Highly absorbing black Mg and rare-earth-Mg switchable mirrors

Apart from a reflecting and a transparent state, rare-earth-Mg alloys (RE-Mg) exhibit also a highly absorbing, black state during loading with hydrogen. The occurrence of such a black state is due to the disproportionation into subwavelength size RE

Нелинейная нетерова краевая задача в критическом случае

Знайдено необхiднi та достатнi умови iснування розв’язкiв слабко нелiнiйної нетерової крайової задачi для системи звичайних диференцiальних рiвнянь у критичному випадку.We construct necessary and sufficient conditions for the existence of the solution of a Noether weakly nonlinear boundary-value problem for a system of ordinary differential equations in the critical case

Optical properties of MgH2 measured in situ in a novel gas cell for ellipsometry/spectrophotometry

The dielectric properties of alpha-MgH2 are investigated in the photon energy range between 1 and 6.5 eV. For this purpose, a novel sample configuration and experimental setup are developed that allow both optical transmission and ellipsometric measurements of a transparent thin film in equilibrium with hydrogen. We show that alpha-MgH2 is a transparent, colour neutral insulator with a band gap of 5.6 +/- 0.1 eV. It has an intrinsic transparency of about 80% over the whole visible spectrum. The dielectric function found in this work confirms very recent band structure calculations using the GW approximation by Alford and Chou [J.A. Alford and M.Y. Chou (unpublished)]. As Pd is used as a cap layer we report also the optical properties of PdHx thin films.Comment: REVTeX4, 15 pages, 12 figures, 5 table

Electrochromism of Mg-Ni hydride switchable mirrors

Switchable mirrors have so far been made of rare-earth and rare-earth-magnesium based metal-hydrides. In this investigation we study Mg-Ni-hydrides, which have been shown by Richardson et al. to exhibit switchable properties similar to those of the rare-earth hydrides. Cyclic voltammetry on MgzNiHx samples with 0.8 < z < 3.7 shows that addition of one Mg atom per Mg2Ni gives the best ab/desorption kinetics for hydrogen. X-ray diffraction reveals a structural change as hydrogen is absorbed. The metal-insulator transition is confirmed with simultaneous resistivity measurements. A pressure-composition isotherm of Mg2NiHx is also determined electrochemically. Optical spectrometry during gas loading gives an optical band gap of 1.6 eV for Mg2NiH4. This gap increases with increasing Mg content in a way similar to that of the Mg-doped rare-earth hydrides

Thermochromic metal-hydride bilayer devices

The temperature dependent optical properties of certain thin films are used in so-called thermochromic devices. As an alternative to a single layer of, e.g. V

The properties of pulsed laser deposited YH2 films for switchable devices

In-situ deposited Y

Self-Organized Layered Hydrogenation in Black Mg2NiHx Switchable Mirrors

In addition to a mirrorlike (Mg2Ni) and a transparent (Mg2NiH4) state, thin films of Mg2NiHx exhibit a remarkable black state with low reflection over the entire visible spectrum, essentially zero transmission and a low electrical resistivity. Such a black state is not explicable for a homogeneous layer since a large absorption coefficient always yields substantial reflection. We show that it results from a self-organized and reversible double layering of metallic Mg2NiH0.3 and semiconducting Mg2NiH4.

Structural, optical and electronic properties of LaMgHx switchable mirrors.

Structural, optical and electronic properties of lanthanum magnesium alloy thin films are studied in situ in real time during hydrogenation. X-ray data show that the as-deposited films contain the intermetallic phase LaMg with CsCl structure as well as fcc β-La and fcc La