22 research outputs found
Dioxygen Copper Reactivity: Generation, Characterisation and Reactivity of a Hydroperoxo-Dicopper(II) Complex
No full textLigand Exchange of Manganese(II) Macrocyclic Pentaamine Complexes: Synthesis, Characterization, and Single-Crystal X-ray Structure Determination
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A Series of Rutile Networks Constructed by Dinuclear Transition Metal Units and 5-Carboxyl-1-carboxymethyl-3-oxidopyridimium
No full textInvestigation of the Effect of Oxy Bridging Groups in Dinuclear Zn(II) Complexes that Catalyze the Cleavage of a Simple Phosphate Diester RNA Analogue
No full textSpectral, thermal and biological activity studies on ruthenium(II) complexes with some pyridylamines
No full textUnique Manganese Phosphorus Complex with a Mn5P7 Core: Synthesis, Molecular Structure, and Magnetic Properties
No full textThe manganese phosphorus cluster [Mn5{N(SiMe3)2}{μ4-PSiiPr3}2{μ-P(H)SiiPr3}5] (1) containing an unusual Mn5P7 core structure and three short Mn-Mn distances was obtained from the reaction of Mn{N(SiMe3)2}2 with H2PSiiPr3. Quantum chemical investigations indicated the presence of comparably strong intramolecular antiferromagnetic interactions leading to a total S ) 5/2 spin ground state, which was confirmed by magnetic measurements
Iron(II) Polyamine Chemistry: Variation of Spin State and Coordination Number in Solid State and Solution with Iron(II) Tris(2-pyridylmethyl)amine Complexes
No full textAerobic Catechol Oxidation Catalyzed by a Bis(m-oxo)dimanganese(III, III) Complex via a Manganese(II)-Semiquinonate Complex
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