53,938 research outputs found
Fluctuations and universality in a catalysis model with long-range reactivity
The critical properties of the Ziff-Gulari-Barshad (ZGB) model with the
addition of long-range reactivity [C.H. Chan and P.A. Rikvold, Phys. Rev. E 91,
012103 (2015)] are further investigated. The scaling behaviors of the order
parameter, susceptibility, and correlation length provide addi- tional evidence
that the universality class of the ZGB system changes from the two-dimensional
Ising class to the mean-field class with the addition of even a weak long-range
reactivity mechanism
The motion of a deformable drop in a second-order fluid
The cross-stream migration of a deformable drop in a unidirectional shear flow of a second-order fluid is considered. Expressions for the particle velocity due to the separate effects of deformation and viscoelastic rheology are obtained. The direction and magnitude of migration are calculated for the particular cases of Poiseuille flow and simple shear flow and compared with experimental data
Modeling of secondary organic aerosol yields from laboratory chamber data
Laboratory chamber data serve as the basis for constraining models of secondary organic aerosol (SOA) formation. Current models fall into three categories: empirical two-product (Odum), product-specific, and volatility basis set. The product-specific and volatility basis set models are applied here to represent laboratory data on the ozonolysis of α-pinene under dry, dark, and low-NOx conditions in the presence of ammonium sulfate seed aerosol. Using five major identified products, the model is fit to the chamber data. From the optimal fitting, SOA oxygen-to-carbon (O/C) and hydrogen-to-carbon (H/C) ratios are modeled. The discrepancy between measured H/C ratios and those based on the oxidation products used in the model fitting suggests the potential importance of particle-phase reactions. Data fitting is also carried out using the volatility basis set, wherein oxidation products are parsed into volatility bins. The product-specific model is most likely hindered by lack of explicit inclusion of particle-phase accretion compounds. While prospects for identification of the majority of SOA products for major volatile organic compounds (VOCs) classes remain promising, for the near future empirical product or volatility basis set models remain the approaches of choice
Transverse Entanglement Migration in Hilbert Space
We show that, although the amount of mutual entanglement of photons
propagating in free space is fixed, the type of correlations between the
photons that determine the entanglement can dramatically change during
propagation. We show that this amounts to a migration of entanglement in
Hilbert space, rather than real space. For the case of spontaneous parametric
down conversion, the migration of entanglement in transverse coordinates takes
place from modulus to phase of the bi-photon state and back again. We propose
an experiment to observe this migration in Hilbert space and to determine the
full entanglement.Comment: 4 pages, 3 figure
Solicited and Unsolicited Credit Ratings: A Global Perspective
We conducted a global study of the long-term issuer ratings of nonfinancial firms from Standard and Poor's Ratings Services (S&P) for the period 1998–2003. Specifically, we focused on the solicited versus unsolicited ratings and sample-selection bias in the analysis. Unlike the literature, we adopted an improved method using Wooldridge’s instrumental-variable approach to mitigate the concern of specification errors in Heckman’s model. We found that the probability of seeking a long-term issuer rating is positively related to the size and profitability of the firm, and negatively related to the growth opportunities and debt levels of the firm. The credit rating is positively related to the sovereign rating, size, and profitability of the issuer, and negatively related to the debt ratio of the issuer. Consistent with the literature, we found sample-selection bias in credit ratings. Our findings suggest that the firms with solicited ratings seem to be more profitable, more liquid, and have lower leverage than the issuers with unsolicited ratings. After controlling for sample-selection bias and some key financial ratios, we found that unsolicited firms, on average, seem to have lower long-term issuer ratings.corporate long-term issuer ratings; solicited and unsolicited
Archetypal analysis of galaxy spectra
Archetypal analysis represents each individual member of a set of data
vectors as a mixture (a constrained linear combination) of the pure types or
archetypes of the data set. The archetypes are themselves required to be
mixtures of the data vectors. Archetypal analysis may be particularly useful in
analysing data sets comprising galaxy spectra, since each spectrum is,
presumably, a superposition of the emission from the various stellar
populations, nebular emissions and nuclear activity making up that galaxy, and
each of these emission sources corresponds to a potential archetype of the
entire data set. We demonstrate archetypal analysis using sets of composite
synthetic galaxy spectra, showing that the method promises to be an effective
and efficient way to classify spectra. We show that archetypal analysis is
robust in the presence of various types of noise.Comment: 6 pages, 5 figures, 1 style-file. Accepted for publication by MNRA
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Organic components in interplanetary dust particles and their implications for the synthesis of cometary organics
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