BaFe2Se2O as an Iron-Based Mott Insulator with Antiferromagnetic Order

A new compound with a quasi-two-dimensional array of FeSe3O tetrahedra and an orthorombic structure, namely BaFe2Se2O, has been successfully fabricated. Experimental results show that this compound is an insulator and has an antiferromagnetic (AF) transition at 240 K. Band structure calculation reveals the narrowing of Fe 3d bands near the Fermi energy, which leads to the localization of magnetism and the Mott insulating behavior. The large distances between the Fe atoms perhaps are responsible for the characters. Linear response calculation further indicates a strong in-plane AF exchange $J$, this can account for the enhanced magnetic susceptibility (which has a maximum at about 450 K) above the Neel temperature.Comment: submitted to PRL on 2 May 2012, resubmitted to PRB on 31 May 2012, and accepted by PRB on 5 July 201

Vortex images on Ba{1-x}KxFe2As2 observed directly by the magnetic force microscopy

The vortex states on optimally doped Ba0.6K0.4Fe2As2 and underdoped Ba0.77K0.23Fe2As2 single crystals are imaged by magnetic force microscopy at various magnetic fields below 100 Oe. Local triangular vortex clusters are observed in optimally doped samples. The vortices are more ordered than those in Ba(Fe{1-x}Co{x})2As2, and the calculated pinning force per unit length is about 1 order of magnitude weaker than that in optimally Co-doped 122 at the same magnetic field, indicating that the Co doping at the Fe sites induces stronger pinning. The proportion of six-neighbored vortices to the total amount increases quickly with increasing magnetic field, and the estimated value reaches 100% at several tesla. Vortex chains are also found in some local regions, which enhance the pinning force as well as the critical current density. Lines of vortex chains are observed in underdoped samples, and they may have originated from the strong pinning near the twin boundaries arising from the structural transition.Comment: 7 pages, 8 figure

Transition of stoichiometricSr2VO3FeAs to a superconducting state at 37.2 K

The superconductor Sr4V2O6Fe2As2 with transition temperature at 37.2 K has been fabricated. It has a layered structure with the space group of p4/nmm, and with the lattice constants a = 3.9296Aand c = 15.6732A. The observed large diamagnetization signal and zero-resistance demonstrated the bulk superconductivity. The broadening of resistive transition was measured under different magnetic fields leading to the discovery of a rather high upper critical field. The results also suggest a large vortex liquid region which reflects high anisotropy of the system. The Hall effect measurements revealed dominantly electron-like charge carriers in this material. The superconductivity in the present system may be induced by oxygen deficiency or the multiple valence states of vanadium.Comment: 5 pages, 4 figure

Superconductivity at 15.6 K in Calcium-doped Tb_{1-x}Ca_xFeAsO: the structure requirement for achieving superconductivity in the hole-doped 1111 phase

Superconductivity at about 15.6 K was achieved in Tb_{1-x}Ca_xFeAsO by partially substituting Tb^{3+} with Ca^{2+} in the nominal doping region x = 0.40 \sim 0.50. A detailed investigation was carried out in a typical sample with doping level of x = 0.44. The upper critical field of this sample was estimated to be 77 Tesla from the magnetic field dependent resistivity data. The domination of hole-like charge carriers in the low-temperature region was confirmed by Hall effect measurements. The comparison between the calcium-doped sample Pr_{1-x}Ca_xFeAsO (non-superconductive) and the Strontium-doped sample Pr_{1-x}Sr_xFeAsO (superconductive) suggests that a lager ion radius of the doped alkaline-earth element compared with that of the rare-earth element may be a necessary requirement for achieving superconductivity in the hole-doped 1111 phase.Comment: 7 pages, 7 figure

Doping effect of Cu and Ni impurities on the Fe-based superconductor Ba0.6K0.4Fe2As2

Copper and Nickel impurities have been doped into the iron pnictide superconductor Ba0.6K0.4Fe2As2. Resistivity measurements reveal that Cu and Ni impurities suppress superconducting transition temperature T_c with rates of \Delta T_c/Cu-1% = -3.5 K and \Delta T_c/Ni-1% = -2.9 K respectively. Temperature dependence of Hall coefficient R_H of these two series of samples show that both Cu-doping and Ni-doping can introduce electrons into Ba0.6K0.4Fe2As2. With more doping, the sign of R_H gradually changes from positive to negative, while the changing rate of Cu-doped samples is much faster than that of Ni-doped ones. Combining with the results of first-principles calculations published previously and the non-monotonic evolution of the Hall coefficient in the low temperature region, we argue that when more Cu impurities were introduced into Ba0.6K0.4Fe2As2, the removal of Fermi spectral weight in the hole-like Fermi surfaces is much stronger than that in the electron-like Fermi surfaces, which is equivalent to significant electron doping effect. DC magnetization and the lattice constants analysis reveal that static magnetic moments and notable lattice compression have been formed in Cu-doped samples. It seems that the superconductivity can be suppressed by the impurities disregard whether they are magnetic or nonmagnetic in nature. This gives strong support to a pairing gap with a sign reversal, like S^\pm. However, the relatively slow suppression rates of T_c show the robustness of superconductivity of Ba0.6K0.4Fe2As2 against impurities, implying that multi-pairing channels may exist in the system.Comment: 7 pages, 7 figure