Aspects of planar, oblique and interacting shock waves in an ideal dissociating gas

We develop a compact dimensionless framework for the analysis of canonical thermo-chemical nonequilibrium flow fields involving normal, oblique and interacting shock waves. Discontinuous solutions of the conservation equations are coupled with thermodynamic and kinetic models for an ideal dissociating gas. Convenient forms are provided for the variation of the relevant dimensionless parameters across shock waves in dissociating gases. The treatment is carried through in a consistent manner for the pressure–flow deflection angle plane representation of shock wave interaction problems. The contribution of the current paper is a careful nondimensionalization of the problem that yields a tractable formulation and allows results with considerable generality to be obtained

Role of Chlamydia trachomatis and emerging Chlamydia-related bacteria in ectopic pregnancy in Vietnam

In this case-control study, we investigated the seroprevalence and molecular evidence of Chlamydia trachomatis and Waddlia chondrophila in ectopic pregnancies (EP) and uneventful control (C) pregnancies in 343 women from Vietnam. Whereas presence of Chlamydia trachomatis IgG was strongly associated with EP (adjusted Odds Ratio [aOR] 5.41; 95% Confidence Intervals [95%CI] 2.58-11.32), its DNA remained undetected in all tubal lesions. We confirmed an independent association between antibodies against Waddlia and previous miscarriage (aOR 1.87, 95%CI 1.02-3.42). Further investigations are needed to understand the clinical significance of Waddlia high seroprevalence (25.9% in C) in this urban population

The influence of non-equilibrium dissociation on the flow produced by shock impingement on a blunt body

We describe an investigation of the effects of non-equilibrium thermochemistry on the interaction between a weak oblique shock and the strong bow shock formed by a blunt body in hypersonic flow. This type of shock-on-shock interaction, also known as an Edney type IV interaction, causes locally intense enhancement of the surface heat transfer rate. A supersonic jet is formed by the nonlinear interaction that occurs between the two shock waves and elevated heat transfer rates and surface pressures are produced by the impingement of the supersonic jet on the body. The current paper is motivated by previous studies suggesting that real gas effects would significantly increase the severity of the phenomenon. Experiments are described in which a free-piston shock tunnel is used to produce shock interaction flows with significant gas dissociation. Surprisingly, the data that are obtained show no significant stagnation enthalpy dependence of the ratio of the peak heat transfer rates with and without shock interaction, in contrast to existing belief. The geometry investigated is the nominally two-dimensional flow about a cylinder with coplanar impinging shock wave. Holographic interferometry is used to visualize the flow field and to quantify increases in the stagnation density caused by shock interaction. Time-resolved heat transfer measurements are obtained from surface junction thermocouples about the model forebody. An improved model is developed to elucidate the finite-rate thermochemical processes occurring in the interaction region. It is shown that severe heat transfer intensification is a result of a jet shock structure that minimizes the entropy rise of the supersonic jet fluid whereas strong thermochemical effects are promoted by conditions that maximize the entropy rise (and hence temperature). This dichotomy underlies the smaller than anticipated influence of real gas effects on the heat transfer intensification. The model accurately predicts the measured heat transfer rates. Improved understanding of the influence of real gas effects on the shock interaction phenomenon reduces a significant element of risk in the design of hypersonic vehicles. The peak heat transfer rate for the Edney type IV interaction is shown to be well-correlated, in the weak impinging shock regime, by an expression of the form [equation] for use in practical design calculations

Ethics and Design in the Brazilian Context

Often driven by practical and immediate requirements, more and more people are incorporating technology into a variety of aspects of their lives, often without reflecting on the consequences of using them. On the other hand, studies on interactive system development that lead to behavioral change have been gaining ground on the agenda of large HCI conferences. This movement brings to the forefront the fundamental issues of ethics in design and technology use. A designer’s intentions, when directing certain actions or behaviors, are not always explicit or desired by the stakeholders affected by the use of the technology. Systems that induce an undesired purchase, or even those that use conditioning strategies to cause a behavioral change are examples of such intentions. The challenge proposed is therefore about the relationship between design and personal freedom in a way that these technology users do not become victims, either passively or submissively, of the effects of its use. This advance allows for the redefinition of the relationship between man and technology, and the application of new forms of designing and developing interactive systems that take into account the ethical aspects of this relationship

Modification of the simple mass balance equation for calculation of critical loads of acidity.

Over the last few years, the simple mass balance equation for the calculation of critical loads of acidity has been gradually modified as the underlying critical load concepts have developed and as problems with particular forms of the equation have been identified, through application in particular countries. The first major update of the equation took place following a workshop held in Vienna, Austria (Hojesky et al. 1993). The workshop was held to discuss problems which had been identified when the then current form of the equation was applied in countries with high rainfall. The problems had largely arisen because of simplifications and assumptions incorporated into the early formulation of the equation. The equation was reformulated to overcome the problems identified at the workshop. However, further problems were identified when the reformulated equation was applied in the UK in situations with a combination of high rainfall, large marine inputs and widespread occurrence of organic soils. A small workshop was, therefore held in Grange-over-Sands, UK in late 1993 to dicuss the problems and to further re-evaluate the equation. The problems had arisen in the UK because of simplifications and assumptions made in the formulation concerning, in particular, cation leaching and uptake. As a result, a more rigorous treatment of these variables was incorporated into the equation. The reformulation of the equation, as derived at the September 1993 workshop is described below

Estudo dos efeitos da radiação ultravioleta nas propriedades termogravimétricas de amido de mandioca oxidado por hipoclorito de sódio.

Resumo

Near-inertial wave scattering by random flows

The impact of a turbulent flow on wind-driven oceanic near-inertial waves is examined using a linearised shallow-water model of the mixed layer. Modelling the flow as a homogeneous and stationary random process with spatial scales comparable to the wavelengths, we derive a transport (or kinetic) equation governing wave-energy transfers in both physical and spectral spaces. This equation describes the scattering of the waves by the flow which results in a redistribution of energy between waves with the same frequency (or, equivalently, with the same wavenumber) and, for isotropic flows, in the isotropisation of the wave field. The time scales for the scattering and isotropisation are obtained explicitly and found to be of the order of tens of days for typical oceanic parameters. The predictions inferred from the transport equation are confirmed by a series of numerical simulations. Two situations in which near-inertial waves are strongly influenced by flow scattering are investigated through dedicated nonlinear shallow-water simulations. In the first, a wavepacket propagating equatorwards as a result from the $\beta$-effect is shown to be slowed down and dispersed both zonally and meridionally by scattering. In the second, waves generated by moving cyclones are shown to be strongly disturbed by scattering, leading again to an increased dispersion.Comment: Accepted for publication in Phys. Rev. Fluid

TG-DTA and DSC investigations of ''pinhão'' starch modified by calcium hypochlorite and UV light.

Starches, when in its native forms, usually do not have the characteristics required for industrial processing. ''Pinhão'', a seed from the Araucaria angustifolia tree, has starch as main presenting as a great alternative source of starch. Samples of native ''pinhão'' starch were treated with standard calcium hypochlorite solutions (0.1, 0.2 and 0.5 mol L-1) and exposed for one hour under UV light. The modification process applied altered the thermal behavior of the ''pinhão'' starch as the TGA-DTA and DSC results presented.Edição dos Anais do 7º Simpósio de Análise Térmica, 2015, Bauru