Lieb-Thirring inequalities for geometrically induced bound states

We prove new inequalities of the Lieb-Thirring type on the eigenvalues of Schr\"odinger operators in wave guides with local perturbations. The estimates are optimal in the weak-coupling case. To illustrate their applications, we consider, in particular, a straight strip and a straight circular tube with either mixed boundary conditions or boundary deformations.Comment: LaTeX2e, 14 page

Magnetic transport in a straight parabolic channel

We study a charged two-dimensional particle confined to a straight parabolic-potential channel and exposed to a homogeneous magnetic field under influence of a potential perturbation $W$. If $W$ is bounded and periodic along the channel, a perturbative argument yields the absolute continuity of the bottom of the spectrum. We show it can have any finite number of open gaps provided the confining potential is sufficiently strong. However, if $W$ depends on the periodic variable only, we prove by Thomas argument that the whole spectrum is absolutely continuous, irrespectively of the size of the perturbation. On the other hand, if $W$ is small and satisfies a weak localization condition in the the longitudinal direction, we prove by Mourre method that a part of the absolutely continuous spectrum persists

Initial state maximizing the nonexponentially decaying survival probability for unstable multilevel systems

The long-time behavior of the survival probability for unstable multilevel systems that follows the power-decay law is studied based on the N-level Friedrichs model, and is shown to depend on the initial population in unstable states. A special initial state maximizing the asymptote of the survival probability at long times is found and examined by considering the spontaneous emission process for the hydrogen atom interacting with the electromagnetic field.Comment: 5 pages, 1 table. Accepted for publication in Phys. Rev.

Time-Energy coherent states and adiabatic scattering

Coherent states in the time-energy plane provide a natural basis to study adiabatic scattering. We relate the (diagonal) matrix elements of the scattering matrix in this basis with the frozen on-shell scattering data. We describe an exactly solvable model, and show that the error in the frozen data cannot be estimated by the Wigner time delay alone. We introduce the notion of energy shift, a conjugate of Wigner time delay, and show that for incoming state $\rho(H_0)$ the energy shift determines the outgoing state.Comment: 11 pages, 1 figur

Atomically dispersed Pt-N-4 sites as efficient and selective electrocatalysts for the chlorine evolution reaction

Chlorine evolution reaction (CER) is a critical anode reaction in chlor-alkali electrolysis. Although precious metal-based mixed metal oxides (MMOs) have been widely used as CER catalysts, they suffer from the concomitant generation of oxygen during the CER. Herein, we demonstrate that atomically dispersed Pt-N-4 sites doped on a carbon nanotube (Pt-1/CNT) can catalyse the CER with excellent activity and selectivity. The Pt-1/CNT catalyst shows superior CER activity to a Pt nanoparticle-based catalyst and a commercial Ru/Ir-based MMO catalyst. Notably, Pt-1/CNT exhibits near 100% CER selectivity even in acidic media, with low Cl- concentrations (0.1M), as well as in neutral media, whereas the MMO catalyst shows substantially lower CER selectivity. In situ electrochemical X-ray absorption spectroscopy reveals the direct adsorption of Cl- on Pt-N-4 sites during the CER. Density functional theory calculations suggest the PtN4C12 site as the most plausible active site structure for the CER

Generalized local interactions in 1D: solutions of quantum many-body systems describing distinguishable particles

As is well-known, there exists a four parameter family of local interactions in 1D. We interpret these parameters as coupling constants of delta-type interactions which include different kinds of momentum dependent terms, and we determine all cases leading to many-body systems of distinguishable particles which are exactly solvable by the coordinate Bethe Ansatz. We find two such families of systems, one with two independent coupling constants deforming the well-known delta interaction model to non-identical particles, and the other with a particular one-parameter combination of the delta- and (so-called) delta-prime interaction. We also find that the model of non-identical particles gives rise to a somewhat unusual solution of the Yang-Baxter relations. For the other model we write down explicit formulas for all eigenfunctions.Comment: 23 pages v2: references adde

Exterior-Interior Duality for Discrete Graphs

The Exterior-Interior duality expresses a deep connection between the Laplace spectrum in bounded and connected domains in $\mathbb{R}^2$, and the scattering matrices in the exterior of the domains. Here, this link is extended to the study of the spectrum of the discrete Laplacian on finite graphs. For this purpose, two methods are devised for associating scattering matrices to the graphs. The Exterior -Interior duality is derived for both methods.Comment: 15 pages 1 figur

Transport and dynamics on open quantum graphs

We study the classical limit of quantum mechanics on graphs by introducing a Wigner function for graphs. The classical dynamics is compared to the quantum dynamics obtained from the propagator. In particular we consider extended open graphs whose classical dynamics generate a diffusion process. The transport properties of the classical system are revealed in the scattering resonances and in the time evolution of the quantum system.Comment: 42 pages, 13 figures, submitted to PR

Spectral and localization properties of the Dirichlet wave guide with two concentric Neumann discs

Bound states of the Hamiltonian describing a quantum particle living on three dimensional straight strip of width $d$ are investigated. We impose the Neumann boundary condition on the two concentric windows of the radii $a$ and $b$ located on the opposite walls and the Dirichlet boundary condition on the remaining part of the boundary of the strip. We prove that such a system exhibits discrete eigenvalues below the essential spectrum for any $a,b>0$. When $a$ and $b$ tend to the infinity, the asymptotic of the eigenvalue is derived. A comparative analysis with the one-window case reveals that due to the additional possibility of the regulating energy spectrum the anticrossing structure builds up as a function of the inner radius with its sharpness increasing for the larger outer radius. Mathematical and physical interpretation of the obtained results is presented; namely, it is derived that the anticrossings are accompanied by the drastic changes of the wave function localization. Parallels are drawn to the other structures exhibiting similar phenomena; in particular, it is proved that, contrary to the two-dimensional geometry, at the critical Neumann radii true bound states exist.Comment: 25 pages, 7 figure

Duality and Anholonomy in Quantum Mechanics of 1D Contact Interactions

We study systems with parity invariant contact interactions in one dimension. The model analyzed is the simplest nontrivial one --- a quantum wire with a point defect --- and yet is shown to exhibit exotic phenomena, such as strong vs weak coupling duality and spiral anholonomy in the spectral flow. The structure underlying these phenomena is SU(2), which arises as accidental symmetry for a particular class of interactions.Comment: 4 pages ReVTeX with 4 epsf figures. KEK preprint 2000-3. Correction in Eq.(14