A sustainable approach to the low-cost recycling of waste glass fibres composites towards circular economy

For practical applications, both environmental and economic aspects are highly required to consider in the development of recycling of fibre reinforced polymers (FRPs) encountering their end-of-life. Here, a sustainable, low cost, and efficient approach for the recycling of the glass fibre (GF) from GF reinforced epoxy polymer (GFRP) waste is introduced, based on a microwave-assisted chemical oxidation method. It was found that in a one-step process using microwave irradiation, a mixture of hydrogen peroxide (H2O2) as a green oxidiser and tartaric acid (TA) as a natural organic acid could be used to decompose the epoxy matrix of a waste GFRP up to 90% yield. The recycled GFs with ~92.7% tensile strength, ~99.0% Young\u27s modulus, and ~96.2% strain-to-failure retentions were obtained when compared to virgin GFs (VGFs). This short microwave irradiation time using these green and sustainable recycling solvents makes this a significantly low energy consumption approach for the recycling of end-of-life GFRPs

Multifunctional PA6 composites using waste glass fiber and green metal organic framework/graphene hybrids

Glass fiber-polyamide 6 (PA6) composites are widely used for various automotive applications, yet the ability to exhibit multifunctional properties and the cost of it remains challenging. Herein this work introduces a cost-effective approach for utilization of waste glass fiber (GF), green aluminium metal organic framework (Al-MOF), and industry-grade graphene nanoplatelets (GNPs) for the fabrication of multifunctional PA6 thermoplastic composites with enhanced mechanical performance and fire retardancy. The results demonstrate that hybrid filler of Al-MOF and GNPs have a synergistic effect in improving the mechanical properties and fire retardancy of GF reinforced PA6 composites. Compared to the neat PA6, the PA6 composite containing 20 wt% GFs, 5 wt% GNPs, and 5 wt% Al-MOF exhibited ~97% and ~93% improvements in tensile and flexural strength, respectively. Also, compared to the neat PA6, 27 and 55°C increases were observed in glass transition temperature (Tg) and heat deflection temperature, respectively. Thermal stability and fire retardancy of the GFs/PA6 composites were significantly improved when hybridized with GNPs and Al-MOF

Effect of matrix modification and fiber surface treatment on the properties of basalt fiber reinforced polypropylene composites

With a focus on sustainable natural fiber reinforced polypropylene composites in varied industries like automotive and aerospace, this study investigates the impact of matrix modification and surface treatment of basalt fibers on the thermomechanical properties of basalt fiber reinforced heterophasic polypropylene composites. Polypropylene matrix modification was achieved by adding maleic anhydride grafted polypropylene (PP-g-MA), resulting in composites that exhibited a 133 % improvement in the tensile strength and 256 % improvement in the tensile modulus at 30 % fiber weight compared to neat polypropylene. The short basalt fibers underwent a silane treatment; However, the thermal treatment used to strip the default manufacturer's sizing resulted in a fluffy fibres texture, which led to agglomeration and feeding issues during processing. Although the silane treatment helped establish a better fiber-matrix interphase, no significant improvement in tensile strength was observed. However, the tensile modulus saw a 343 % improvement at 30 % fiber weight as compared to neat polypropylene. Resizing short basalt fibers following fiber recovery at the end-of-life stage of the composite would be challenging due to the fluffy nature of the fibers. Therefore, any fiber treatment should be done at the initial fiber manufacturing stage, and surface treatment at later stages requires detailed study