2,629 research outputs found
Triphilic ionic-liquid mixtures: fluorinated and non-fluorinated aprotic ionic-liquid mixtures
We present here the possibility of forming triphilic mixtures from alkyl- and fluoroalkylimidazolium ionic liquids, thus, macroscopically homogeneous mixtures for which instead of the often observed two domainspolar and nonpolarthree stable microphases are present: polar, lipophilic, and fluorous ones. The fluorinated side chains of the cations indeed self-associate and form domains that are segregated from those of the polar and alkyl domains. To enable miscibility, despite the generally preferred macroscopic separation between fluorous and alkyl moieties, the importance of strong hydrogen bonding is shown. As the long-range structure in the alkyl and fluoroalkyl domains is dependent on the composition of the liquid, we propose that the heterogeneous, triphilic structure can be easily tuned by the molar ratio of the components. We believe that further development may allow the design of switchable, smart liquids that change their properties in a predictable way according to their composition or even their environment
Effect of aggregation on chromophore structure in allophycocyanin studied by resonance CARS-spectroscopy
Influence of aggregation and linker proteins on chromophore structure in allophycocyanin (Mastigocladus laminosus).
High resolution millimeter wave SAR interferometry
High resolution millimeter wave synthetic aperture radar (SAR) interferometry is presented using the MEMPHIS multi-baseline InSAR system. A complete processing chain is used to generate digital elevation models starting from the radar raw data. A deeper focus is laid on the phase unwrapping step, which is achieved using the multi-baseline properties of the system. In November 2006, an experiment was realized including two test sites in Switzerland; the actual results are presented and discussed
Processing of MEMPHIS millimeter wave multi-baseline InSAR data
This paper presents a processing method for multi-baseline interferometric data acquired with the MEMPHIS airborne sensor. The processing method ingests the SAR raw data from each receiver and extends up to the generation of digital elevation models (DEMs). Critical steps include the correction of the azimuth phase undulations, the multi- baseline processing and the phase-to-DEM conversion. Methods for resolving the various hurdles were adapted to the MEMPHIS sensor and are presented here. The results obtained for a data take over a test site near Zurich, Switzerland are shown; these results are in a good agreement with comparable LIDAR products
Technology Needs Assessment of an Atmospheric Observation System for Multidisciplinary Air Quality/Meteorology Missions, Part 2
The technology advancements that will be necessary to implement the atmospheric observation systems are considered. Upper and lower atmospheric air quality and meteorological parameters necessary to support the air quality investigations were included. The technology needs were found predominantly in areas related to sensors and measurements of air quality and meteorological measurements
Mitochondrial portrait of the Cabo Verde archipelago: the Senegambian outpost of Atlantic slave trade
In order to study the matrilineal genetic composition in Cabo Verde (Republic of Cape Verde), an archipelago that used to serve as a Portuguese entrepôt of the Atlantic slave trade, we have analysed a total of 292 mtDNAs sampled from the seven inhabited islands for the hypervariable segment I (HVS-I) and some characteristic RFLPs of the coding regions. The different settlement history of the northwestern group of the islands is well reflected in the mtDNA pool. The total Cabo Verde sample clearly displays the characteristic mitochondrial features of the Atlantic fringe of western Africa and testifies to almost no mitochondrial input from the Portuguese colonizers.info:eu-repo/semantics/publishedVersio
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Performance prediction for complex parallel applications
Today`s massively parallel machines are typically message-passing systems consisting of hundreds or thousands of processors. Implementing parallel applications efficiently in this environment is a challenging task, and poor parallel design decisions can be expensive to correct. Tools and techniques that allow the fast and accurate evaluation of different parallelization strategies would significantly improve the productivity of application developers and increase throughput on parallel architectures. This paper investigates one of the major issues in building tools to compare parallelization strategies: determining what type of performance models of the application code and of the computer system are sufficient for a fast and accurate comparison of different strategies. The paper is built around a case study employing the Performance Prediction Tool (PerPreT) to predict performance of the Parallel Spectral Transform Shallow Water Model code (PSTSWM) on the Intel Paragon. 13 refs., 6 tabs
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