Stabilization of carbon nanotubes by filling with inner tubes: An optical spectroscopy study on double-walled carbon nanotubes under hydrostatic pressure

The stabilization of carbon nanotubes via the filling with inner tubes is demonstrated by probing the optical transitions in double-walled carbon nanotube bundles under hydrostatic pressure with optical spectroscopy. Double-walled carbon nanotube films were prepared from fullerene peapods and characterized by HRTEM and optical spectroscopy. In comparison to single-walled carbon nanotubes, the pressure-induced redshifts of the optical transitions in the outer tubes are significantly smaller below $\sim$10 GPa, demonstrating the enhanced mechanical stability due to the inner tube already at low pressures. Anomalies at the critical pressure P$_d$$\approx$12 GPa signal the onset of the pressure-induced deformation of the tubular cross-sections. The value of P$_d$ is in very good agreement with theoretical predictions of the pressure-induced structural transitions in double-walled carbon nanotube bundles with similar average diameters.Comment: 6 pages, 4 figures; to appear in Phys. Rev.

A Raman study of the Charge-Density-Wave State in A0.3_{0.3}MoO3_3 (A = K,Rb)

We report a comparative Raman spectroscopic study of the quasi-one-dimensional charge-density-wave systems \ab (A = K, Rb). The temperature and polarization dependent experiments reveal charge-coupled vibrational Raman features. The strongly temperature-dependent collective amplitudon mode in both materials differ by about 3 cm, thus revealing the role of alkali atom. We discus the observed vibrational features in terms of charge-density-wave ground state accompanied by change in the crystal symmetry. A frequency-kink in some modes seen in \bb between T = 80 K and 100 K supports the first-order lock-in transition, unlike \rb. The unusually sharp Raman lines(limited by the instrumental response) at very low temperatures and their temperature evolution suggests that the decay of the low energy phonons is strongly influenced by the presence of the temperature dependent charge density wave gap.Comment: 13 pages, 7 figure

Crystal structure of LaTiO_3.41 under pressure

The crystal structure of the layered, perovskite-related LaTiO_3.41 (La_5Ti_5O_{17+\delta}) has been studied by synchrotron powder x-ray diffraction under hydrostatic pressure up to 27 GPa (T = 295 K). The ambient-pressure phase was found to remain stable up to 18 GPa. A sluggish, but reversible phase transition occurs in the range 18--24 GPa. The structural changes of the low-pressure phase are characterized by a pronounced anisotropy in the axis compressibilities, which are at a ratio of approximately 1:2:3 for the a, b, and c axes. Possible effects of pressure on the electronic properties of LaTiO_3.41 are discussed.Comment: 5 pages, 6 figure

Pressure-induced metallization and structural phase transition of the Mott-Hubbard insulator TiOBr

We investigated the pressure-dependent optical response of the low-dimensional Mott-Hubbard insulator TiOBr by transmittance and reflectance measurements in the infrared and visible frequency range. A suppression of the transmittance above a critical pressure and a concomitant increase of the reflectance are observed, suggesting a pressure-induced metallization of TiOBr. The metallic phase of TiOBr at high pressure is confirmed by the presence of additional excitations extending down to the far-infrared range. The pressure-induced metallization coincides with a structural phase transition, according to the results of x-ray powder diffraction experiments under pressure.Comment: 4 pages, 3 figure

Extremely Small Energy Gap in the Quasi-One-Dimensional Conducting Chain Compound SrNbO3.41_{3.41}

Resistivity, optical, and angle-resolved photoemission experiments reveal unusual one-dimensional electronic properties of highly anisotropic SrNbO$_{3.41}$. Along the conducting chain direction we find an extremely small energy gap of only a few meV at the Fermi level. A discussion in terms of typical 1D instabilities (Peierls, Mott-Hubbard) shows that neither seems to provide a satisfactory explanation for the unique properties of SrNbO$_{3.41}$.Comment: 4 pages, 3 figure

Signatures of polaronic excitations in quasi-one-dimensional LaTiO3.41_{3.41}

The optical properties of quasi-one-dimensional metallic LaTiO$_{3.41}$ are studied for the polarization along the $a$ and $b$ axes. With decreasing temperature modes appear along both directions suggestive for a phase transition. The broadness of these modes along the conducting axis might be due to the coupling of the phonons to low-energy electronic excitations across an energy gap. We observe a pronounced midinfrared band with a temperature dependence consistent with (interacting) polaron models. The polaronic picture is corroborated by the presence of strong electron-phonon coupling and the temperature dependence of the dc conductivity.Comment: 5 pages, 5 figure

Comparative magnetotransport and Tc measurements on kappa-(BEDT-TTF)2Cu(SCN)2 under pressure

We compare magnetotransport measurements under pressure on the organic superconductor $\kappa$-(BEDT-TTF)$_{2}$Cu(SCN)$_{2}$ with different pressure-media and discover that the results are pressure media dependent. This pressure-medium dependence is thought to originate from the difference in thermal contraction between the very soft and highly anisotropic sample and the isotropically contracting, but solid pressure medium, thus resulting in non-hydrostatic pressure on the sample. However, comparison of pressure measurements with different media reveals a pressure-medium independent correlation between the superconducting transition temperature, T$_{\rm c}$, and the size of the quasi 2-dimensional Fermi surface pocket and thus the quasi 2-dimensional carrier density in $\kappa$-(BEDT-TTF)$_{2}$Cu(SCN)$_{2}$. The observed pressure-induced increase in the quasi 2-dimensional carrier density can be interpreted as a transfer of carriers from quasi 1-dimensional Fermi surface sections, reminiscent of a mechanism in cuprate superconductors, where pressure is known to transfer carriers from the insulating charge reservoir layers into the conducting cuprate sheets.Comment: 11 pages, 6 figure