Impact of SARS-CoV-2 on ambient air particulate matter in Tehran

The pandemic caused by severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) has indirectly produced both positive and negative effects on the environment, particularly in terms of air quality. Our study aimed to determine these effects in the city of Tehran by comparing the ambient PM2.5 and PM10 levels recorded at 22 air quality monitoring stations during the outbreak (20 February–2 April 2020) with those from the corresponding period last year (20 February–3 April 2019). Contrary to expectation, the average concentrations of both the PM2.5 and the PM10 were markedly higher during the former, increasing by 20.5% and 15.7%, respectively, for the first month of the outbreak (20 February–19 March 2020) and by 23.5% and 20.0% for the subsequent Nowruz New Year holidays (from late March till early April), which resulted in overall increases of 20.5% and 16.5% for the entire period. The non-integrated responses to the pandemic, including the failure to close administrative centers and, in particular, the recommendation to maintain social distancing by reducing public transportation use (prompting citizens to travel by private vehicle), have worsened the ambient air quality in Tehran, providing an exceptional opportunity to evaluate the direct/indirect influence of air quality policies and emission control measures on PM2.5 and PM10. Because of the significant association between the lethality of coronavirus disease 2019 (COVID-19) and exposure to ambient air pollution, the rise in airborne PM2.5 during this outbreak may increase the mortality rate of SARS-CoV-2.</p

Effect of salinity on the potential cadmium phytoremediation from the polluted soil by carpobrotus rossii

Nowadays, toxic metals accumulation in soil texture due to anthropogenic activities is a major form of pollution, which can lead to worldwide concerns; however, there are many treatment methods to remove them from soil such as phytoremediation. The carpobrotus rossii, has shown great potential to tolerate high salinity and accumulate Cd from contaminated soils. The experiments, in this study, are analyzed and optimized by Central Composite Design (CCD) as method and using Response Surface Methodology (RSM) package in R software. The Cd removal by root and the whole plant followed the quadratic model and the R2 values were 94.95 and 94.81, respectively. The results showed that a decrease in NaCl concentration in Cd-containing solution can increase the phytoremediation process of Cd by carpobrotus rossii, significantly. The optimum conditions for 58% Cd removal by the whole plant, predicted through a CCD response surface methodology model were as follows: initial Cd concentration of 49 mgKg−1,NaCl concentration of 16 dSm−1, time of 17 days, and pH of 6.5. C. rossii's potential in removing 58% of Cd under the obtained optimum condition from the modelling was evaluated in real condition in the laboratory. The results revealed that around 56% of the initial added Cd concentration was removed by carpobrotus rossii. As a take home message, carpobrotus rossii can be recommended as an efficient plant to remove heavy metals especially cadmium from soil and sediments in arid area which have a salty soil

Adsorptive removal of anthracene from water by biochar derived amphiphilic carbon dots decorated with chitosan

Anthracene belongs to the polycyclic aromatic hydrocarbon (PAH) consisting of benzene rings, unusually highly stable through more π-electrons and localized π-bond in entire rings. Aqueous-phase anthracene adsorption using carbon-based materials such as biochar is ineffective. In this paper, carbon dots (CDs) derived from the acid treatment of coconut shell biochar (CDs/MCSB) decorated with chitosan (CS) are successfully synthesized and applied for anthracene removal from aqueous solutions. The h-CDs/MCSB exhibited fast adsorption of anthracene with significant sorption capacity (Qmax = 49.26 mg g−1) with 95 % removal efficiency at 60 min. The study suggested chemisorption dominated monolayer anthracene adsorption onto h-CDs/MCSB, where a significant role was played by ion-exchange. Density Functional Theory (DFT) suggested the anthracene adsorption was dominated by the electrostatic interactions and delocalized electron, induced by higher polarizability of functional groups on the surface of hybrid CDs/MCSB assisted by chitosan (h-CDs/MCSB). In addition, the aromatic structure of CDs/MCSB and high polarizability of functional groups provided the strong interactions between benzene rings of anthracene and hybrid adsorbent-assisted multiple π-bond through delocalized π-bond and polarization-induced H-bond interactions. The presence of carboxylic and sulfonic groups on the CDs/MCSB surface also contributed to the effective adsorption of anthracene was confirmed by the fluorescence spectra. The results showed that the hybrid adsorbent was an effective material for removing PAHs, usually difficult to remove from water owing to the presence of benzene rings in their structures. Further, consistency in the DFT results suggested the outstanding binding capacity with the anthracene molecules with h-CDs/MCSB