Moving liquids with light: Photoelectrowetting on semiconductors

Liquid transport in microchip-based systems is important in many areas such as Laboratory-on-a-chip, Microfluidics and Optofluidics. Actuation of liquids in such systems is usually achieved using either mechanical displacement11 or via energy conversion e.g. electrowetting which modifies wetting. However, at the moment there is no clear way of actuating a liquid using light. Here, by linking semiconductor physics and wetting phenomenon a brand new effect "photoelectrowetting" is demonstrated for a droplet of conducting liquid resting on an insulator-semiconductor stack. Optical generation of carriers in the space-charge region of the underlying semiconductor alters the capacitance of the insulator-semiconductor stack; the result of this is a modification of the wetting contact angle of the droplet upon illumination. The effect is demonstrated using commercial silicon wafers, both n- and p-type having a doping range spanning four orders of magnitude (6\times1014-8\times1018 cm-3), coated with a commercial fluoropolymer insulating film (Teflon\textregistered). Impedance measurements confirm that the observations are semiconductor space-charge related effects. The impact of the work could lead to new silicon-based technologies in the above mentioned areas

A chip scale nanofluidic pump using electrically controllable hydrophobicity

10.1007/s00542-009-0960-9Microsystem Technologies164561-57

Electrowetting Force and Velocity Dependence on Fluid Surface Energy

Electrowetting on dielectric is a phenomenon in which the shape and apparent contact angle of a droplet changes when an electric field is applied across the droplet interface. If the field is asymmetric with respect to the droplet, then a net force can be applied to the droplet. In this work, we have measured the electrowetting force by confining the droplet shape beneath a glass plate and measuring the force on the plate. The force was measured as a function of voltage for a range of fluids with different surface energy. Measured forces show excellent agreement with predictions based on the Young–Lippmann equation with measured contact angles. Results also show that the electrowetting force is independent of fluid surface energy below saturation but that the peak force is proportional to the surface tension. This work shows that lowering the surface energy of the fluid can induce larger contact angle change under the same voltage, but it has no beneficial impact on the actuation force in droplet-based actuators. In contrast, velocity tests with deformable droplets show higher speeds for lower surface energy fluids, even above their saturation voltage. However, when the droplet’s shape is restrained, the highest velocity is achieved with high surface energy fluids due to the larger electrowetting actuation forces applied

Heat Transfer Enhancement During Water and Hydrocarbon Condensation on Lubricant Infused Surfaces

Vapor condensation is routinely used as an effective means of transferring heat or separating fluids. Dropwise condensation, where discrete droplets form on the condenser surface, offers a potential improvement in heat transfer of up to an order of magnitude compared to filmwise condensation, where a liquid film covers the surface. Low surface tension fluid condensates such as hydrocarbons pose a unique challenge since typical hydrophobic condenser coatings used to promote dropwise condensation of water often do not repel fluids with lower surface tensions. Recent work has shown that lubricant infused surfaces (LIS) can promote droplet formation of hydrocarbons. In this work, we confirm the effectiveness of LIS in promoting dropwise condensation by providing experimental measurements of heat transfer performance during hydrocarbon condensation on a LIS, which enhances heat transfer by ≈450% compared to an uncoated surface. We also explored improvement through removal of noncondensable gases and highlighted a failure mechanism whereby shedding droplets depleted the lubricant over time. Enhanced condensation heat transfer for low surface tension fluids on LIS presents the opportunity for significant energy savings in natural gas processing as well as improvements in thermal management, heating and cooling, and power generation.National Science Foundation (U.S.) (Grant 1122374