49 research outputs found
Suppressed dependence of polarization on epitaxial strain in highly polar ferroelectrics
A combined experimental and computational investigation of coupling between
polarization and epitaxial strain in highly polar ferroelectric
PbZr_0.2Ti_0.8O_3 (PZT) thin films is reported. A comparison of the properties
of relaxed (tetragonality c/a = 1.05) and highly-strained (c/a = 1.09)
epitaxial films shows that polarization, while being amongst the highest
reported for PZT or PbTiO_3 in either film or bulk forms (P_r = 82
microC/cm^2), is almost independent of the epitaxial strain. We attribute this
behavior to a suppressed sensitivity of the A-site cations to epitaxial strain
in these Pb-based perovskites, where the ferroelectric displacements are
already large, contrary to the case of less polar perovskites, such as BaTiO_3.
In the latter case, the A-site cation (Ba) and equatorial oxygen displacements
can lead to substantial polarization increases.Comment: 4 pages, 3 figure