Early-age Thermal Characteristics of Clinker Cements in Relation to Microstructure and Composition: Implications for Temperature Development in Large Concrete Elements

The thermal response of concrete due to hydration of cement is a predominant factor in the potential for early-age cracking of large concrete elements. An anal¬ysis of this cracking potential requires an ability to quantify both the amount of heat that is evolved by the cement as well as the rate at which this heat is evolved [1]. Both these parameters are strongly influenced by the chemical and mineralogical composition of the cement, insofar as it affects the kinetics of the hydration reac¬tions of cement. Furthermore, clinker morphology has been shown [2] to influence the compressive strength and, by inference, the hydration development of cement. Clearly, an ability to estimate the thermal response of cement in concrete, based on a knowledge of clinker characteristics would be of assistance to mass concreteThis paper presents an assessment of the heat response of nominally similar cement clinkers from a range of cement production facilities in South Africa. Clinker samples were collected at nine cement plants and cements were prepared by grinding each clinker with a uniform quality of gypsum. XRF and optical microscope techniques were then used to characterise each clinker and cement in terms of chemical composition and cement compound morphology

A Maturity Approach to the Rate of Heat Evolution in Concrete

Early-age cracking as a result of temperature induced stresses can be a serious problem in mass concrete structures or in concrete structural elements in which a high cement content concrete is used. These stresses are induced by temperature differences in the concrete as a result of the heat liberated by hydrating cement. A strategy that is aimed at controlling or limiting such cracking must include a reliable determination of the space-time distribution of temperature throughout the concrete element under consideration.This paper discusses the use of the concept of maturity as a means of combining the effects of time and temperature in describing the rate of heat evolution from hydrating cement in concrete. The proposed maturity approach allows the rate of heat evolution determined from an adiabatic test to be expressed in a form which is independent of the starting temperature of the test. This relationship can then be directly used in a time-temperature prediction model which requires a solution of the Fourier equation for heat flow

Early-age heat evolution of clinker cements in relation to microstructure and composition: Implications for temperature development in large concrete elements.

This paper presents an assessment of the range and extent of variation of heat evolution of nominally similar cement clinkers from a range of cement production facilities in South Africa. Clinker samples were collected at nine cement plants and cements were prepared by grinding each clinker with a uniform quality of gypsum. X-ray fluorescence and optical microscope techniques were then used to characterise each clinker and cement in terms of chemical composition and cement compound morphology. Concretes were then prepared with the laboratory-manufactured cements and these were tested in an adiabatic calorimeter in order to determine the rate of heat evolution from each of the clinker samples. The results of these tests were related to the chemical and morphological characteristics of the corresponding cement clinkers. The results indicate a clear differentiation of clinker cements into low, medium and high heat cements. The relationships between this classification of the heat performance of the cements and the chemistry and morphology of the clinker is not clear at this stage. However, using a finite difference heat model, the paper presents an indication of the implications of the measured heat characteristics of the cement for early-age temperature distributions in large concrete elements.MvdH2016http://www.journals.elsevier.com/cement-and-concrete-composite

The effects of supplementary cementing materials in modifying the heat of hydration of concrete.

This paper is intended to provide guidance on the form and extent to which supplementary cementing materials, in combination with Portland cement, modifies the rate of heat evolution during the early stages of hydration in concrete. In this investigation, concretes were prepared with fly ash, condensed silica fume and ground granulated blastfurnace slag, blended with Portland cement in proportions ranging from 5% to 80%. These concretes were subjected to heat of hydration tests under adiabatic conditions and the results were used to assess and quantify the effects of the supplementary cementing materials in altering the heat rate profiles of concrete. The paper also proposes a simplified mathematical form of the heat rate curve for blended cement binders in concrete to allow a design stage assessment of the likely early-age time–temperature profiles in large concrete structures. Such an assessment would be essential in the case of concrete structures where the potential for thermally induced cracking is of concern.Financial support from South African cement industry, Cement and Concrete Institute, Eskom and the National Research Foundation (South Africa).MvdH2016http://link.springer.com/journal/volumesAndIssues/1152

Effectiveness of the fi neness of two South African Portland cements for controllingearly-age temperaturedevelopment in concrete

It is generally agreed that, for a given Portland cement, the rate and amount of heat liberated during the early stages of hydration (up to 28 days) is strongly influenced by the fineness of grinding of the cement (see review by Hooton et al 2005). This is intuitively correct since finer grinding means that the hydration reac¬tions between cement and water will proceed more vigorously at early ages and hence pro¬duce more heat and at a higher maximum rate. However, as Hooton et al (2005) show, opin¬ions vary in the literature as to the sensitivity of the relationship between cement fineness and early-age heat of hydration. Furthermore, when considering different cement types, the significance of the fineness of the cement has to be judged in relation to mineralogical parameters, such as the C3A, C3S and gypsum content, equally important factors in deter¬mining the heat characteristics of cement.In developing an assessment of the quantum and rate of heat evolution from hydrating cement, an important controllable variable is the fineness of grinding of the cement. This paper presents the results of a project in which two cement clinkers were used to produce cements with five different levels of fineness. These ten cements were then used to make concretes which were subjected to testing in an adiabatic calorimeter to determine the heat evolution characteristics. The results indicate that the effect of increasing fineness on the total amount of heat released during hydration is dependent on the mineralogy and crystal composition of the cement clinker. Also, the potential benefits of a so-called low heat cement can be lost if the cement is too finely ground. Based on simulations of temperature development using the different cement types tested, the results indicate that the fineness of grinding of cement is a more important parameter in the case of concrete elements with high cement contents but of moderate dimensions. In sections of larger dimension, coarse ground cements show lower levels of temperature development with lower thermal gradients

Damage Spreading During Domain Growth

We study damage spreading in models of two-dimensional systems undergoing first order phase transitions. We consider several models from the same non-conserved order parameter universality class, and find unexpected differences between them. An exact solution of the Ohta-Jasnow-Kawasaki model yields the damage growth law $D \sim t^{\phi}$, where $\phi = t^{d/4}$ in $d$ dimensions. In contrast, time-dependent Ginzburg-Landau simulations and Ising simulations in $d= 2$ using heat-bath dynamics show power-law growth, but with an exponent of approximately $0.36$, independent of the system sizes studied. In marked contrast, Metropolis dynamics shows damage growing via $\phi \sim 1$, although the damage difference grows as $t^{0.4}$. PACS: 64.60.-i, 05.50.+qComment: 4 pags of revtex3 + 3 postscript files appended as a compressed and uuencoded file. UIB940320

Dynamic charge density correlation function in weakly charged polyampholyte globules

We study solutions of statistically neutral polyampholyte chains containing a large fraction of neutral monomers. It is known that, even if the quality of the solvent with respect to the neutral monomers is good, a long chain will collapse into a globule. For weakly charged chains, the interior of this globule is semi-dilute. This paper considers mainly theta-solvents, and we calculate the dynamic charge density correlation function g(k,t) in the interior of the globules, using the quadratic approximation to the Martin-Siggia-Rose generating functional. It is convenient to express the results in terms of dimensionless space and time variables. Let R be the blob size, and let T be the characteristic time scale at the blob level. Define the dimensionless wave vector q = R k, and the dimensionless time s = t/T. We find that for q<1, corresponding to length scales larger than the blob size, the charge density fluctuations relax according to g(q,s) = q^2(1-s^(1/2)) at short times s < 1, and according to g(q,s) = q^2 s^(-1/2) at intermediate times 1 < s 0.1, where entanglements are unimportant.Comment: 12 pages RevTex, 1 figure ps, PACS 61.25.Hq, reason replacement: Expression for dynamic corr. function g(k,t) in old version was incorrect (though expression for Fourier transform g(k,w) was correct, so the major part of the calculation remains.) Also major textual chang

Clinical management of ovarian small-cell carcinoma of the hypercalcemic type: A proposal for conservative surge

Ovarian small-cell carcinoma of the hypercalcemic type is a rare and highly malignant tumor. In two thirds of the patients, the tumor is associated with asymptomatic paraneoplastic hypercalcemia. The diagnosis may be impeded; the tumor must be distinguished

Hard Instances of the Constrained Discrete Logarithm Problem

The discrete logarithm problem (DLP) generalizes to the constrained DLP, where the secret exponent $x$ belongs to a set known to the attacker. The complexity of generic algorithms for solving the constrained DLP depends on the choice of the set. Motivated by cryptographic applications, we study sets with succinct representation for which the constrained DLP is hard. We draw on earlier results due to Erd\"os et al. and Schnorr, develop geometric tools such as generalized Menelaus' theorem for proving lower bounds on the complexity of the constrained DLP, and construct sets with succinct representation with provable non-trivial lower bounds

Solitons in the noisy Burgers equation

We investigate numerically the coupled diffusion-advective type field equations originating from the canonical phase space approach to the noisy Burgers equation or the equivalent Kardar-Parisi-Zhang equation in one spatial dimension. The equations support stable right hand and left hand solitons and in the low viscosity limit a long-lived soliton pair excitation. We find that two identical pair excitations scatter transparently subject to a size dependent phase shift and that identical solitons scatter on a static soliton transparently without a phase shift. The soliton pair excitation and the scattering configurations are interpreted in terms of growing step and nucleation events in the interface growth profile. In the asymmetrical case the soliton scattering modes are unstable presumably toward multi soliton production and extended diffusive modes, signalling the general non-integrability of the coupled field equations. Finally, we have shown that growing steps perform anomalous random walk with dynamic exponent z=3/2 and that the nucleation of a tip is stochastically suppressed with respect to plateau formation.Comment: 11 pages Revtex file, including 15 postscript-figure