Carrier multiplication yields in PbS and PbSe nanocrystals measured by transient photoluminescence

We report here an assessment of carrier multiplication (CM) yields in PbSe and PbS nanocrystals (NCs) by a quantitative analysis of biexciton and exciton dynamics in transient photoluminescence decays. Interest in CM, the generation of more than one electron and hole in a semiconductor after absorption of one photon, has renewed in recent years because of reports suggesting greatly increased efficiencies in nanocrystalline materials compared to the bulk form, in which CM was otherwise too weak to be of consequence in photovoltaic energy conversion devices. In our PbSe and PbS NC samples, however, we estimate using transient photoluminescence that at most 0.25 additional e-h pairs are generated per photon even at energies hv > 5Eg, instead of the much higher values reported in the literature. We argue by comparing NC CM estimates and reported bulk values on an absolute energy basis, which we justify as appropriate on physical grounds, that the data reported thus far are inconclusive with respect to the importance of nanoscale-specific phenomena in the CM process.Comment: 10 pages, 7 figure

Coordinate Singularities in Harmonically-sliced Cosmologies

Harmonic slicing has in recent years become a standard way of prescribing the lapse function in numerical simulations of general relativity. However, as was first noticed by Alcubierre (1997), numerical solutions generated using this slicing condition can show pathological behaviour. In this paper, analytic and numerical methods are used to examine harmonic slicings of Kasner and Gowdy cosmological spacetimes. It is shown that in general the slicings are prevented from covering the whole of the spacetimes by the appearance of coordinate singularities. As well as limiting the maximum running times of numerical simulations, the coordinate singularities can lead to features being produced in numerically evolved solutions which must be distinguished from genuine physical effects.Comment: 21 pages, REVTeX, 5 figure

General approach for studying first-order phase transitions at low temperatures

By combining different ideas, a general and efficient protocol to deal with discontinuous phase transitions at low temperatures is proposed. For small $T$'s, it is possible to derive a generic analytic expression for appropriate order parameters, whose coefficients are obtained from simple simulations. Once in such regimes simulations by standard algorithms are not reliable, an enhanced tempering method, the parallel tempering -- accurate for small and intermediate system sizes with rather low computational cost -- is used. Finally, from finite size analysis, one can obtain the thermodynamic limit. The procedure is illustrated for four distinct models, demonstrating its power, e.g., to locate coexistence lines and the phases density at the coexistence.Comment: 5 page

Non-Hermitian oscillator Hamiltonian and su(1,1): a way towards generalizations

The family of metric operators, constructed by Musumbu {\sl et al} (2007 {\sl J. Phys. A: Math. Theor.} {\bf 40} F75), for a harmonic oscillator Hamiltonian augmented by a non-Hermitian $\cal PT$-symmetric part, is re-examined in the light of an su(1,1) approach. An alternative derivation, only relying on properties of su(1,1) generators, is proposed. Being independent of the realization considered for the latter, it opens the way towards the construction of generalized non-Hermitian (not necessarily $\cal PT$-symmetric) oscillator Hamiltonians related by similarity to Hermitian ones. Some examples of them are reviewed.Comment: 11 pages, no figure; changes in title and in paragraphs 3 and 5; final published versio

Lifshitz-type formulas for graphene and single-wall carbon nanotubes: van der Waals and Casimir interations

Lifshitz-type formulas are obtained for the van der Waals and Casimir interaction between graphene and a material plate, graphene and an atom or a molecule, and between a single-wall carbon nanotube and a plate. The reflection properties of electromagnetic oscillations on graphene are governed by the specific boundary conditions imposed on the infinitely thin positively charged plasma sheet, carrying a continuous fluid with some mass and charge density. The obtained formulas are applied to graphene interacting with Au and Si plates, to hydrogen atoms and molecules interacting with graphene, and to single-wall carbon nanotubes interacting with Au and Si plates. The generalizations to more complicated carbon nanostructures are discussed.Comment: 11 pages, 5 figures, 2 tables; to appear in Phys. Rev. B; misprints in Eqs.(33) and (34) are correcte

Moyal products -- a new perspective on quasi-hermitian quantum mechanics

The rationale for introducing non-hermitian Hamiltonians and other observables is reviewed and open issues identified. We present a new approach based on Moyal products to compute the metric for quasi-hermitian systems. This approach is not only an efficient method of computation, but also suggests a new perspective on quasi-hermitian quantum mechanics which invites further exploration. In particular, we present some first results which link the Berry connection and curvature to non-perturbative properties and the metric.Comment: 14 pages. Submitted to J Phys A special issue on The Physics of Non-Hermitian Operator