Narrowband Near-Infrared Perovskite/Organic Photodetector: TCAD Numerical Simulation

Narrowband photodetectors (PD) established in the near-infrared (NIR) wavelength range are highly required in a variety of applications including high-quality bioimaging. In this simulation study, we propose a filter-less narrowband PD based on the architecture of perovskite/organic heterojunction. The most decisive part of the photodetector is the hierarchical configuration of a larger bandgap perovskite material with a thicker film followed by a lower bandgap organic material with a narrower layer. The design of the structure is carried out by TCAD numerical simulations. Our structure is based on an experimentally validated wideband organic PD, which is modified by invoking an additional perovskite layer having a tunable bandgap. The main detector device comprises of ITO/perovskite (CsyFA1−yPb(IxBr1−x)3)/organic blend (PBDTTT-c:C60-PCBM)/PEDOT:PSS/Al. The simulation results show that the proposed heterojunction PD achieves satisfactory performance when the thickness of perovskite and organic layers are 2.5 µm and 500 nm, respectively. The designed photodetector achieves a narrow spectral response at 730 nm with a full width at half-maximum (FWHM) of 33 nm in the detector, while having a responsivity of about 0.12 A/W at zero bias. The presented heterojunction perovskite/organic PD can efficiently detect light in the wavelength range of 700 to 900 nm. These simulation results can be employed to drive the development of filter-less narrowband NIR heterojunction PD

Oil Palm Biomass Sap-Rotten Rice as a Source to Remove Metal Ions and Generate Electricity as By-Products through Microbial Fuel Cell Technology

Microbial fuel cell (MFC) is a new and interesting technology that can be used to treat wastewater without using electricity. The current research focuses on electron generation, which is one of the technique’s major challenges. According to the latest literature, the study was planned to successfully remove the metals from artificial wastewater at high concentrations and generate electricity. On average, after 18 days of operation, it offered 610 mV with 1000 ῼ constant external resistance. The internal resistance was found to be 520 ῼ. The achieved power density was 3.164 mW/m2 at an external resistance of 1000 ῼ. The achieved removal efficiencies of Pb2+, Cd2+, Cr3+, and Ni2+ were 83.67%, 84.10%, 84.55%, and 95.99%, respectively. The operation lasted for 25 days. The cyclic voltameter studies show that there is a gradual oxidation rate of organic substances, while on day 25, the removal efficiency reached its maximum. The specific capacitance was found to be high between days 15 and 20, i.e., 0.0000540 F/g. It also indicated that biofilm was stable around day 18. Furthermore, the biological characterization also demonstrated that MFC operation was very smooth throughout the process, even at high concentrations (100 mg/L) of metal ions. Finally, there is the MFC method, as well as some new challenges and future recommendations

Advancement in Microbial Fuel Cells Technology by Using Waste Extract as an Organic Substrate to Produce Energy with Metal Removal

Energy generation using microbial fuel cells (MFC) and removing toxic metal ions is a potentially exciting new field of study as it has recently attracted a lot of interest in the scientific community. However, MFC technology is facing several challenges, including electron production and transportation. Therefore, the present work focuses on enhancing electron generation by extracting sugarcane waste. MFC was successfully operated in a batch mode for 79 days in the presence of 250 mg/L Pb2+ and Hg2+ ions. Sugarcane extract was regularly fed to it without interruption. On day 38, the maximum current density and power density were recorded, which were 86.84 mA/m2 and 3.89 mW/m2, respectively. The electrochemical data show that a sufficient voltage generation and biofilm formation produce gradually. The specific capacitance was found to be 11 × 10−4 F/g on day 79, indicating the steady growth of biofilm. On the other hand, Pb2+ and Hg2+ removal efficiencies were found to be 82% and 74.85%, respectively. Biological investigations such as biofilm analysis and a recent literature survey suggest that conductive-type pili species can be responsible for energy production and metal removal. The current research also explored the oxidation method of sugarcane extract by bacterial communities, as well as the metal removal mechanism. According to the parameter optimization findings, a neutral pH and waste produced extract can be an optimal condition for MFC operation

Green Synthetized Selenium Nanoparticles Using <i>Syzygium aromaticum</i> (Clove) Extract Reduce Pentylenetetrazol-Induced Epilepsy and Associated Cortical Damage in Rats

We aimed to investigate the potential anticonvulsant effect of green synthetized selenium nanoparticles (SeNPs) using Syzygium aromaticum extract (SAE) (SAE-SeNPs) against epileptic seizures and cortical damage induced by pentylenetetrazole (PTZ) injection in rats and its mechanism. A total of 84 rats were divided into six groups; control, PTZ-exposed group, SAE + PTZ-treated group, sodium selenite (Na2SeO3) + PTZ-treated group, SAE-SeNPs + PTZ-treated group, and diazepam + PTZ-treated group. SAE-SeNPs significantly increase (p p p p < 0.05) the PTZ-induced changes in the neurotransmitter norepinephrine level and acetylcholinesterase enzymatic activity. These data concluded the anticonvulsant activity of SAE-SeNPs via their antioxidant, anti-inflammatory, and anti-apoptotic effects, along with their ability to modulate neurotransmitters