Ruthenium-Based Heterocyclic Carbene-Coordinated Olefin Metathesis Catalysts

The fascinating story of olefin (or alkene) metathesis (eq 1) began almost five decades ago, when Anderson and Merckling reported the first carbon-carbon double-bond rearrangement reaction in the titanium-catalyzed polymerization of norbornene. Nine years later, Banks and Bailey reported “a new disproportionation reaction . . . in which olefins are converted to homologues of shorter and longer carbon chains...”. In 1967, Calderon and co-workers named this metal-catalyzed redistribution of carbon-carbon double bonds olefin metathesis, from the Greek word “μετάθεση”, which means change of position. These contributions have since served as the foundation for an amazing research field, and olefin metathesis currently represents a powerful transformation in chemical synthesis, attracting a vast amount of interest both in industry and academia

Capacity Comparison between MIMO-NOMA and MIMO-OMA with Multiple Users in a Cluster

In this paper, the performance of multiple-input multiple-output non-orthogonal multiple access (MIMO-NOMA) is investigated when multiple users are grouped into a cluster. The superiority of MIMO-NOMA over MIMO orthogonal multiple access (MIMO-OMA) in terms of both sum channel capacity and ergodic sum capacity is proved analytically. Furthermore, it is demonstrated that the more users are admitted to a cluster, the lower is the achieved sum rate, which illustrates the tradeoff between the sum rate and maximum number of admitted users. On this basis, a user admission scheme is proposed, which is optimal in terms of both sum rate and number of admitted users when the signal-to-interference-plus-noise ratio thresholds of the users are equal. When these thresholds are different, the proposed scheme still achieves good performance in balancing both criteria. Moreover, under certain conditions,it maximizes the number of admitted users. In addition, the complexity of the proposed scheme is linear to the number of users per cluster. Simulation results verify the superiority of MIMO-NOMA over MIMO-OMA in terms of both sum rate and user fairness, as well as the effectiveness of the proposed user admission scheme.Comment: accepted IEEE Journal on Selected Topics in Communications, June 2017, Keywords: Non-orthogonal multiple access (NOMA), multiple-input multiple-output (MIMO), channel capacity, sum rate, fairness, user admission, power allocatio

A Two-Phase Power Allocation Scheme for CRNs Employing NOMA

In this paper, we consider the power allocation (PA) problem in cognitive radio networks (CRNs) employing nonorthogonal multiple access (NOMA) technique. Specifically, we aim to maximize the number of admitted secondary users (SUs) and their throughput, without violating the interference tolerance threshold of the primary users (PUs). This problem is divided into a two-phase PA process: a) maximizing the number of admitted SUs; b) maximizing the minimum throughput among the admitted SUs. To address the first phase, we apply a sequential and iterative PA algorithm, which fully exploits the characteristics of the NOMA-based system. Following this, the second phase is shown to be quasiconvex and is optimally solved via the bisection method. Furthermore, we prove the existence of a unique solution for the second phase and propose another PA algorithm, which is also optimal and significantly reduces the complexity in contrast with the bisection method. Simulation results verify the effectiveness of the proposed two-phase PA scheme