment: 13 pages, 4 figure
Kappa-deformed Statistics and the Formation of a Quark-Gluon Plasma
The effect of the non-extensive form of statistical mechanics proposed by
Tsallis on the formation of a quark-gluon plasma (QGP) has been recently
investigated in ref. \cite{1}. The results show that for small deviations
() from Boltzmann-Gibbs (BG) statistics in the QGP phase, the
critical temperature for the formation of a QGP does not change substantially
for a large variation of the chemical potential. In the present effort we use
the extensive -deformed statistical mechanics constructed by Kaniadakis
to represent the constituents of the QGP and compare the results with ref. [1].Comment: 2 Figure
N=(1,1) super Yang--Mills theory in 1+1 dimensions at finite temperature
We present a formulation of N=(1,1) super Yang-Mills theory in 1+1 dimensions
at finite temperature. The partition function is constructed by finding a
numerical approximation to the entire spectrum. We solve numerically for the
spectrum using Supersymmetric Discrete Light-Cone Quantization (SDLCQ) in the
large-N_c approximation and calculate the density of states. We find that the
density of states grows exponentially and the theory has a Hagedorn
temperature, which we extract. We find that the Hagedorn temperature at
infinite resolution is slightly less than one in units of (g^(2) N_c/pi)^(1/2).
We use the density of states to also calculate a standard set of thermodynamic
functions below the Hagedorn temperature. In this temperature range, we find
that the thermodynamics is dominated by the massless states of the theory.Comment: 16 pages, 8 eps figures, LaTe
Strangeness, Equilibration, Hadronization
In these remarks I explain the motivation which leads us to consider chemical
nonequilibrium processes in flavor equilibration and in statistical
hadroniziation of quark--gluon plasma (QGP). Statistical hadronization allowing
for chemical non-equilibrium is introduced. The reesults of fits to
RHIC-130 results, including multistrange hadrons, are shown to agree only
with the model of an exploding QGP fireball.Comment: 8 pages including one figure, discussion contribution at Strange
Quark Matter 2001, Frankfurt, submitted to J. Phys.
A Nonlinear Adiabatic Theorem for Coherent States
We consider the propagation of wave packets for a one-dimensional nonlinear
Schrodinger equation with a matrix-valued potential, in the semi-classical
limit. For an initial coherent state polarized along some eigenvector, we prove
that the nonlinear evolution preserves the separation of modes, in a scaling
such that nonlinear effects are critical (the envelope equation is nonlinear).
The proof relies on a fine geometric analysis of the role of spectral
projectors, which is compatible with the treatment of nonlinearities. We also
prove a nonlinear superposition principle for these adiabatic wave packets.Comment: 21 pages, no figur
Semiclassical (Quantum Field Theory) and Quantum (String) de Sitter Regimes: New Results
We compute the quantum string entropy S_s(m, H) from the microscopic string
density of states rho_s (m,H) of mass m in de Sitter space-time. We find for
high m, a {\bf new} phase transition at the critical string temperature T_s=
(1/2 pi k_B)L c^2/alpha', higher than the flat space (Hagedorn) temperature
t_s. (L = c/H, the Hubble constant H acts at the transition as producing a
smaller string constant alpha' and thus, a higher tension). T_s is the precise
quantum dual of the semiclassical (QFT Hawking-Gibbons) de Sitter temperature
T_sem = hbar c /(2\pi k_B L). We find a new formula for the full de Sitter
entropy S_sem (H), as a function of the usual Bekenstein-Hawking entropy
S_sem^(0)(H). For L << l_{Planck}, ie. for low H << c/l_Planck,
S_{sem}^{(0)}(H) is the leading term, but for high H near c/l_Planck, a new
phase transition operates and the whole entropy S_sem (H) is drastically
different from the Bekenstein-Hawking entropy S_sem^(0)(H). We compute the
string quantum emission cross section by a black hole in de Sitter (or
asymptotically de Sitter) space-time (bhdS). For T_sem ~ bhdS << T_s, (early
evaporation stage), it shows the QFT Hawking emission with temperature T_sem ~
bhdS, (semiclassical regime). For T_sem ~ bhdS near T_{s}, it exhibits a phase
transition into a string de Sitter state of size L_s = l_s^2/L}, l_s=
\sqrt{\hbar alpha'/c), and string de Sitter temperature T_s. Instead of
featuring a single pole singularity in the temperature (Carlitz transition), it
features a square root branch point (de Vega-Sanchez transition). New bounds on
the black hole radius r_g emerge in the bhdS string regime: it can become r_g =
L_s/2, or it can reach a more quantum value, r_g = 0.365 l_s.Comment: New original materia
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