Antifouling bastadin congeners target blue mussel phenoloxidase and complex copper(II) ions

Synthetically prepared congeners of spongederived bastadin derivatives such as 5,5'-dibromohemibastadin- 1 (DBHB) that suppress the settling of barnacle larvae were identified in this study as strong inhibitors of blue mussel phenoloxidase that is involved in the firm attachment of mussels to a given substrate. The IC50 value of DBHB as the most active enzyme inhibitor encountered in this study amounts to 0.84 mu M. Inhibition of phenoloxidase by DBHB is likely due to complexation of copper(II) ions from the catalytic centre of the enzyme by the a-oxo-oxime moiety of the compound as shown here for the first time by structure activity studies and by X-ray structure determination of a copper(II) complex of DBHB.Biotechnology & Applied MicrobiologyMarine & Freshwater BiologySCI(E)EI0ARTICLE61148-11581

Optical Quantum Computation with Perpetually Coupled Spins

The possibility of using strongly and continuously interacting spins for quantum computation has recently been discussed. Here we present a simple optical scheme that achieves this goal while avoiding the drawbacks of earlier proposals. We employ a third state, accessed by a classical laser field, to create an effective barrier to information transfer. The mechanism proves to be highly efficient both for continuous and pulsed laser modes; moreover it is very robust, tolerating high decay rates for the excited states. The approach is applicable to a broad range of systems, in particular dense structures such as solid state self-assembled (e.g., molecular) devices. Importantly, there are existing structures upon which `first step' experiments could be immediately performed.Comment: 5 pages including 3 figures. Updated to published versio

Exciton spin relaxation in single semiconductor quantum dots

We study the relaxation of the exciton spin (longitudinal relaxation time $T_{1}$) in single asymmetrical quantum dots due to an interplay of the short--range exchange interaction and acoustic phonon deformation. The calculated relaxation rates are found to depend strongly on the dot size, magnetic field and temperature. For typical quantum dots and temperatures below 100 K, the zero--magnetic field relaxation times are long compared to the exciton lifetime, yet they are strongly reduced in high magnetic fields. We discuss explicitly quantum dots based on (In,Ga)As and (Cd,Zn)Se semiconductor compounds.Comment: accepted for Phys. Rev.

Correlated Photon-Pair Emission from a Charged Single Quantum Dot

The optical creation and recombination of charged biexciton and trion complexes in an (In,Ga)As/GaAs quantum dot is investigated by micro-photoluminescence spectroscopy. Photon cross-correlation measurements demonstrate the temporally correlated decay of charged biexciton and trion states. Our calculations provide strong evidence for radiative decay from the excited trion state which allows for a deeper insight into the spin configurations and their dynamics in these systems.Comment: 5 pages, 3 figures, submitted for publicatio