1 research outputs found
The effect of a nucleating agent on lamellar growth in melt-crystallizing polyethylene oxide
The effects of a (non co-crystallizing) nucleating agent on secondary
nucleation rate and final lamellar thickness in isothermally melt-crystallizing
polyethylene oxide are considered. SAXS reveals that lamellae formed in
nucleated samples are thinner than in the pure samples crystallized at the same
undercoolings. These results are in quantitative agreement with growth rate
data obtained by calorimetry, and are interpreted as the effect of a local
decrease of the basal surface tension, determined mainly by the nucleant
molecules diffused out of the regions being about to crystallize. Quantitative
agreement with a simple lattice model allows for some interpretation of the
mechanism.Comment: submitted to Journal of Applied Physics (first version on 22 Apr
2002