Valorization of a high-acidity residual oil generated in the waste cooking oils recycling industries

A sludge fraction is obtained from the industries which recycle cooking oil and this sludge contains a large amount of oil with an extremely high acidity (> 60%). In this work, we propose a scheme for methyl ester production from this residual oil consisting of the esterification of the free fatty acids followed by the transesterification of the remaining triglycerides. Esterifications were carried out with different methanol:oil molar ratios, and various catalysts in different weight ratios. The results revealed that homogeneous catalysts produced higher yields than heterogeneous ones in the esterification reaction. With the aim of improving the process, a previous triglyceride hydrolysis was assayed using lipases from Candida rugosa. Finally, the 3-stage process was performed under the most favorable conditions for each stage obtaining 84% wt. fatty acid methyl esters, which shows the potential of this residual oil as a source of biodiesel.This work was supported by the European Union Funds under grant LIFE 13-Bioseville ENV/1113. The authors are grateful to Grupo BIOSEL for supplying the residual oil

Determination of the SO/PHI-HRT wavefront degradation using multiple defocused images

The Polarimetric and Helioseismic Imager on board the Solar Orbiter mission (SO/PHI) offers refocusing capabilities to cope with the strongly varying thermal environment of the optical system along the spacecraft's elliptical orbit. The series of images recorded during in-flight focus calibrations can be employed for phase diversity analyses. In this work we infer the wavefront degradation caused by the thermo-optical effects in the High Resolution Telescope (HRT) from images taken during the fine and coarse focus scans performed in the commissioning phase of the instrument. The difference between these two series of images are mainly related to the employed defocused step (smaller for the fine scans) and the signal-to-noise ratio (higher for the coarse scans). We use the retrieved wavefronts to reconstruct the original scene observed during the calibration of the instrument. We applied a generalized phase diversity algorithm that allowed us to use several images taken with different amounts of defocus to sense the wavefront degradation caused by the instrument. The algorithm also uses information from both the inferred wavefront and the series of images to restore the solar scene We find that most of the retrieved Zernike coefficients tend to converge to the same value when increasing the number of images employed for PD for both the fine and the coarse focusing scans. The restored scenes also show signs of convergence, and the merit function is minimized more as $K$ increases. Apart from a defocus, the inferred wavefronts are consistent for the two datasets ($For the fine scan images, the quiet-sun contrast improves from$4.5\,$for the original focused image up to about$10\,$. For the coarse scan images, the contrast of the restored scene is as high as$11\,$