2-(o-Tol­yloxy)benzoic acid

In the crystal structure of the title compound, C14H12O3, mol­ecules are linked via inter­molecular O—H⋯O hydrogen bonds, resulting in dimer formation. The dihedral angle between the two phenyl rings is 76.2 (2)°

Superconductivity Induced by Site-Selective Arsenic Doping in Mo5_5Si3_3

Arsenic doping in silicides has been much less studied compared with phosphorus. In this study, superconductivity is successfully induced by As doping in Mo$_5$Si$_3$. The superconducting transition temperature ($T_c$) reaches 7.7 K, which is higher than those in previously known W$_5$Si$_3$-type superconductors. Mo$_5$Si$_2$As is a type-II BCS superconductor with upper and lower critical fields of 6.65 T and 22.4 mT, respectively. In addition, As atoms are found to selectively take the 8$h$ sites in Mo$_5$Si$_2$As. The emergence of superconductivity is possibly due to the shift of Fermi level as a consequence of As doping, as revealed by the specific heat measurements and first-principles calculations. Our work provides not only another example of As doping, but also a practical strategy to achieve superconductivity in silicides through Fermi level engineering.Comment: Supporting Information available at the corresponding DO

Strong-Coupling Superconductivity with TcT_c ∼\sim 10.8 K Induced by P Doping in the Topological Semimetal Mo5_5Si3_3

By performing P doping on the Si sites in the topological semimetal Mo$_5$Si$_3$, we discover strong-coupling superconductivity in Mo$_5$Si$_{3-x}$P$_x$ (0.5 $\le$ $x$ $\le$ 2.0). Mo$_5$Si$_3$ crystallizes in the W$_5$Si$_3$-type structure with space group of $I4/mcm$ (No. 140), and is not a superconductor itself. Upon P doping, the lattice parameter $a$ decreases while $c$ increases monotonously. Bulk superconductivity is revealed in Mo$_5$Si$_{3-x}$P$_x$ (0.5 $\le$ $x$ $\le$ 2.0) from resistivity, magnetization, and heat capacity measurements. $T_c$ in Mo$_5$Si$_{1.5}$P$_{1.5}$ reaches as high as 10.8 K, setting a new record among the W$_5$Si$_3$-type superconductors. The upper and lower critical fields for Mo$_5$Si$_{1.5}$P$_{1.5}$ are 14.56 T and 105 mT, respectively. Moreover, Mo$_5$Si$_{1.5}$P$_{1.5}$ is found to be a fully gapped superconductor with strong electron-phonon coupling. First-principles calculations suggest that the enhancement of electron-phonon coupling is possibly due to the shift of the Fermi level, which is induced by electron doping. The calculations also reveal the nontrivial band topology in Mo$_5$Si$_3$. The $T_c$ and upper critical field in Mo$_5$Si$_{3-x}$P$_x$ are fairly high among pseudobinary compounds. Both of them are higher than those in NbTi, making future applications promising. Our results suggest that the W$_5$Si$_3$-type compounds are ideal platforms to search for new superconductors. By examinations of their band topologies, more candidates for topological superconductors can be expected in this structural family.Comment: 15 pages, 5 figures. Supplementary Information availabe at the corresponding DO

Searching for Black Hole Candidates by LAMOST and ASAS-SN

Most dynamically confirmed stellar-mass black holes (BHs) and their candidates were originally selected from X-ray outbursts. In the present work, we search for BH candidates in the Large Sky Area Multi-Object Fiber Spectroscopic Telescope (LAMOST) survey using the spectra along with photometry from the All Sky Automated Survey for SuperNovae (ASAS-SN), where the orbital period of the binary may be revealed by the periodic light curve, such as the ellipsoidal modulation type. Our sample consists of nine binaries, where each source contains a giant star with large radial velocity variation (ΔV_R ≳ 70 km s^(-1)) and periods known from light curves. We focus on the nine sources with long periods (T_(ph) > 5 days) and evaluate the mass M_2 of the optically invisible companion. Since the observed ΔV_R from only a few repeating spectroscopic observations is a lower limit of the real amplitude, the real mass M_2 can be significantly higher than the current evaluation. It is likely an efficient method to place constraints on M 2 by combining ΔV_R from LAMOST and T_(ph) from ASAS-SN, particularly by the ongoing LAMOST Medium Resolution Survey

Extremely long quasiparticle spin lifetimes in superconducting aluminium using MgO tunnel spin injectors

There has been an intense search in recent years for long-lived spin-polarized carriers for spintronic and quantum-computing devices. Here we report that spin polarized quasi-particles in superconducting aluminum layers have surprisingly long spin-lifetimes, nearly a million times longer than in their normal state. The lifetime is determined from the suppression of the aluminum's superconductivity resulting from the accumulation of spin polarized carriers in the aluminum layer using tunnel spin injectors. A Hanle effect, observed in the presence of small in-plane orthogonal fields, is shown to be quantitatively consistent with the presence of long-lived spin polarized quasi-particles. Our experiments show that the superconducting state can be significantly modified by small electric currents, much smaller than the critical current, which is potentially useful for devices involving superconducting qubits