Theoretical studies of a hydrogen abstraction tool for nanotechnology

In the design of a nanoscale, site-specific hydrogen abstraction tool, the authors suggest the use of an alkynyl radical tip. Using ab initio quantum-chemistry techniques including electron correlation they model the abstraction of hydrogen from dihydrogen, methane, acetylene, benzene and isobutane by the acetylene radical. By conservative estimates, the abstraction barrier is small (less than 7.7 kcal mol^-1) in all cases except for acetylene and zero in the case of isobutane. Thermal vibrations at room temperature should be sufficient to supply the small activation energy. Several methods of creating the radical in a controlled vacuum setting should be feasible. The authors show how nanofabrication processes can be accurately and inexpensively designed in a computational framework

Numerical study of resistivity of model disordered three-dimensional metals

We calculate the zero-temperature resistivity of model 3-dimensional disordered metals described by tight-binding Hamiltonians. Two different mechanisms of disorder are considered: diagonal and off-diagonal. The non-equilibrium Green function formalism provides a Landauer-type formula for the conductance of arbitrary mesoscopic systems. We use this formula to calculate the resistance of finite-size disordered samples of different lengths. The resistance averaged over disorder configurations is linear in sample length and resistivity is found from the coefficient of proportionality. Two structures are considered: (1) a simple cubic lattice with one s-orbital per site, (2) a simple cubic lattice with two d-orbitals. For small values of the disorder strength, our results agree with those obtained from the Boltzmann equation. Large off-diagonal disorder causes the resistivity to saturate, whereas increasing diagonal disorder causes the resistivity to increase faster than the Boltzmann result. The crossover toward localization starts when the Boltzmann mean free path relative to the lattice constant has a value between 0.5 and 2.0 and is strongly model dependent.Comment: 4 pages, 5 figure

Vector Coherent State Realization of Representations of the Affine Lie Algebra sl^(2)\hat{sl}(2)

The method of vector coherent states is generalized to study representations of the affine Lie algebra $\hat{sl}(2)$. A large class of highest weight irreps is explicitly constructed, which contains the integrable highest weight irreps as special cases.Comment: 8 pages plain latex. To appear in J. Phys.

Note and Comment

Public Utility Valuation - Cost of Reproduction Theory and the World War - The very grave objections to the cost-of-reproduction theory of valuation of public utilities was pointed out at large in 15 MICH. L. REv. 2o5. The violent price changes following the World War have greatly increased the weight of these objections to calling anything a base which rests on such uncertainties and fluctuations as cost-of-reproduction. A base should be stable, but this has the stability Of a flying machine. There had been a rising curve of costs from 1893 to 1i16, but since that date the rise has been almost vertical. The public utilities by- the thousands desire to take advantage of it. They are as fond of cost-of-reproduction now as they were of original cost in 1893, while for the public the transfer of affections has been reversed. Cost-of-reproduction has not proved a friend that either party can trust, and if the present flight of prices comes back to earth the utilities will have a revulsion of feeling to the efficient investment theory of valuation for which the public just now exhibits a touching fondness. The amusing, although regrettable, changes in attitude toward the cost-of-reproduction rule have been stated with great clearness by the Indiana Commission in Re Indianapolls Water Co., P. U. R. i919 A 448, 464. In general, it may be said that the Commissions, being in more constant and intimate touch with conditions, are much more impressed by this than are most of the courts

Quantising Gravity Using Physical States of a Superstring

A symmetric zero mass tensor of rank two is constructed using the superstring modes of excitation which satisfies the physical state constraints of a superstring. These states have one to one correspondence with quantised operators and are shown to be the absorption and emission quanta of the Minkowski space Lorentz tensors using the Gupta-Bleuler method of quantisation. The principle of equivalence makes the tensor identical to the metric tensor at any arbitrary space-time point. The propagator for the quantised field is deduced. The gravitational interaction is switched on by going over from ordinary derivatives to coderivatives.The Riemann-Christoffel affine connections are calculated and the weak field Ricci tensor $R^{0}_{\mu \nu}$ is shown to vanish. The interaction part $R^{int}_{\mu \nu}$ is found out and the exact $R_{\mu \nu}$ of theory of gravity is expressed in terms of the quantised metric. The quantum mechanical self energy of the gravitational field, in vacuum, is shown to vanish. It is suggested that quantum gravity may be renormalisable by the use of the physical ground states of the superstring theory.Comment: 14 page

Field Theory On The World Sheet: Improvements And Generalizations

This article is the continuation of a project of investigating planar phi^3 model in various dimensions. The idea is to reformulate them on the world sheet, and then to apply the classical (meanfield) approximation, with two goals: To show that the ground state of the model is a solitonic configuration on the world sheet, and the quantum fluctuations around the soliton lead to the formation of a transverse string. After a review of some of the earlier work, we introduce and discuss several generalizations and new results. In 1+2 dimensions, a rigorous upper bound on the solitonic energy is established. A phi^4 interaction is added to stabilize the original phi^3 model. In 1+3 and 1+5 dimensions, an improved treatment of the ultraviolet divergences is given. And significantly, we show that our approximation scheme can be imbedded into a systematic strong coupling expansion. Finally, the spectrum of quantum fluctuations around the soliton confirms earlier results: In 1+2 and 1+3 dimensions, a transverse string is formed on the world sheet.Comment: 29 pages, 5 figures, several typos and eqs.(74) and (75) are corrected, a comment added to section

Systematic approach to cyclic orbifolds

We introduce an orbifold induction procedure which provides a systematic construction of cyclic orbifolds, including their twisted sectors. The procedure gives counterparts in the orbifold theory of all the current-algebraic constructions of conformal field theory and enables us to find the orbifold characters and their modular transformation properties.Comment: 39 pages, LaTeX. v2,3: references added. v4: typos correcte

More On The Connection Between Planar Field Theory And String Theory

We continue work on the connection between world sheet representation of the planar phi^3 theory and string formation. The present article, like the earlier work, is based on the existence of a solitonic solution on the world sheet, and on the zero mode fluctuations around this solution. The main advance made in this paper is the removal of the cutoff and the transition to the continuum limit on the world sheet. The result is an action for the modes whose energies remain finite in this limit (light modes). The expansion of this action about a dense background of graphs on the world sheet leads to the formation of a string.Comment: 27 pages, 3 figure

Strings from N=2N=2 Gauged Wess-Zumino-Witten Models

We present an algebraic approach to string theory. An embedding of $sl(2|1)$ in a super Lie algebra together with a grading on the Lie algebra determines a nilpotent subalgebra of the super Lie algebra. Chirally gauging this subalgebra in the corresponding Wess-Zumino-Witten model, breaks the affine symmetry of the Wess-Zumino-Witten model to some extension of the $N=2$ superconformal algebra. The extension is completely determined by the $sl(2|1)$ embedding. The realization of the superconformal algebra is determined by the grading. For a particular choice of grading, one obtains in this way, after twisting, the BRST structure of a string theory. We classify all embeddings of $sl(2|1)$ into Lie super algebras and give a detailed account of the branching of the adjoint representation. This provides an exhaustive classification and characterization of both all extended $N=2$ superconformal algebras and all string theories which can be obtained in this way.Comment: 50 pages, LaTe