Representative surface snow density on the East Antarctic Plateau

Surface mass balances of polar ice sheets are essential to estimate the contribution of ice sheets to sea level rise. Uncertain snow and firn densities lead to significant uncertainties in surface mass balances, especially in the interior regions of the ice sheets, such as the East Antarctic Plateau (EAP). Robust field measurements of surface snow density are sparse and challenging due to local noise. Here, we present a snow density dataset from an overland traverse in austral summer 2016/17 on the Dronning Maud Land plateau. The sampling strategy using 1 m carbon fiber tubes covered various spatial scales, as well as a high-resolution study in a trench at 79∘ S, 30∘ E. The 1 m snow density has been derived volumetrically, and vertical snow profiles have been measured using a core-scale microfocus X-ray computer tomograph. With an error of less than 2 %, our method provides higher precision than other sampling devices of smaller volume. With four spatially independent snow profiles per location, we reduce the local noise and derive a representative 1 m snow density with an error of the mean of less than 1.5 %. Assessing sampling methods used in previous studies, we find the highest horizontal variability in density in the upper 0.3 m and therefore recommend the 1 m snow density as a robust measure of surface snow density in future studies. The average 1 m snow density across the EAP is 355 kg m−3, which we identify as representative surface snow density between Kohnen Station and Dome Fuji. We cannot detect a temporal trend caused by the temperature increase over the last 2 decades. A difference of more than 10 % to the density of 320 kg m−3 suggested by a semiempirical firn model for the same region indicates the necessity for further calibration of surface snow density parameterizations. Our data provide a solid baseline for tuning the surface snow density parameterizations for regions with low accumulation and low temperatures like the EAP

Spatial Distribution of Crusts in Antarctic and Greenland Snowpacks and Implications for Snow and Firn Studies

The occurrence of snowpack features has been used in the past to classify environmental regimes on the polar ice sheets. Among these features are thin crusts with high density, which contribute to firn stratigraphy and can have significant impact on firn ventilation as well as on remotely inferred properties like accumulation rate or surface mass balance. The importance of crusts in polar snowpack has been acknowledged, but nonetheless little is known about their large-scale distribution. From snow profiles measured by means of microfocus X-ray computer tomography we created a unique dataset showing the spatial distribution of crusts in snow on the East Antarctic Plateau as well as in northern Greenland including a measure for their local variability. With this method, we are able to find also weak and oblique crusts, to count their frequency of occurrence and to measure the high-resolution density. Crusts are local features with a small spatial extent in the range of tens of meters. From several profiles per sampling site we are able to show a decreasing number of crusts in surface snow along a traverse on the East Antarctic Plateau. Combining samples from Antarctica and Greenland with a wide range of annual accumulation rate, we find a positive correlation (R2 = 0.89) between the logarithmic accumulation rate and crusts per annual layer in surface snow. By counting crusts in two Antarctic firn cores, we can show the preservation of crusts with depth and discuss their temporal variability as well as the sensitivity to accumulation rate. In local applications we test the robustness of crusts as a seasonal proxy in comparison to chemical records like impurities or stable water isotopes. While in regions with high accumulation rates the occurrence of crusts shows signs of seasonality, in low accumulation areas dating of the snowpack should be done using a combination of volumetric and stratigraphic elements. Our data can bring new insights for the study of firn permeability, improving of remote sensing signals or the development of new proxies in snow and firn core research

Photocurrent dynamics in a poly(phenylene vinylene)-based photorefractive composite,” Phys

All parameters describing the charge carrier dynamics in a poly͑phenylene vinylene͒-based photorefractive ͑PR͒ composite relevant to PR grating dynamics were determined using photoconductivity studies under various illumination conditions. In particular, the values of the coefficients for trap filling and recombination of charges with ionized sensitizer molecules could be extracted independently. It is concluded that the PR growth time without preillumination is mostly determined by the competition between deep trap filling and recombination with ionized sensitizer molecules. Further, the pronounced increase in PR speed upon homogeneous preillumination ͑gating͒ as reported recently is quantitatively explained by deep trap filling

The role of sublimation as a driver of climate signals in the water isotope content of surface snow: Laboratory and field experimental results

Ice core water isotope records from Greenland and Antarctica are a valuable proxy for paleoclimate reconstruction, yet the processes influencing the climate signal stored in the isotopic composition of the snow are being challenged and revisited. Apart from precipitation input, post-depositional processes such as wind-driven redistribution and vapor–snow exchange processes at and below the surface are hypothesized to contribute to the isotope climate signal subsequently stored in the ice. Recent field studies have shown that surface snow isotopes vary between precipitation events and co-vary with vapor isotopes, which demonstrates that vapor–snow exchange is an important driving mechanism. Here we investigate how vapor–snow exchange processes influence the isotopic composition of the snowpack. Controlled laboratory experiments under forced sublimation show an increase in snow isotopic composition of up to 8 ‰ δ18O in the uppermost layer due to sublimation, with an attenuated signal down to 3 cm snow depth over the course of 4–6 d. This enrichment is accompanied by a decrease in the second-order parameter d-excess, indicating kinetic fractionation processes. Our observations confirm that sublimation alone can lead to a strong enrichment of stable water isotopes in surface snow and subsequent enrichment in the layers below. To compare laboratory experiments with realistic polar conditions, we completed four 2–3 d field experiments at the East Greenland Ice Core Project site (northeast Greenland) in summer 2019. High-resolution temporal sampling of both natural and isolated snow was conducted under clear-sky conditions and demonstrated that the snow isotopic composition changes on hourly timescales. A change of snow isotope content associated with sublimation is currently not implemented in isotope-enabled climate models and is not taken into account when interpreting ice core isotopic records. However, our results demonstrate that post-depositional processes such as sublimation contribute to the climate signal recorded in the water isotopes in surface snow, in both laboratory and field settings. This suggests that the ice core water isotope signal may effectively integrate across multiple parameters, and the ice core climate record should be interpreted as such, particularly in regions of low accumulation.publishedVersio

Evidence of Isotopic Fractionation During Vapor Exchange Between the Atmosphere and the Snow Surface in Greenland

Several recent studies from both Greenland and Antarctica have reported significant changes in the water isotopic composition of near‐surface snow between precipitation events. These changes have been linked to isotopic exchange with atmospheric water vapor and sublimation‐induced fractionation, but the processes are poorly constrained by observations. Understanding and quantifying these processes are crucial to both the interpretation of ice core climate proxies and the formulation of isotope‐enabled general circulation models. Here, we present continuous measurements of the water isotopic composition in surface snow and atmospheric vapor together with near‐surface atmospheric turbulence and snow‐air latent and sensible heat fluxes, obtained at the East Greenland Ice‐Core Project drilling site in summer 2016. For two 4‐day‐long time periods, significant diurnal variations in atmospheric water isotopologues are observed. A model is developed to explore the impact of this variability on the surface snow isotopic composition. Our model suggests that the snow isotopic composition in the upper subcentimeter of the snow exhibits a diurnal variation with amplitudes in δ18O and δD of ~2.5‰ and ~13‰, respectively. As comparison, such changes correspond to 10–20% of the magnitude of seasonal changes in interior Greenland snow pack isotopes and of the change across a glacial‐interglacial transition. Importantly, our observation and model results suggest, that sublimation‐induced fractionation needs to be included in simulations of exchanges between the vapor and the snow surface on diurnal timescales during summer cloud‐free conditions in northeast Greenland

Near-infrared sensitivity enhancement of photorefractive polymer composites by pre-illumination

Among the various applications for reversible holographic storage media, a particularly interesting one is time-gated holographic imaging (TGHI). This technique could provide a noninvasive medical diagnosis tool, related to optical coherence tomography. In this technique, biological samples are illuminated within their transparency windowwith near-infrared light, and information about subsurface features is obtained by a detection method that distinguishes between reflected photons originating from a certain depth and those scattered from various depths. Such an application requires reversible holographic storage media with very high sensitivity in the near-infrared. Photorefractive materials, in particular certain amorphous organic systems, are in principle promising candidate media, but their sensitivity has so far been too low, mainly owing to their long response times in the near-infrared. Here we introduce an organic photorefractive material—a composite based on the poly(arylene vinylene) copolymer TPD-PPV—that exhibits favourable near-infrared characteristics. We show that pre-illumination of this material at a shorter wavelength before holographic recording improves the response time by a factor of 40. This process was found to be reversible. We demonstrate multiple holographic recording with this technique at video rate under practical conditions