10 research outputs found

    N-Phosphorylated Azolylidenes: Novel Ligands for Dinuclear Complexes of Coinage Metals

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    Dinuclear silver(I) complexes with bridging Nphosphorylated azolylidene ligands have been synthesized. Subsequent transfer of the ligands to other group 11 metal centers (Cu, Au) has been accomplished, highlighting the usefulness of the silver complexes as an easy to handle, air- and moisture-stable source of these ligands. Preliminary results indicate that dinuclear copper(I) complexes with Nphosphorylated imidazolylidene ligands display notable catalytic efficiency in nitrene transfer reactions

    The Thermodynamic Properties of Phosphorus and Solid Binary Phosphides

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    Chemical Reactions at Isolated Single-Sites Inside Metal–Organic Frameworks

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