Electrode Polarization Effects in Broadband Dielectric Spectroscopy

In the present work, we provide broadband dielectric spectra showing strong electrode polarization effects for various materials, belonging to very different material classes. This includes both ionic and electronic conductors as, e.g., salt solutions, ionic liquids, human blood, and colossal-dielectric-constant materials. These data are intended to provide a broad data base enabling a critical test of the validity of phenomenological and microscopic models for electrode polarization. In the present work, the results are analyzed using a simple phenomenological equivalent-circuit description, involving a distributed parallel RC circuit element for the modeling of the weakly conducting regions close to the electrodes. Excellent fits of the experimental data are achieved in this way, demonstrating the universal applicability of this approach. In the investigated ionically conducting materials, we find the universal appearance of a second dispersion region due to electrode polarization, which is only revealed if measuring down to sufficiently low frequencies. This indicates the presence of a second charge-transport process in ionic conductors with blocking electrodes.Comment: 9 pages, 6 figures, experimental data are provided in electronic form (see "Data Conservancy"

Pumping of liquids with ac voltages applied to asymmetric pairs of microelectrodes

The net flow of electrolyte induced by an ac electric potential applied to an array of asymmetric pairs of microelectrodes has recently been reported. The interaction between the oscillating electric field and the oscillating induced charge at the diffuse double layer on the electrodes results in a steady electro-osmotic velocity distribution on top of the electrodes. This slip velocity distribution is anisotropic and produces a net flow of fluid. This paper presents a theoretical analysis of the pumping phenomena based upon an electro osmotic model in ac fields. The electrical equations are solved numerically using the charge simulation method. The bulk flow generated by the electro-osmotic slip velocity is calculated. The dependence of the fluid flow on voltage and frequency is described and compared to experiment