110 research outputs found
Information Value: Measuring Utterance Predictability as Distance from Plausible Alternatives
We present information value, a measure which quantifies the predictability of an utterance relative to a set of plausible alternatives. We introduce a method to obtain interpretable estimates of information value using neural text generators, and exploit their psychometric predictive power to investigate the dimensions of predictability that drive human comprehension behaviour. Information value is a stronger predictor of utterance acceptability in written and spoken dialogue than aggregates of token-level surprisal and it is complementary to surprisal for predicting eye-tracked reading times
AnaLog: Testing Analytical and Deductive Logic Learnability in Language Models
Acknowledgements We would like to thank the anonymous ARR and *SEM 2022 reviewers for their feedback and suggestions, as well as Ece Takmaz for her comments. Samuel Ryb and Arabella Sinclair worked on this project while affiliated with the University of Amsterdam. The project has received funding from the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme (grant agreement No. 819455). 1The dataset is available at https://github.com/dmg-illc/analogPublisher PD
In situ physical and chemical characterisation of the Eyjafjallajökull aerosol plume in the free troposphere over Italy
Continuous measurements of physical and chemical properties at the Mt.
Cimone (Italy) GAW-WMO (Global Atmosphere Watch, World Meteorological
Organization) Global Station (2165 m a.s.l.) have allowed the detection of the
volcanic aerosol plume resulting from the Eyjafjallajökull (Iceland) eruption of
spring 2010. The event affected the Mt. Cimone site after a transport over a distance
of more than 3000 km. Two main transport episodes were detected during the
eruption period, showing a volcanic fingerprint discernible against the free
tropospheric background conditions typical of the site, the first from April
19 to 21 and the second from 18 to 20 May 2010. This paper reports the
modification of aerosol characteristics observed during the two episodes,
both characterised by an abrupt increase in fine and, especially, coarse
mode particle number.
Analysis of major, minor and trace elements by different analytical
techniques (ionic chromatography, particle induced X-ray emission–particle
induced gamma-ray emission (PIXE–PIGE) and inductively
coupled plasma mass spectrometry (ICP-MS)) were performed on
aerosols collected by ground-level discrete sampling. The resulting database
allows the characterisation of aerosol chemical composition during the
volcanic plume transport and in background conditions. During the passage of
the volcanic plume, the fine fraction was dominated by sulphates, denoting
the secondary origin of this mode, mainly resulting from in-plume oxidation
of volcanic SO2. By contrast, the coarse fraction was characterised by
increased concentration of numerous elements of crustal origin, such as Fe,
Ti, Mn, Ca, Na, and Mg, which enter the composition of silicate minerals.
Data analysis of selected elements (Ti, Al, Fe, Mn) allowed the estimation
of the volcanic plume's contribution to total PM10, resulting in a local
enhancement of up to 9.5 μg m−3, i.e. 40% of total PM10 on
18 May, which was the most intense of the two episodes. These results appear
significant, especially in light of the huge distance of Mt. Cimone from
the source, confirming the widespread diffusion of the Eyjafjallajökull
ashes over Europe
In situ physical and chemical characterisation of the Eyjafjallajökull aerosol plume in the free troposphere over Italy
Abstract. Continuous measurements of physical and chemical properties at the Mt. Cimone (Italy) GAW-WMO (Global Atmosphere Watch, World Meteorological Organization) Global Station (2165 m a.s.l.) have allowed the detection of the volcanic aerosol plume resulting from the Eyjafjallajökull (Iceland) eruption of spring 2010. The event affected the Mt. Cimone site after a transport over a distance of more than 3000 km. Two main transport episodes were detected during the eruption period, showing a volcanic fingerprint discernible against the free tropospheric background conditions typical of the site, the first from April 19 to 21 and the second from 18 to 20 May 2010. This paper reports the modification of aerosol characteristics observed during the two episodes, both characterised by an abrupt increase in fine and, especially, coarse mode particle number. Analysis of major, minor and trace elements by different analytical techniques (ionic chromatography, particle induced X-ray emission–particle induced gamma-ray emission (PIXE–PIGE) and inductively coupled plasma mass spectrometry (ICP-MS)) were performed on aerosols collected by ground-level discrete sampling. The resulting database allows the characterisation of aerosol chemical composition during the volcanic plume transport and in background conditions. During the passage of the volcanic plume, the fine fraction was dominated by sulphates, denoting the secondary origin of this mode, mainly resulting from in-plume oxidation of volcanic SO2. By contrast, the coarse fraction was characterised by increased concentration of numerous elements of crustal origin, such as Fe, Ti, Mn, Ca, Na, and Mg, which enter the composition of silicate minerals. Data analysis of selected elements (Ti, Al, Fe, Mn) allowed the estimation of the volcanic plume's contribution to total PM10, resulting in a local enhancement of up to 9.5 μg m−3, i.e. 40% of total PM10 on 18 May, which was the most intense of the two episodes. These results appear significant, especially in light of the huge distance of Mt. Cimone from the source, confirming the widespread diffusion of the Eyjafjallajökull ashes over Europe
Size-resolved aerosol composition at an urban and a rural site in the Po Valley in summertime: implications for secondary aerosol formation
The aerosol size-segregated chemical composition was analyzed at an urban (Bologna) and a rural (San Pietro Capofiume) site in the Po Valley, Italy, during June and July 2012, by ion-chromatography (major water-soluble ions and organic acids) and evolved gas analysis (total and water-soluble carbon), to investigate sources and mechanisms of secondary aerosol formation during the summer. A significant enhancement of secondary organic and inorganic aerosol mass was observed under anticyclonic conditions with recirculation of planetary boundary layer air but with substantial differences between the urban and the rural site. The data analysis, including a principal component analysis (PCA) on the size-resolved dataset of chemical concentrations, indicated that the photochemical oxidation of inorganic and organic gaseous precursors was an important mechanism of secondary aerosol formation at both sites. In addition, at the rural site a second formation process, explaining the largest fraction (22 %) of the total variance, was active at nighttime, especially under stagnant conditions. Nocturnal chemistry in the rural Po Valley was associated with the formation of ammonium nitrate in large accumulation-mode (0.42–1.2 µm) aerosols favored by local thermodynamic conditions (higher relative humidity and lower temperature compared to the urban site). Nocturnal concentrations of fine nitrate were, in fact, on average 5 times higher at the rural site than in Bologna. The water uptake by this highly hygroscopic compound under high RH conditions provided the medium for increased nocturnal aerosol uptake of water-soluble organic gases and possibly also for aqueous chemistry, as revealed by the shifting of peak concentrations of secondary compounds (water-soluble organic carbon (WSOC) and sulfate) toward the large accumulation mode (0.42–1.2 µm). Contrarily, the diurnal production of WSOC (proxy for secondary organic aerosol) by photochemistry was similar at the two sites but mostly affected the small accumulation mode of particles (0.14–0.42 µm) in Bologna, while a shift to larger accumulation mode was observed at the rural site. A significant increment in carbonaceous aerosol concentration (for both WSOC and water-insoluble carbon) at the urban site was recorded mainly in the quasi-ultrafine fraction (size range 0.05–0.14 µm), indicating a direct influence of traffic emissions on the mass concentrations of this range of particles
The role of immune PSA complex (iXip) in the prediction of prostate cancer
Purpose: To analyse the performance of iXip in the prediction of prostate cancer (PCa) and high-grade PCa. Methods: A consecutive series of men undergoing MRI/FUSION prostate biopsies were enrolled in one centre. Indications for prostate biopsy included abnormal prostate-specific antigen (PSA) levels (PSA>4 ng/ml) and/or abnormal digital rectal examination (DRE) and/or abnormal MRI. All patients underwent the evaluation of serum PSA-IgM concentration and the iXip ratio was calculated. Accuracy iXip for the prediction of PCa was evaluated using multivariable binary regression analysis and receiver operator characteristics (ROC) curves. Results: Overall 160 patients with a median age of 65 (62/73) years were enrolled. Overall, 42% patients were diagnosed with PCa and 75% of them had high-grade cancer (Epstein ≥ 3). Patients with PCa were older and presented higher PSA levels, higher PIRADS scores and lower prostate volumes (PVs). On ROC analysis iXip presented an area under the curve (AUC) of 0.57 in the prediction of PCa and of 0.54 for the prediction of high-grade PCa. Conclusions: In our experience, immune PSA complexes are not predictors of PCa. iXip analysis should not be included in the diagnostic pathway of patients at increased risk of PCa
Aerosol properties associated with air masses arriving into the North East Atlantic during the 2008 Mace Head EUCAARI intensive observing period: an overview
As part of the EUCAARI Intensive Observing Period, a 4-week campaign to measure aerosol physical, chemical and optical properties, atmospheric structure, and cloud microphysics was conducted from mid-May to mid-June, 2008 at the Mace Head Atmospheric Research Station, located at the interface of Western Europe and the N. E. Atlantic and centered on the west Irish coastline. During the campaign, continental air masses comprising both young and aged continental plumes were encountered, along with polar, Arctic and tropical air masses. Polluted-continental aerosol concentrations were of the order of 3000 cm(-3), while background marine air aerosol concentrations were between 400-600 cm(-3). The highest marine air concentrations occurred in polar air masses in which a 15 nm nucleation mode, with concentration of 1100 cm(-3), was observed and attributed to open ocean particle formation. Continental air submicron chemical composition (excluding refractory sea salt) was dominated by organic matter, closely followed by sulphate mass. Although the concentrations and size distribution spectral shape were almost identical for the young and aged continental cases, hygroscopic growth factors (GF) and cloud condensation nuclei (CCN) to total condensation nuclei (CN) concentration ratios were significantly less in the younger pollution plume, indicating a more oxidized organic component to the aged continental plume. The difference in chemical composition and hygroscopic growth factor appear to result in a 40-50% impact on aerosol scattering coefficients and Aerosol Optical Depth, despite almost identical aerosol microphysical properties in both cases, with the higher values been recorded for the more aged case. For the CCN/CN ratio, the highest ratios were seen in the more age plume. In marine air, sulphate mass dominated the sub-micron component, followed by water soluble organic carbon, which, in turn, was dominated by methanesulphonic acid (MSA). Sulphate concentrations were highest in marine tropical air - even higher than in continental air. MSA was present at twice the concentrations of previously-reported concentrations at the same location and the same season. Both continental and marine air exhibited aerosol GFs significantly less than ammonium sulphate aerosol pointing to a significant organic contribution to all air mass aerosol properties
Corrigendum to "Chemical characterization of springtime submicrometer aerosol in Po Valley, Italy" published in Atmos. Chem. Phys., 12, 8401–8421, 2012
No abstract available
Un proyecto de educación masiva de calidad
Algunos autores convergen sobre la idea de masividad como acceso formal a las universidades y acceso real al conocimiento, aunque para ser posible esto último, es necesario que exista un alto grado de calidad en la educación. La introducción a la noción de masividad o inclusión cambia el eje de discusión al reconocer que la sociedad no es homogénea, y la diversidad constituye un componente a ser revalorizado. El presente informe contempla el análisis y estudio de la relación de los conceptos de calidad y masividad dentro de la Educación Universitaria, observando particularmente el caso de La Universidad Nacional de La Matanza, que ha sabido correlacionar estos conceptos. El ingreso directo a la mayor parte de las Instituciones de Educación Superior públicas en Argentina, junto a la gratuidad de las mismas son factores considerados por sí mismos políticas inclusivas en sentido amplio. Según el Centro de Estudios de la Educación Argentina, en 2015 las Universidades incrementaron el promedio de graduados. Particularmente, este trabajo pone de manifiesto que en la UNLaM la concurrencia masiva de alumnos no ha ido en detrimento de la calidad -tanto educativa como de gestión-de esta Casa de Altos Estudios, contrariamente a lo que habitualmente ocurre.Fil: Narváez, Jorge Luis. Universidad Nacional de La Matanza. Departamento de Ingeniería e Investigaciones Tecnológicas; Argentina.Fil: Pepe, María Laura. Universidad Nacional de La Matanza. Departamento de Ingeniería e Investigaciones Tecnológicas; Argentina.Fil: Carro, Roberto Ricardo. Universidad Nacional de La Matanza. Departamento de Ingeniería e Investigaciones Tecnológicas; Argentina.Fil: Narváez, Adriana Haydee. Universidad Nacional de La Matanza. Departamento de Ingeniería e Investigaciones Tecnológicas; Argentina.Fil: García, Adrián Rafael. Universidad Nacional de La Matanza. Departamento de Ingeniería e Investigaciones Tecnológicas; Argentina.Fil: Bombino, María Alejandra. Universidad Nacional de La Matanza. Departamento de Ingeniería e Investigaciones Tecnológicas; Argentina.Fil: Cinquegrani, Clara Irma. Universidad Nacional de La Matanza. Departamento de Ingeniería e Investigaciones Tecnológicas; Argentina.Fil: Spósitto, Verónica Andrea. Universidad Nacional de La Matanza. Departamento de Ingeniería e Investigaciones Tecnológicas; Argentina.Fil: Narváez, Gabriela Andrea. Universidad Nacional de La Matanza. Departamento de Ingeniería e Investigaciones Tecnológicas; Argentina.Fil: Giulianelli, Juan Ignacio. Universidad Nacional de La Matanza. Departamento de Ingeniería e Investigaciones Tecnológicas; Argentina.Fil: Mouta, Silvina Raquel. Universidad Nacional de La Matanza. Departamento de Ingeniería e Investigaciones Tecnológicas; Argentina.Fil: Pera, Florencia S. Universidad Nacional de La Matanza. Departamento de Ingeniería e Investigaciones Tecnológicas; Argentina
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