49 research outputs found
Temperature and field dependence of the phase separation, structure, and magnetic ordering in LaCaMnO, (, 0.50, and 0.53)
Neutron powder diffraction measurements, combined with magnetization and
resistivity data, have been carried out in the doped perovskite
LaCaMnO (, 0.50, and 0.53) to elucidate the structural,
magnetic, and electronic properties of the system around the composition
corresponding to an equal number of Mn3+ and Mn4+. At room temperature all
three samples are paramagnetic and single phase, with crystallographic symmetry
Pnma. The samples then all become ferromagnetic (FM) at K. At
K, however, a second distinct crystallographic phase (denoted A-II)
begins to form. Initially the intrinsic widths of the peaks are quite large,
but they narrow as the temperature decreases and the phase fraction increases,
indicating microscopic coexistence. The fraction of the sample that exhibits
the A-II phase increases with decreasing temperature and also increases with
increasing Ca doping, but the transition never goes to completion to the lowest
temperatures measured (5 K) and the two phases therefore coexist in this
temperature-composition regime. Phase A-II orders antiferromagnetically (AFM)
below a N\'{e}el temperature K, with the CE-type magnetic
structure. Resistivity measurements show that this phase is a conductor, while
the CE phase is insulating. Application of magnetic fields up to 9 T
progressively inhibits the formation of the A-II phase, but this suppression is
path dependent, being much stronger for example if the sample is field-cooled
compared to zero-field cooling and then applying the field. The H-T phase
diagram obtained from the diffraction measurements is in good agreement with
the results of magnetization and resistivity.Comment: 12 pages, 3 tables, 11 figure
Independent freezing of charge and spin dynamics in La1.5Sr0.5CoO4
We present elastic and quasielastic neutron scattering measurements
characterizing peculiar short-range charge-orbital and spin order in the
layered perovskite material La1.5Sr0.5CoO4. We find that below Tc~750 K holes
introduced by Sr doping lose mobility and enter a statically ordered {\it
charge glass} phase with loosely correlated checkerboard arrangement of empty
and occupied d{3z2-r2} orbitals (Co3+ and Co2+). The dynamics of the resultant
mixed spin system is governed by the anisotropic nature of the crystal-field
Hamiltonian and the peculiar exchange pattern produced by the orbital order. It
undergoes a {\it spin freezing} transition at much a lower temperature, Ts~30
K.Comment: 4 pages, 3 figures, Latex. Submitted to PR
Magnetic properties of the S=1/2 quasi-one-dimensional antiferromagnet CaCu2O3
We report single crystal growth and magnetic susceptibility and neutron
diffraction studies of the S=1/2 quasi-1D antiferromagnet CaCu2O3. The
structure of this material is similar to that of the prototype two-leg
spin-ladder compound SrCu2O3. However, the Cu-O-Cu bond angle in the ladder
rungs in CaCu2O3 is equal to 123 deg, and therefore the magnetic interaction
along the rungs is expected to be much weaker in this material. At high
temperatures, the magnetic susceptibility of CaCu2O3 can be decomposed into a
contribution from 1D antiferromagnetic chains of finite-size chain segments
together with a weak Curie contribution. The intrachain magnetic exchange
constant, determined from the magnetic susceptibility measurements, is 2000 K.
CaCu2O3 undergoes a Neel transition at T_N=25 K with ordering wavevector of
(0.429(5), 0.5, 0.5). The magnetic structure is incommensurate in the direction
of the frustrated interchain interaction. Weak commensurate (0.5, 0.5, 0.5)
magnetic peaks are also observed below T_N. Application of a magnetic field
induces a metamagnetic transition at which the incommensurability of the
magnetic structure is substantially reduced. The material possesses only
short-range magnetic order above the transition field.Comment: 12 pages, 10 embedded figure
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