7 research outputs found
Impact of Electric Fields on Highly Excited Rovibrational States of Polar Dimers
We study the effect of a strong static homogeneous electric field on the
highly excited rovibrational levels of the LiCs dimer in its electronic ground
state. Our full rovibrational investigation of the system includes the
interaction with the field due to the permanent electric dipole moment and the
polarizability of the molecule. We explore the evolution of the states next to
the dissociation threshold as the field strength is increased. The rotational
and vibrational dynamics are influenced by the field; effects such as
orientation, angular motion hybridization and squeezing of the vibrational
motion are demonstrated and analyzed. The field also induces avoided crossings
causing a strong mixing of the electrically dressed rovibrational states.
Importantly, we show how some of these highly excited levels can be shifted to
the continuum as the field strength is increased, and reversely how two atoms
in the continuum can be brought into a bound state by lowering the electric
field strength.Comment: 10 pages, 4 figure
Formation of Ultracold Heteronuclear Dimers in Electric Fields
The formation of ultracold molecules via stimulated emission followed by a
radiative deexcitation cascade in the presence of a static electric field is
investigated. By analyzing the corresponding cross sections, we demonstrate the
possibility to populate the lowest rotational excitations via photoassociation.
The modification of the radiative cascade due to the electric field leads to
narrow rotational state distributions in the vibrational ground state. External
fields might therefore represent an additional valuable tool towards the
ultimate goal of quantum state preparation of molecules
Comparative study of the rovibrational properties of heteronuclear alkali dimers in electric fields
A comparative study of the effect of a static homogeneous electric field on the rovibrational spectra of several polar dimers in their electronic ground state is performed. Focusing upon the rotational ground state within each vibrational band, results for energies and various expectation values are presented. For moderate field strengths the electric-fieldinduced energy shifts, orientation, alignment, and angular-motion hybridization are analyzed up to high vibrational excitations close to the dissociation threshold