66 research outputs found
Observations of transient high temperature vortical microstructures in solids during adiabatic shear banding
By using a unique infrared high-speed camera especially constructed for recording highly transient temperature fields at the microscale, we are able to reveal the spatial and temporal microstructure within dynamically growing shear bands in metals. It is found that this structure is highly nonuniform and possesses a transient, short range periodicity in the direction of shear band growth in the form of an array of intense "hot spots" reminiscent of the well-known, shear-induced hydrodynamic instabilities in fluids. This is contrary to the prevailing classical view that describes the deformations and the temperatures within shear bands as being essentially one-dimensional fields. These observations are also reminiscent of the nonuniform structure of localized shear regions believed to exist, at an entirely different length scale, in the earth's lower crust and upper mantle
Real-time Measurement of Stress and Damage Evolution During Initial Lithiation of Crystalline Silicon
Crystalline to amorphous phase transformation during initial lithiation in
(100) silicon-wafers is studied in an electrochemical cell with lithium metal
as the counter and reference electrode. It is demonstrated that severe stress
jumps across the phase boundary lead to fracture and damage, which is an
essential consideration in designing silicon based anodes for lithium ion
batteries. During initial lithiation, a moving phase boundary advances into the
wafer starting from the surface facing the lithium electrode, transforming
crystalline silicon into amorphous LixSi. The resulting biaxial compressive
stress in the amorphous layer is measured in situ and it was observed to be ca.
0.5 GPa. HRTEM images reveal that the crystalline-amorphous phase boundary is
very sharp, with a thickness of ~ 1 nm. Upon delithiation, the stress rapidly
reverses, becomes tensile and the amorphous layer begins to deform plastically
at around 0.5 GPa. With continued delithiation, the yield stress increases in
magnitude, culminating in sudden fracture of the amorphous layer into
micro-fragments and the cracks extend into the underlying crystalline silicon.Comment: 12 pages, 5 figure
Effect of loading rate on fracture morphology in a high strength ductile steel
Fracture experiments in a high-strength ductile steel (2.3Ni-1.3Cr-0.17C) were conducted under static and dynamic loading conditions in a three-point bend and a one-point bend configurations. A qualitative description of the influence of loading rate on the microscopic features of the fracture surfaces and their role in the fracture initiation process was considered. The fracture surfaces consist of tunneled region and shear lips. The size of the shear lips increases wit increasing loading rate and is characterized by microvoids and cell structures. The tunneled region consists of large voids and micro-voids that coalesce by impingement. At high loading rates, localized molten zones are observed at the tunnel-shear lip interface
On plastic deformation and fracture in Si films during electrochemical lithiation/delithiation cycling
An in situ study of deformation, fracture, and fatigue behavior of silicon as
a lithium-ion battery electrode material is presented. Thin films (100-200 nm)
of silicon are cycled in a half-cell configuration with lithium metal foil as
counter/reference electrode, with 1M lithium hexafluorophosphate in ethylene
carbonate, diethylene carbonate, dimethyl carbonate solution (1:1:1, wt.%) as
electrolyte. Stress evolution in the Si thin-film electrodes during
electrochemical lithiation and delithiation is measured by monitoring the
substrate curvature using the multi-beam optical sensing method. The stress
measurements have been corrected for contributions from residual stress arising
from sputter-deposition. An indirect method for estimating the potential errors
due to formation of the solid-electrolyte-interphase layer and surface charge
on the stress measurements was presented. The films undergo extensive inelastic
deformation during lithiation and delithiation. The peak compressive stress
during lithiation was 1.48 GPa. The stress data along with the electron
microscopy observations are used to estimate an upper bound fracture resistance
of lithiated Si, which is approximately 9-11 J/m^2. Fracture initiation and
crack density evolution as a function of cycle number is also reported.Comment: 25 pages, 9 figure
Quantifying Capacity Loss due to Solid-Electrolyte-Interphase Layer Formation on Silicon Negative Electrodes in Lithium-ion Batteries
Charge lost per unit surface area of a silicon electrode due to the formation
of solid-electrolyte-interphase (SEI) layer during initial lithiation was
quantified, and the species that constitute this layer were identified. Coin
cells made with Si thin-film electrodes were subjected to a combination of
galvanostatic and potentiostatic lithiation and delithiation cycles to
accurately measure the capacity lost to SEI-layer formation. While the planar
geometry of amorphous thin films allows accurate calculation of surface area,
creation of additional surface by cracking was prevented by minimizing the
thickness of the Si film. The cycled electrodes were analyzed with X-ray
photoelectron spectroscopy to characterize the composition of the SEI layer.
The charge lost due to SEI formation measured from coin cell experiments was
found to be in good agreement with the first-cycle capacity loss during the
initial lithiation of a Si (100) crystal with planar geometry. The methodology
presented in this work is expected to provide a useful practical tool for
battery-material developers in estimating the expected capacity loss due to
first cycle SEI-layer formation and in choosing an appropriate particle size
distribution that balances mechanical integrity and the first cycle capacity
loss in large volume expansion electrodes for lithium-ion batteries.Comment: 15 pages, 9 figures; Journal of Power Sources, 201
Stress Evolution in Composite Silicon Electrodes during Lithiation/Delithiation
We report real-time average stress measurements on composite silicon
electrodes made with two different binders [Carboxymethyl cellulose (CMC), and
polyvinylidene fluoride (PVDF)] during electrochemical lithiation and
delithiation. During galvanostatic lithiation at very slow rates, the stress in
a CMC-based electrode becomes compressive and increases to 70 MPa, where it
reaches a plateau and increases slowly thereafter with capacity. The PVDF-based
electrode exhibits similar behavior, although with lower peak compressive
stress of about 12 MPa. These initial experiments indicate that the stress
evolution in a Si composite electrode depends strongly on the mechanical
properties of the binder. Stress data obtained from a series of
lithiation/delithiation cycles suggests plasticity induced irreversible shape
changes in contacting Si particles, and as a result, the stress response of the
system during any given lithiation/delithiation cycle depends on the cycling
history of the electrode. While these results constitute the first in-situ
stress measurements on composite Si electrodes during electrochemical cycling,
the diagnostic technique described herein can be used to assess the mechanical
response of a composite electrode made with other active material/binder
combinations.Comment: 22 pages, 8 figure
Observations of transient high temperature vortical microstructures in solids during adiabatic shear banding
A. Venkert Effect of Loading Rate on Fracture Morphology in a High Strength Ductile Steel
Fracture experiments in a high-strength ductile stee
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