634 research outputs found
Random laser from engineered nanostructures obtained by surface tension driven lithography
The random laser emission from the functionalized thienyl-S,S-dioxide
quinquethiophene (T5OCx) in confined patterns with different shapes is
demonstrated. Functional patterning of the light emitter organic material in
well defined features is obtained by spontaneous molecular self-assembly guided
by surface tension driven (STD) lithography. Such controlled supramolecular
nano-aggregates act as scattering centers allowing the fabrication of
one-component organic lasers with no external resonator and with desired shape
and efficiency. Atomic force microscopy shows that different geometric pattern
with different supramolecular organization obtained by the lithographic process
tailors the coherent emission properties by controlling the distribution and
the size of the random scatterers
Experimental evidence of replica symmetry breaking in random lasers
Spin-glass theory is one of the leading paradigms of complex physics and
describes condensed matter, neural networks and biological systems, ultracold
atoms, random photonics, and many other research fields. According to this
theory, identical systems under identical conditions may reach different states
and provide different values for observable quantities. This effect is known as
Replica Symmetry Breaking and is revealed by the shape of the probability
distribution function of an order parameter named the Parisi overlap. However,
a direct experimental evidence in any field of research is still missing. Here
we investigate pulse-to-pulse fluctuations in random lasers, we introduce and
measure the analogue of the Parisi overlap in independent experimental
realizations of the same disordered sample, and we find that the distribution
function yields evidence of a transition to a glassy light phase compatible
with a replica symmetry breaking.Comment: 10 pages, 5 figure
Casein haplotype variability in Sicilian dairy goat breeds
In the Mediterranean region, goat milk production is an important economic activity. In the present study, 4 casein genes were genotyped in 5 Sicilian goat breeds to 1) identify casein haplotypes present in the Argentata dell'Etna, Girgentana, Messinese, Derivata di Siria, and Maltese goat breeds; and 2) describe the structure of the Sicilian goat breeds based on casein haplotypes and allele frequencies. In a sample of 540 dairy goats, 67 different haplotypes with frequency >or=0.01 and 27 with frequency >or=0.03 were observed. The most common CSN1S1-CSN2-CSN1S2-CSN3 haplotype for Derivata di Siria and Maltese was FCFB (0.17 and 0.22, respectively), whereas for Argentata dell'Etna, Girgentana and Messinese was ACAB (0.06, 0.23, and 0.10, respectively). According to the haplotype reconstruction, Argentata dell'Etna, Girgentana, and Messinese breeds presented the most favorable haplotype for cheese production, because the casein concentration in milk of these breeds might be greater than that in Derivata di Siria and Maltese breeds. Based on a cluster analysis, the breeds formed 2 main groups: Derivata di Siria, and Maltese in one group, and Argentata dell'Etna and Messinese in the other; the Girgentana breed was between these groups but closer to the latter
Disease Activity and Progression in Multiple Sclerosis: New Evidences and Future Perspectives
Multiple sclerosis (MS) is a chronic, debilitating, autoimmune-mediated, inflammatory disease of the central nervous system (CNS), in which a combination of inflammation, demyelination and axonal degeneration takes place with extreme highly interpersonal variability [...]
An organic solution to the Kelvin myth?: White light with true color temperature via exciplex formation
Abstract Many white light sources are described as having a "color temperature", a practice that has been termed the "Kelvin myth", since, in general, only incandescent light-emitters have a spectral distribution which closely approximates that of a black-body curve. We show that the white light emitted, via exciplex formation, from blends of two blue-emitting organic materials, has the same spectral form as black-body light, as perceived by the human eye. The color temperature is tunable, depending on the relative concentrations of the two materials. This suggests that organics could provide a white light source with a tunable, true, color temperature
Surface morphology and optical properties of thin films of thiophene-based binary blends
We report on the relationship between optical and morphological properties of thin films of a blend of thiophene-based monomer and a diamine derivative. This system is of interest as it gives rise to white emission, due to the formation of exciplex energy levels in the solid state. The photoluminescence emission has been collected for different relative concentrations of the two blend components, and the film topography has been mapped correspondingly by means of atomic force microscopy. Along with a complex evolution of the film surface morphology, a significant variation of the emission properties has been observed upon change of the blend composition. In particular, the intensity of the broad low-energy exciplex band turns out to be affected by a balance of two factors, namely, the extension of homogeneous blend film areas, and their effective concentration
White light emission from blends of blue-emitting organic molecules: A general route to the white organic light-emitting diode?
We show that all possible binary combinations of molecules from four different families of organics - a diamine derivative, N,N′-bis(3methylphenyl)-N,N′-diphenylbenzidine, an oxidiazole derivative, 2-(4-biphenylyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole, a substituted thiophene dioxide, 2,5-bis(trimethylsilyl thiophene)-1,1-dioxide, and poly(9-vinylcarbazole) - produce white or near-white emission. We suggest that this is due to exciplex formation, and that this is likely to be a general phenomenon for blends of blue-emitting aromatic organics. This implies that films of spin-coated blends of blue-emitting organics represent a general, simple, and cheap route to white-emitting organic light-emitting diodes
Optimal maps and exponentiation on finite dimensional spaces with Ricci curvature bounded from below
We prove existence and uniqueness of optimal maps on spaces under the assumption that the starting measure is absolutely continuous. We also discuss how this result naturally leads to the notion of exponentiation. \ua9 2015, Mathematica Josephina, Inc
Calculus and heat flow in metric measure spaces and applications to spaces with Ricci bounds from below
This paper is devoted to a deeper understanding of the heat flow and to the
refinement of calculus tools on metric measure spaces (X,d,m). Our main results
are:
- A general study of the relations between the Hopf-Lax semigroup and
Hamilton-Jacobi equation in metric spaces (X,d).
- The equivalence of the heat flow in L^2(X,m) generated by a suitable
Dirichlet energy and the Wasserstein gradient flow of the relative entropy
functional in the space of probability measures P(X).
- The proof of density in energy of Lipschitz functions in the Sobolev space
W^{1,2}(X,d,m).
- A fine and very general analysis of the differentiability properties of a
large class of Kantorovich potentials, in connection with the optimal transport
problem.
Our results apply in particular to spaces satisfying Ricci curvature bounds
in the sense of Lott & Villani [30] and Sturm [39,40], and require neither the
doubling property nor the validity of the local Poincar\'e inequality.Comment: Minor typos corrected and many small improvements added. Lemma 2.4,
Lemma 2.10, Prop. 5.7, Rem. 5.8, Thm. 6.3 added. Rem. 4.7, Prop. 4.8, Prop.
4.15 and Thm 4.16 augmented/reenforced. Proof of Thm. 4.16 and Lemma 9.6
simplified. Thm. 8.6 corrected. A simpler axiomatization of weak gradients,
still equivalent to all other ones, has been propose
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