Estimating Potential Ground and Surface Water Pollution from Land Application of Poultry Litter - II

In Arkansas, approximately 1 Tg of poultry (Gallus gallus domesticus) manure and litter is produced annually. These waste products are commonly applied to pastures as a soil amendment or fertilizer, but excessive application rates and poor management practices could result in nutrient contamination of ground and surface water. The purpose of this study was to: (1) assess the nutrient concentrations in poultry manure and (2) evaluate the nitrogen loss from land-applied poultry litter and manure due to ammonia volatilization and denitrification. Analyses for total Kjeldahl nitrogen (TKN), inorganic nitrogen (Ni), phosphorus (P), and potassium (K) were compared in 12 wet and dry hen manure samples. Drying the manure reduced the TKN from 57 to 40 g N/kg on a dry weight basis in wet and dry manure, respectively. The Ni in the manure was in the ammoniacal form with values of 19 and 2 g N/kg for wet and dry manure, respectively. The P and K levels were not influenced by drying the manure and had values of 24 and 21 g/kg, respectively. The results indicate that the nitrogen content of hen manure can be significantly reduced by drying the sample prior to analysis. In a 10-day laboratory study and an 11-day field study to evaluate ammonia volatilization from surface-applied hen manure, results indicated that 37% of the total nitrogen content of the manure was lost. The results indicated that a substantial amount of nitrogen in surface-applied poultry waste can be lost due to ammonia volatilization. Laboratory studies to evaluate denitrification in a Captina silt loam amended with 9 Mg/ha of poultry litter were conducted. When the soil was aerobically incubated for 168 h and then flooded for 66 h, the nitrate-nitrogen level decreased a net of 17 mg N/kg. The results indicated that, if the ammoniacal nitrogen in the litter is oxidized to nitrate under aerobic conditions and then the soil is flooded and available carbon is present, denitrification can occur rapidly. Results from these studies indicate that soil and environmental conditions playa critical role in determining the potential for nitrate pollution of ground and surface water when poultry manure and litter are surface-applied to pastures

The Behavior of Soluble Salt in Sharkey Clay

Soluble salt problems do exist and are significant in Arkansas. Studies have been conducted on Crowley silt loam (Typic Albaqualfs) which have established the behavior of soluble salt in that soil. The major objective of this study was to quantify the behavior of soluble salt in a second important Mississippi River Delta soil - the Sharkey (Vertic Haplaquepts). To this end, estimation of the downward redistribution of salt and the estimation of various components of the water balance for this soil served as specific objectives. Field studies were designed to monitor the movement of salt in the Sharkey soil and to characterize selected components of the water balance. In total, three tentative conclusions may be drawn from the data. First, the infiltration for the Sharkey soil was approximately three times that of the Crowley silt loam. The average value was 29 cm for the rice season. Second, levee seepage, while significant for small plots, was shown to be small for production-sized fields. Levee seepage remained relatively constant throughout the season and averaged 0.025 nvfym/d. And third, downward redistribution of salt was large and appeared to follow a pattern where a peak occurred at the surface and, possibly, at the lower soil depths

Organic-inorganic spatial relationships in carbonaceous chondrites

The use of a novel technique to determine the spatial relationships of organic and aqueously produced inorganic phases in carbonaceous chondrites, in order to support proposals of a genetic link between the two

Mars simulated exposure and the characteristic Raman biosignatures of amino acids and halophilic microbes

Though Raman bands of α-amino acids (AA) are well documented, often only the strongest intensity bands are quoted as identifiers (e.g. Jenkins et al., 2005; De Gelder et al., 2007; Zhu et al., 2011). Unknown regolith mixtures on Mars-sampling missions could obscure these bands. Here the case is made for determining, via a statistical method, sets of characteristic bands to be used as identifiers, independent of band intensity or number of bands (Rolfe et al., 2016). AA have upwards of 25 potentially identifying bands and this method defines sets of 10–19 bands per AA. Examination of AA-doped Mars-like basalt resulted in a maximum of eight bands being identified, as some characteristic bands were obscured by mineral bands, including the strongest intensity band in some cases. This proved the need for characteristic bands to be defined, enabling successful identification of AA. The ESA ExoMars Rover mission will crush and then pass the sample to the Raman Laser Spectrometer. We crushed a Mars-like basalt to a similar grain size expected to be created by the rover. Our samples were doped with 1 % (by weight) AA samples, resulting in no detection of AA, because of loss of original spatial context and spaces between the grains. We recommend that Raman spectroscopy on future missions should be conducted before the sample is crushed. Halite-entombed halophilic microbes, known to survive being entombed, were exposed to Mars-like surface (including temperature, pressure, atmospheric composition and UV) and freeze-thaw cycle (plus pressure and atmospheric composition) conditions. This test on the survival of the microbes showed that survival rates quickly deteriorated in surface conditions, but freeze-thaw cycle samples had well preserved Raman biosignatures, indicating that similar signatures could be detectable on Mars if similar life persists in evaporitic material or brines today

Pyrolysis-GC×GC-TOFMS to characterize carbonaceous chondrites

Using pyrolysis-GCxGC-TOFMS to analyze organic carbon in carbonaceous chondrites gives a massive increase in both sensitivity and structural information from samples when compared to traditional Py-GC-MS

Improving Water Quality Through BMPs For Crop Production Systems Whole Farm Soil and Water Management

The major objective of this demonstration project was to assess the usefulness of Global Positioning Systems/Geographic Information Systems (GPS/GIS), water testing, soil testing and yield monitoring in a whole farm water and soil management plan. An important part of this objective was to make recommendations to increase crop productivity and decrease the potential for surface water degradation through erosion and runoff at the farm. The farm was located on 2400 acres in the Bayou de View watershed in Monroe County, Arkansas. The farm lies approximately five miles southwest of the town of Brinkley straddling Highway 17 just south of its intersection with County Road 302 and with U. S. Highway 70. Slightly over 2200 acres were under cultivation and this was generally in a 1 :2 ratio of rice to soybeans, with approximately half of the soybean fields double-cropped with winter wheat each year

Estimating Potential Ground and Surface Water Pollution from Land Application of Poultry Litter

In 1985, more than 750 million broiler chickens were produced in Arkansas. During the same year over 15 million laying chickens produced 3.6 million eggs. The waste products of these agricultural production systems, poultry litter and manure, were about 1 million metric tons. As a result of land application of these wastes, about 5,000 metric tons of annnonium N and 12,000 metric tons of mineralized nitrogen were applied to Arkansas pastures in 1985. Manures contributed about 2-3 percent of the total. The objective of this research was to quantify major components of the nitrogen cycle which influence the ground and surface water pollution potential and the proper use of poultry or hen manure in a land application program. Both decomposition and N mineralization of representative samples of surface applied hen manure were evaluated. During the decomposition, N mineralization followed two patterns. Initially, N mineralization was rapid and the mineralized N plus initial inorganic N was converted to volatile ammonia and lost to the atmosphere. Later, one of two scenarios appeared to be operative. If nitrification and denitrification were small, then N illlllobilization likely occurred at a rate near that of N mineralization resulting in only small increases in inorganic N. Undigested feed was suggested as the inmobilizing agent. If nitrification and denitrification were large, then N mineralization could have proceeded at expected rates and would not be measured by the methods employed herein . In a practical vein, the initial inorganic N and mineralized N in surface applied hen manure has a low N fertilizer value and water pollution potential due to volatilization of N. If the manure is incorporated or a rainfall event occurs soon after surface addition, more than 50 percent of the manure N could be available for plant uptake and contamination of ground and surface waters

A Comparison of Rainfall Estimation Techniques

This study compares two techniques that have been developed for rainfall and streamflow estimation with the aim of identifying strengths and weaknesses of each. The first technique utilises thin plate smoothing splines to develop rainfall surfaces for the catchment, which are then, in conjunction with daily point-wise rainfall data used to determine areal catchment estimates. The second technique develops a regression-based model relating elevation to total annual rainfall in order to scale rainfall for daily mean catchment rainfall estimates. Both approaches are compared in common catchments in the upper Murrumbidgee catchment. The comparison includes using the data from each of the approaches as input to a rainfall-runoff model and by comparison of the quality of modelled results to observed streamflow. The strengths, weaknesses and use for catchment managers in decision making are identified. The study results revealed that where rain station spatial density and data quality are high, both regression and the spline method perform equally as well in estimating long term rainfall trends. In conclusion, catchment managers could apply the simple regression technique over the sophisticated spline method to achieve the comparable results. This is particularly useful where an efficient yet simple method is required for assessing streamflow within similar catchments

The Behavior of Soluble Salt in Sharkey Clay- II

Soluble salts have been shown to accumulate in Arkansas soils in sufficient quantities to impair crop plant growth. The major objective of this study was to describe the behavior of soluble chloride salt over long time periods in Sharkey clay - a major Mississippi Delta soil. Prior to flooding rice, leaching of chloride in response to rainfall was observed. The inclusion of a sandy subsoil layer reduced this effect presumably by limiting downward movement of water under unsaturated conditions. No lateral movement of the chloride salt was found during the period prior to flooding. Removal of soluble chloride salts from the top 100 cm of Sharkey soil was complete in a 1-2 year period depending on weather conditions. In a year where the rice cropping season was followed by a wet winter, losses were smaller than in a year where the rice cropping season was followed by a drier winter. These results suggested that removal of soluble salts via leaching in this soil was more efficient under less saturated soil conditions