59 research outputs found

    Stable isotope dilution assay for the accurate determination of mycotoxins in maize by UHPLC-MS/MS

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    A fast, easy-to-handle and cost-effective analytical method for 11 mycotoxins currently regulated in maize and other cereal-based food products in Europe was developed and validated for maize. The method is based on two extraction steps using different acidified acetonitrile–water mixtures. Separation is achieved using ultrahigh-performance liquid chromatography (UHPLC) by a linear water–methanol gradient. After electrospray ionisation, tandem mass spectrometric detection is performed in dynamic multiple reaction monitoring mode. Since accurate mass spectrometric quantification is hampered by matrix effects, uniformly [13C]-labelled mycotoxins for each of the 11 compounds were added to the sample extracts prior to UHPLC-MS/MS analysis. Method performance parameters were obtained by spiking blank maize samples with mycotoxins before as well as after extraction on six levels in triplicates. The twofold extraction led to total recoveries of the extraction steps between 97% and 111% for all target analytes, including fumonisins. The [13C]-labelled internal standards efficiently compensated all matrix effects in electrospray ionisation, leading to apparent recoveries between 88% and 105% with reasonable additional costs. The relative standard deviations of the whole method were between 4% and 11% for all analytes. The trueness of the method was verified by the measurement of several maize test materials with well-characterized concentrations. In conclusion, the developed method is capable of determining all regulated mycotoxins in maize and presuming similar matrix effects and extraction recovery also in other cereal-based foods

    Buyer Behavior in Personalized Shopping Environments

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    One of the most exciting aspects of electronic shopping environments (such as online stores) is that they allow firms to create personalized customer interfaces. That is, user interfaces of commercial web sites can be designed to be adaptive to the specific interests, needs, and preferences of individual shoppers at particula

    When Rational Sellers Face Nonrational Buyers: Evidence from Herding on eBay

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    With a little help from my peers

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    \u3cp\u3eHow can recommender interfaces help users to adopt new behaviors? In the behavioral change literature, nudges and norms are studied to understand how to convince people to take action (e.g. towel re-use is boosted when stating that '75% of hotel guests' do so), but what is advised is typically not personalized. Most recommender systems know what to recommend in a personalized way, but not much research has considered how to present such advice to help users to change their current habits. We examine the value of presenting normative messages (e.g. '75% of users do X') based on actual user data in a personalized energy recommender interface called 'Saving Aid'. In a study among 207 smart thermostat owners, we compared three different normative explanations ('Global', 'Similar', and 'Experienced' norm rates) to a non-social baseline ('kWh savings'). Although none of the norms increased the total number of chosen measures directly, we show evidence that the effect of norms seems to be mediated by the perceived feasibility of the measures. Also, how norms were presented (i.e. specific source, adoption rate) affected which measures were chosen within our Saving Aid interface.\u3c/p\u3
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