HYDROGEN BONDING IN betabeta-NITRO ALCOHOLS. III. PYRIDINE COMPLEXES

BETA -Nitro alcohols form stable 1:1 complexes with pyridine, examples of which were prepared. In solvents such as dichloromethane and carbon tetrachloride the complexes partially dissociate into their components. The dissociation constants for the equilibria were determined by infrared methods and may be used as a measure of the strength of the complex hydrogen bond. The dissociation constants decrease with increasing number of BETA -nitro groups. Some reactions of the pyridine complexes are described. (auth

The glass transition and crystallization kinetic studies on BaNaB9O15 glasses

Transparent glasses of BaNaB9O15 (BNBO) were fabricated via the conventional melt-quenching technique. The amorphous and the glassy nature of the as-quenched samples were respectively, confirmed by X-ray powder diffraction (XRD) and differential scanning calorimetry (DSC). The glass transition and crystallization parameters were evaluated under non-isothermal conditions using DSC. The correlation between the heating rate dependent glass transition and the crystallization temperatures was discussed and deduced the Kauzmann temperature for BNBO glass-plates and powdered samples. The values of the Kauzmann temperature for the plates and powdered samples were 776 K and 768 K, respectively. Approximation-free method was used to evaluate the crystallization kinetic parameters for the BNBO glass samples. The effect of the sample thickness on the crystallization kinetics of BNBO glasses was also investigated.Comment: 23 pages, 12 figure

Non-Classical Response from Quench-Cooled Solid Helium Confined in Porous Gold

We have investigated the non-classical response of solid 4He confined in porous gold set to torsional oscillation. When solid helium is grown rapidly, nearly 7% of the solid helium appears to be decoupled from the oscillation below about 200 mK. Dissipation appears at temperatures where the decoupling shows maximum variation. In contrast, the decoupling is substantially reduced in slowly grown solid helium. The dynamic response of solid helium was also studied by imposing a sudden increase in the amplitude of oscillation. Extended relaxation in the resonant period shift, suggesting the emergence of the pinning of low energy excitations, was observed below the onset temperature of the non-classical response. The motion of a dislocation or a glassy solid is restricted in the entangled narrow pores and is not likely responsible for the period shift and long relaxation

Glass transition temperature variation, cross-linking and structure in network glasses

We give general topological rules which very accurately predict the chemical trends in glass transition temperature $T_g$ variation as a function of cross-linking. In multicomponent glasses, these chemical trends permit to distinguish homogeneous compositions (random network) from inhomogeneous ones (local phase separation). The stochastic origin of the Gibbs-Di Marzio equation is predicted at low connectivity and the analytical expression of its parameter emerges naturally from the calculation.Comment: 5 pages, Revtex, accepted for publication in Europhysics Letters, 2 figures not included, available at http://www.gcr.jussieu.fr/matthieu.htm#Researc

Non-equilibrium Phase Transitions with Long-Range Interactions

This review article gives an overview of recent progress in the field of non-equilibrium phase transitions into absorbing states with long-range interactions. It focuses on two possible types of long-range interactions. The first one is to replace nearest-neighbor couplings by unrestricted Levy flights with a power-law distribution P(r) ~ r^(-d-sigma) controlled by an exponent sigma. Similarly, the temporal evolution can be modified by introducing waiting times Dt between subsequent moves which are distributed algebraically as P(Dt)~ (Dt)^(-1-kappa). It turns out that such systems with Levy-distributed long-range interactions still exhibit a continuous phase transition with critical exponents varying continuously with sigma and/or kappa in certain ranges of the parameter space. In a field-theoretical framework such algebraically distributed long-range interactions can be accounted for by replacing the differential operators nabla^2 and d/dt with fractional derivatives nabla^sigma and (d/dt)^kappa. As another possibility, one may introduce algebraically decaying long-range interactions which cannot exceed the actual distance to the nearest particle. Such interactions are motivated by studies of non-equilibrium growth processes and may be interpreted as Levy flights cut off at the actual distance to the nearest particle. In the continuum limit such truncated Levy flights can be described to leading order by terms involving fractional powers of the density field while the differential operators remain short-ranged.Comment: LaTeX, 39 pages, 13 figures, minor revision

Left Atrial scar assessment using imaging with isotropic spatial resolution and compressed sensing

Summary. We assess left atrial scar using late gadolinium enhancement (LGE) with isotropic spatial resolution of $1.4^3 mm^3$ by using highly accelerated LOST [1] reconstruction. Background. Atrial fibrillation (AF) is the most common sustained cardiac arrhythmia [2]. Pulmonary vein isolation (PVI) using radiofrequency (RF)-ablation is the leading treatment for AF. Recently, LGE imaging of the LA has been used to identify atrial wall scar due to RF-ablation [3]. However, current LGE methods have limited spatial resolution that substantially impact assessment of scar in the complex geometry of PVs and LA. In this study, we sought to utilize prospective random k-space sampling and LOST [1] for accelerated LGE imaging, where reduction in imaging time was traded-off for improved isotropic spatial-resolution. Methods. 23 patients with history of AF (6 females, $58.1 \pm 9.6$ years, 9 pre-PVI, 2 with history of PVI; 8 post-PVI; 3 with both pre and post-PVI) were recruited for this study. LGE images were acquired 10-to-20 minutes after bolus infusion of 0.2 mmol/kg Gd-DTPA. Free-breathing ECG-triggered navigator-gated inversion-recovery GRE sequences were used for all acquisitions ($TR/TE/ \alpha = 5.2/2.6ms/25°, FOV=320×320×100mm$). The PV inflow artifact reduction technique in [4] was also utilized. For each patient, a standard non-isotropic 3D LGE scan ($1.4×1.4×4.0mm^3$) and a 3-fold-accelerated highresolution 3D LGE scan ($1.4^3 mm^3$) were performed, with randomized acquisition order. For random undersampling, central k-space (45×35 in ky-kz) was fullysampled, edges randomly discarded, and phase reordering performed as in [5]. Acquisition times were ~4 mins assuming 100% scan-efficiency at 70bpm for both scans. All undersampled data were reconstructed offline using LOST [1]. LOST-reconstructed high-resolution, and standard LGE images were scored by two blinded readers for diagnostic value, presence of LGE(yes/no); and image quality in axial(Ax), coronal(Co) and sagittal (Sa) views (1=poor,4=excellent). Results. Three cases were declared non-diagnostic due to contrast-washout and imperfect inversion-time. LGE was visually present in 14 of the remaining 20 patients based on standard-LGE images, and 12 based on LOST-reconstructed ones (disagreement on one pre- and one postPVI patient). Figure 1 and 2 show comparisons of isotropic vs. non-isotropic LGE images in two patients. Image scores for LOST-LGE: $Ax=2.90 \pm 0.70, Sa=3.33 \pm 0.66, Co=3.00 \pm 0.63$; and standard LGE: $Ax=3.76 \pm 0.54, Sa=2.48 \pm 0.60, Co=2.24 \pm 0.44$, where differences were significant in all views. Conclusions. LOST allows isotropic spatial-resolution in LGE for assessment of LA and PV scar. Isotropic resolution allows reformatting LGE images in any orientation and facilitates assessment of scar. Further clinical study is needed to assess if the improved spatial resolution will impact the diagnostic interpretation of data

Estimation of the solubility parameters of model plant surfaces and agrochemicals: a valuable tool for understanding plant surface interactions

Background Most aerial plant parts are covered with a hydrophobic lipid-rich cuticle, which is the interface between the plant organs and the surrounding environment. Plant surfaces may have a high degree of hydrophobicity because of the combined effects of surface chemistry and roughness. The physical and chemical complexity of the plant cuticle limits the development of models that explain its internal structure and interactions with surface-applied agrochemicals. In this article we introduce a thermodynamic method for estimating the solubilities of model plant surface constituents and relating them to the effects of agrochemicals. Results Following the van Krevelen and Hoftyzer method, we calculated the solubility parameters of three model plant species and eight compounds that differ in hydrophobicity and polarity. In addition, intact tissues were examined by scanning electron microscopy and the surface free energy, polarity, solubility parameter and work of adhesion of each were calculated from contact angle measurements of three liquids with different polarities. By comparing the affinities between plant surface constituents and agrochemicals derived from (a) theoretical calculations and (b) contact angle measurements we were able to distinguish the physical effect of surface roughness from the effect of the chemical nature of the epicuticular waxes. A solubility parameter model for plant surfaces is proposed on the basis of an increasing gradient from the cuticular surface towards the underlying cell wall. Conclusions The procedure enabled us to predict the interactions among agrochemicals, plant surfaces, and cuticular and cell wall components, and promises to be a useful tool for improving our understanding of biological surface interactions