Comparative Evaluation on the Coupled Fracture Characteristics for Longmaxi Anisotropic Shale

AbstractThe shale fracture characteristics are important for realizing the complex hydraulic fracture network, predicting wellbore fracture pressure, and optimizing wellbore trajectory and the rock fragmentation efficiency. Through a three-point bending test of notched semicircular specimens of Longmaxi shale, the coupled relationship of mode-I fracture toughness (Kic), peak fracture force (Pmax), energy release rate (GI), applied work (W), and loading rate was studied by using kernel density analysis method. The results showed that the dynamic characteristics of force-displacement curve exhibited obvious loading angle dependence, including two types of the “deformation accumulation-brittleness” and “deformation accumulation-brittleness-plasticity.” The Kic and GI increased linearly with Pmax increasing. With the increasing of the loading angle, the dispersion degree of Pmax, Kic, GI, and W all increased. The GI increased nonlinearly with the increasing of Kic. With the increasing of the loading rate, the Kic basically increased linearly. The dynamic Kic under static and quasistatic conditions had strong anisotropy. At the high loading rate, the anisotropy index gradually decreased as the loading rate increasing. The results have significant implications for the design of hydraulic fracturing and the exact fracture control of Longmaxi shale

A Review of the Evaluation, Control, and Application Technologies for Drill String Vibrations and Shocks in Oil and Gas Well

Drill string vibrations and shocks (V&S) can limit the optimization of drilling performance, which is a key problem for trajectory optimizing, wellbore design, increasing drill tools life, rate of penetration, and intelligent drilling. The directional wells and other special trajectory drilling technologies are often used in deep water, deep well, hard rock, and brittle shale formations. In drilling these complex wells, the cost caused by V&S increases. According to past theories, indoor experiments, and field studies, the relations among ten kinds of V&S, which contain basic forms, response frequency, and amplitude, are summarized and discussed. Two evaluation methods are compared systematically, such as theoretical and measurement methods. Typical vibration measurement tools are investigated and discussed. The control technologies for drill string V&S are divided into passive control, active control, and semiactive control. Key methods for and critical equipment of three control types are compared. Based on the past development, a controlling program of drill string V&S is devised. Application technologies of the drill string V&S are discussed, such as improving the rate of penetration, controlling borehole trajectory, finding source of seismic while drilling, and reducing the friction of drill string. Related discussions and recommendations for evaluating, controlling, and applying the drill string V&S are made

A Review of the Evaluation, Control, and Application Technologies for Drill String Vibrations and Shocks in Oil and Gas Well

Drill string vibrations and shocks (V&S) can limit the optimization of drilling performance, which is a key problem for trajectory optimizing, wellbore design, increasing drill tools life, rate of penetration, and intelligent drilling. The directional wells and other special trajectory drilling technologies are often used in deep water, deep well, hard rock, and brittle shale formations. In drilling these complex wells, the cost caused by V&S increases. According to past theories, indoor experiments, and field studies, the relations among ten kinds of V&S, which contain basic forms, response frequency, and amplitude, are summarized and discussed. Two evaluation methods are compared systematically, such as theoretical and measurement methods. Typical vibration measurement tools are investigated and discussed. The control technologies for drill string V&S are divided into passive control, active control, and semiactive control. Key methods for and critical equipment of three control types are compared. Based on the past development, a controlling program of drill string V&S is devised. Application technologies of the drill string V&S are discussed, such as improving the rate of penetration, controlling borehole trajectory, finding source of seismic while drilling, and reducing the friction of drill string. Related discussions and recommendations for evaluating, controlling, and applying the drill string V&S are made

3D Numerical Simulation and Experiment Validation of Dynamic Damage Characteristics of Anisotropic Shale for Percussive-Rotary Drilling with a Full-Scale PDC Bit

The lower rate of penetration (ROP) is one of the key technical difficulties during drilling of shale reservoirs. Percussive-rotary drilling (PRD) is crucial for increasing ROP. One of the core problems of ROP optimization for PRD are the dynamic damage characteristics of rock fragmentation. By considering the dynamic drilling parameters, a new model for estimating the PRD with a full-scale polycrystalline diamond compact (PDC) bit is established. The mechanical parameters of shale are measured by a wave velocity method. Rock damage characteristics are simulated by using the finite element method. The numerical simulation model is verified by the actual drilling case in LMX shale reservoir in Sichuan (China). The results indicate that rock element damage occurs along the direction of maximum principal stress. The order of decreasing rock damage rate is impact-static load, static load and impact load. When the impact load has the same peak value, and the rock elements in contact with the cutters obtain more energy with load frequency increasing. The rock fragmentation efficiency under a sine wave is higher than rectangular and pulse waves. The rock can obtain more energy to be broken with the increasing impact load duration and peak values. When the impact-static load goes over the rock damage threshold value, the higher the peak value of the impact load is, the more energy the rock will obtain. The higher the lateral vibration amplitude of the drill bit, the lower the efficiency of rock fragmentation. Repetitions of drill bit axial vibration at one indentation point will reduce the ROP, and the axial vibration energy of the drill bit is consumed. Therefore, a small lateral movement and reasonable axial vibration frequency increase the rock breaking efficiency. The ROP was increased through the suppression of drill string and the application of vibration. The study results can be used in the optimization designs of bit trajectory and ROP for PRD tools

The Experimental Investigation of Longmaxi Shale Dynamic Parameters under Water-Based Mud Soaking

Shale damage investigation is important in shale gas development. This paper is concerned with the experimental identification of ultrasonic wave velocities and damage mechanic parameters of Longmaxi shale under water-based mud soaking and confining pressure loading. The wave velocities increased with increasing confining pressure, while wave velocities decreased with increasing soaking time. The anisotropy of Young’s modulus decreases when confining pressure increases. As soaking time increases, the anisotropy coefficient increases. As soaking time and confining pressure rise, the damage parameters also show complex changes. The results are beneficial for shale gas development.Peer Reviewe

Self-triggered thermoelectric nanoheterojunction for cancer catalytic and immunotherapy

Abstract The exogenous excitation requirement and electron-hole recombination are the key elements limiting the application of catalytic therapies. Here a tumor microenvironment (TME)-specific self-triggered thermoelectric nanoheterojunction (Bi0.5Sb1.5Te3/CaO2 nanosheets, BST/CaO2 NSs) with self-built-in electric field facilitated charge separation is fabricated. Upon exposure to TME, the CaO2 coating undergoes rapid hydrolysis, releasing Ca2+, H2O2, and heat. The resulting temperature difference on the BST NSs initiates a thermoelectric effect, driving reactive oxygen species production. H2O2 not only serves as a substrate supplement for ROS generation but also dysregulates Ca2+ channels, preventing Ca2+ efflux. This further exacerbates calcium overload-mediated therapy. Additionally, Ca2+ promotes DC maturation and tumor antigen presentation, facilitating immunotherapy. It is worth noting that the CaO2 NP coating hydrolyzes very slowly in normal cells, releasing Ca2+ and O2 without causing any adverse effects. Tumor-specific self-triggered thermoelectric nanoheterojunction combined catalytic therapy, ion interference therapy, and immunotherapy exhibit excellent antitumor performance in female mice

Enhanced Photocatalytic Activities for Degradation of Dyes and Drugs by Crystalline Bismuth Ferrite-Modified Graphene Hybrid Aerogel

Industrial wastewater contains diverse toxic dyes and drugs, which pollute the environment and poison creatures. Utilizing photocatalysts has been accepted to be an effective method to degrade water pollutions using solar light. Crystalline bismuth ferrite (Bi2Fe4O9) with a band gap of 1.9–2.0 eV is expected to be one of the most promising candidates for photocatalysts in the visible light region. Amorphous graphene is also a promising candidate as a photocatalyst owing to its excellent electronic and optical properties. Herein, a composite of Bi2Fe4O9/graphene aerogels (GAs) was prepared with a two-step hydrothermal method. The prepared Bi2Fe4O9 powders were confirmed to be successfully doped into GAs and evenly dispersed between graphene sheets. The Bi2Fe4O9/GA composite was utilized to perform photodegradation for organic dyes and antibiotic drugs under visible light irradiation, yielding efficiencies of 90.22%, 92.3%, 71.8% and 78.58% within 330 min for methyl orange, methylene blue, Rhodamine B and tetracycline hydrochloride, respectively. Such distinct photocatalytic activities overwhelmed the pure Bi2Fe4O9 powders of 14.10%, 22.19%, 13.98% and 48.08%, respectively. Additionally, the composite produced a degradation rate constant of 0.00623 min−1 for methylene blue, which is significantly faster than that of 0.00073 min−1 obtained by the pure powder. These results provide an innovative strategy for designing 3D visible-light-responsive photocatalysts combined with graphene aerogel for water purification

Enhanced Photocatalytic Activities for Degradation of Dyes and Drugs by Crystalline Bismuth Ferrite-Modified Graphene Hybrid Aerogel

Industrial wastewater contains diverse toxic dyes and drugs, which pollute the environment and poison creatures. Utilizing photocatalysts has been accepted to be an effective method to degrade water pollutions using solar light. Crystalline bismuth ferrite (Bi2Fe4O9) with a band gap of 1.9–2.0 eV is expected to be one of the most promising candidates for photocatalysts in the visible light region. Amorphous graphene is also a promising candidate as a photocatalyst owing to its excellent electronic and optical properties. Herein, a composite of Bi2Fe4O9/graphene aerogels (GAs) was prepared with a two-step hydrothermal method. The prepared Bi2Fe4O9 powders were confirmed to be successfully doped into GAs and evenly dispersed between graphene sheets. The Bi2Fe4O9/GA composite was utilized to perform photodegradation for organic dyes and antibiotic drugs under visible light irradiation, yielding efficiencies of 90.22%, 92.3%, 71.8% and 78.58% within 330 min for methyl orange, methylene blue, Rhodamine B and tetracycline hydrochloride, respectively. Such distinct photocatalytic activities overwhelmed the pure Bi2Fe4O9 powders of 14.10%, 22.19%, 13.98% and 48.08%, respectively. Additionally, the composite produced a degradation rate constant of 0.00623 min−1 for methylene blue, which is significantly faster than that of 0.00073 min−1 obtained by the pure powder. These results provide an innovative strategy for designing 3D visible-light-responsive photocatalysts combined with graphene aerogel for water purification