Visualizing the Local Optical Response of Semiconducting Carbon Nanotubes to DNA-Wrapping

We studied the local optical response of semiconducting single-walled carbon nanotubes to wrapping by DNA segments using high resolution tip-enhanced near-field microscopy. Photoluminescence (PL) near-field images of single nanotubes reveal large DNA-wrapping-induced red shifts of the exciton energy that are two times higher than indicated by spatially averaging confocal microscopy. Near-field PL spectra taken along nanotubes feature two distinct PL bands resulting from DNA-wrapped and unwrapped nanotube segments. The transition between the two energy levels occurs on a length scale smaller than our spatial resolution of about 15 nm

Exciton decay dynamics in individual carbon nanotubes at room temperature

We studied the exciton decay dynamics of individual semiconducting single-walled carbon nanotubes at room temperature using time-resolved photoluminescence spectroscopy. The photoluminescence decay from nanotubes of the same (n,m) type follows a single exponential decay function, however, with lifetimes varying between about 1 and 40 ps from nanotube to nanotube. A correlation between broad photoluminescence spectra and short lifetimes was found and explained by defects promoting both nonradiative decay and vibronic dephasing

Nitrogen-Functionalized Graphene Nanoflakes (GNFs:N): Tunable Photoluminescence and Electronic Structures

This study investigates the strong photoluminescence (PL) and X-ray excited optical luminescence observed in nitrogen-functionalized 2D graphene nanoflakes (GNFs:N), which arise from the significantly enhanced density of states in the region of {\pi} states and the gap between {\pi} and {\pi}* states. The increase in the number of the sp2 clusters in the form of pyridine-like N-C, graphite-N-like, and the C=O bonding and the resonant energy transfer from the N and O atoms to the sp2 clusters were found to be responsible for the blue shift and the enhancement of the main PL emission feature. The enhanced PL is strongly related to the induced changes of the electronic structures and bonding properties, which were revealed by the X-ray absorption near-edge structure, X-ray emission spectroscopy, and resonance inelastic X-ray scattering. The study demonstrates that PL emission can be tailored through appropriate tuning of the nitrogen and oxygen contents in GNFs and pave the way for new optoelectronic devices.Comment: 8 pages, 6 figures (including toc figure

Multiwavelength study of extreme variability in LEDA 1154204: A changing-look event in a type 1.9 Seyfert

Context. Multiwavelength studies of transients in actively accreting supermassive black holes have revealed that large-amplitude variability is frequently linked to significant changes in the optical spectra -- a phenomenon referred to as changing-look AGN (CLAGN). Aim. In 2020, the Zwicky Transient Facility detected a transient flaring event in the type-1.9 AGN 6dFGS~gJ042838.8-000040, wherein a sharp increase in magnitude of $\sim$0.55 and $\sim$0.3 in the $g$- and $r$-bands, respectively, occurred over $\sim$40 days. Spectrum Roentgen Gamma (SRG)/eROSITA also observed the object in X-rays as part of its all-sky survey, but only after the flare had started decaying. Methods. We performed a three-year, multiwavelength follow-up campaign of the source to track its spectral and temporal characteristics. This campaign included multiple ground-based facilities for optical spectroscopic monitoring and space-based observatories including \textit{XMM-Newton} and \textit{Swift} for X-ray and UV observations. Results. An optical spectrum taken immediately after the peak revealed a changing-look event wherein the source had transitioned from type 1.9 to 1, with the appearance of a double-peaked broad H$\beta$ line and a blue continuum, both absent in an archival spectrum from 2005. The X-ray emission exhibits dramatic flux variation: a factor of $\sim$17, but with no spectral evolution, as the power-law photon index remained $\sim$1.9. There is no evidence of a soft X-ray excess. Overall the object exhibits no apparent signatures of a tidal disruption event. Conclusions. The transient event was likely triggered by a disk instability in a pre-existing accretion flow, culminating in the observed multi-wavelength variability and CLAGN event.Comment: 34 pages, 24 figures, Submitted to Astronomy & Astrophysic

Discovery of the luminous X-ray ignition eRASSt J234402.9−-352640; I. Tidal disruption event or a rapid increase in accretion in an active galactic nucleus?

In November 2020, a new, bright object, eRASSt J234402.9$-$352640, was discovered in the second all-sky survey of SRG/eROSITA. The object brightened by a factor of at least 150 in 0.2--2.0 keV flux compared to an upper limit found six months previous, reaching an observed peak of $1.76_{-0.24}^{+0.03} \times 10^{-11}$ erg cm$^{-2}$ s$^{-1}$. The X-ray ignition is associated with a galaxy at $z=0.10$, making the peak luminosity log$_{10}(L_{\rm 0.2-2keV}/[\textrm{erg s}^{-1}])$=$44.7\pm0.1$. Around the time of the rise in X-ray flux, the nucleus of the galaxy brightened by approximately 3 mag. in optical photometry, after correcting for the host. We present data from Swift, XMM-Newton, and NICER, which reveal a very soft spectrum as well as strong 0.2--2.0 keV flux variability on multiple timescales. Optical spectra taken in the weeks after the ignition event show a blue continuum with broad, asymmetric Balmer emission lines, and high-ionisation ([OIII]$\lambda\lambda$4959,5007) and low-ionisation ([NII]$\lambda$6585, [SII]$\lambda\lambda$6716,6731) narrow emission lines. Following the peak in the optical light curve, the X-ray, UV, and optical photometry all show a rapid decline. The X-ray light curve shows a decrease in luminosity of $\sim$0.45 over 33 days and the UV shows a drop of $\sim$0.35. eRASSt J234402.9$-$352640 also shows a brightening in the mid-infrared, likely powered by a dust echo of the luminous ignition. We find no evidence in Fermi-LAT $\gamma$-ray data for jet-like emission. The event displays characteristics of a tidal disruption event (TDE) as well as of an active galactic nucleus (AGN), complicating its classification. Based on the softness of the X-ray spectrum, the presence of high-ionisation optical emission lines, and the likely infrared echo, we find that a TDE within a turned-off AGN best matches our observations.Comment: 25 pages, 17 figures, 9 tables, Accepted for publication in A&

Graphene Photonics and Optoelectronics

The richness of optical and electronic properties of graphene attracts enormous interest. Graphene has high mobility and optical transparency, in addition to flexibility, robustness and environmental stability. So far, the main focus has been on fundamental physics and electronic devices. However, we believe its true potential to be in photonics and optoelectronics, where the combination of its unique optical and electronic properties can be fully exploited, even in the absence of a bandgap, and the linear dispersion of the Dirac electrons enables ultra-wide-band tunability. The rise of graphene in photonics and optoelectronics is shown by several recent results, ranging from solar cells and light emitting devices, to touch screens, photodetectors and ultrafast lasers. Here we review the state of the art in this emerging field.Comment: Review Nature Photonics, in pres

Graphene Mode-Locked Ultrafast Laser

Graphene is at the center of a significant research effort. Near-ballistic transport at room temperature and high mobility make it a potential material for nanoelectronics. Its electronic and mechanical properties are also ideal for micro and nanomechanical systems, thin-film transistors and transparent and conductive composites and electrodes. Here we exploit the optoelectronic properties of graphene to realize an ultrafast laser. A graphene-polymer composite is fabricated using wet-chemistry techniques. Pauli blocking following intense illumination results in saturable absorption, independent of wavelength. This is used to passively mode-lock an Erbium-doped fibre laser working at 1559nm, with a 5.24nm spectral bandwidth and ~460fs pulse duration, paving the way to graphene-based photonics