5 research outputs found
Aminoguanidinium hydrogen fumarate
The title compound, CH7N4
+·C4H3O4
−, is a molecular salt in which the aminoguanidinium cations and fumarate monoanions are close to planar, with maximum deviations of 0.011 (1) and 0.177 (1) Å, respectively. The crystal packing is stabilized by intermolecular N—H⋯O and O—H⋯O hydrogen bonds
(3E)-11,16-Dioxatricyclo[15.4.0.05,10]henicosa-1(21),3,5,7,9,17,19-heptaen-2-one
The title compound, C19H18O3, crystallizes with three molecules (A, B and C) in the asymmetric unit. The carbonyl O atom shows positional disorder over two sites in molecules A and B; the site-occupancy ratios are 0.76 (3):0.24 (3) and 0.86 (3):0.14 (3), respectively. The ethylene fragments in each molecule have an E conformation, while the C—O—C—C torsion angles indicate near planarity. The dihedral angles formed by the aromatic rings are 20.0 (1), 23.7 (1) and 16.1 (1)° for molecules A, B and C, respectively. Intramolecular C—H...O hydrogen bonds occur in each molecule
A diastereomer of methyl (1R,3′S)-1′,1′′-dimethyl-2,2′′-dioxo-2H-dispiro[acenaphthylene-1,2′-pyrrolidine-3′,3′′-indoline]-4′-carboxylate
In the title compound, C26H22N2O4, the central pyrrolidine ring adopts a twist conformation and the cyclopentane ring of the dihydroacenapthylene group adopts an envelope conformation with the spiro C atom as the flap. The naphthalene ring system of the dihydroacenaphthylene group forms dihedral angles of 83.4 (9) and 61.3 (7)°, respectively, with the mean planes of the pyrrolidine and indole rings. The crystal packing is stabilized by intermolecular C—H...O hydrogen bonds. The title compound is a diastereomer of a previously reported structure