Impact of Electric Fields on Highly Excited Rovibrational States of Polar Dimers

We study the effect of a strong static homogeneous electric field on the highly excited rovibrational levels of the LiCs dimer in its electronic ground state. Our full rovibrational investigation of the system includes the interaction with the field due to the permanent electric dipole moment and the polarizability of the molecule. We explore the evolution of the states next to the dissociation threshold as the field strength is increased. The rotational and vibrational dynamics are influenced by the field; effects such as orientation, angular motion hybridization and squeezing of the vibrational motion are demonstrated and analyzed. The field also induces avoided crossings causing a strong mixing of the electrically dressed rovibrational states. Importantly, we show how some of these highly excited levels can be shifted to the continuum as the field strength is increased, and reversely how two atoms in the continuum can be brought into a bound state by lowering the electric field strength.Comment: 10 pages, 4 figure

Formation of Ultracold Heteronuclear Dimers in Electric Fields

The formation of ultracold molecules via stimulated emission followed by a radiative deexcitation cascade in the presence of a static electric field is investigated. By analyzing the corresponding cross sections, we demonstrate the possibility to populate the lowest rotational excitations via photoassociation. The modification of the radiative cascade due to the electric field leads to narrow rotational state distributions in the vibrational ground state. External fields might therefore represent an additional valuable tool towards the ultimate goal of quantum state preparation of molecules

Comparative study of the rovibrational properties of heteronuclear alkali dimers in electric fields

A comparative study of the effect of a static homogeneous electric field on the rovibrational spectra of several polar dimers in their ${\rm X}^{1}\Sigma ^{+}$ electronic ground state is performed. Focusing upon the rotational ground state within each vibrational band, results for energies and various expectation values are presented. For moderate field strengths the electric-field$\hbox{--}$induced energy shifts, orientation, alignment, and angular-motion hybridization are analyzed up to high vibrational excitations close to the dissociation threshold