10 research outputs found
N-Phosphorylated Azolylidenes: Novel Ligands for Dinuclear Complexes of Coinage Metals
Dinuclear silver(I) complexes with bridging Nphosphorylated
azolylidene ligands have been synthesized.
Subsequent transfer of the ligands to other group 11 metal
centers (Cu, Au) has been accomplished, highlighting the
usefulness of the silver complexes as an easy to handle, air- and
moisture-stable source of these ligands. Preliminary results
indicate that dinuclear copper(I) complexes with Nphosphorylated
imidazolylidene ligands display notable
catalytic efficiency in nitrene transfer reactions