Dispersed fs-FWM for Investigations of Low Frequency Vibrations of Transient Species in Combustion

Understanding the role of peroxides in combustion, in atmospheric and in surface science involves investigations on a molecular level, at which energy transfers and rearrangements of the nuclei dictate the chemistry. Due to their high reactivity they appear as unstable transient species, which impedes detailed spectroscopic investigations. Low frequency modes, especially internal and hindered rotations with energies less than 200 cm-1 play an important role for the determination of molecular energies and reaction rates. Unfortunately, these motions are in general difficult to address. Femtosecond four-wave mixing (fs-FWM) is a powerful tool that allows for investigations of ground state dynamics of molecules. The high peak-power output of fs-lasers, facilitates the excitation of weak Raman coherences. Results from the combustion relevant di-tert-butyl peroxide molecule are exemplified

Evolution of submarine canyon-fan systems in fault-controlled margins: Insights from physical experiments

Different fault settings make the morphology of submarine canyon-fan systems on active margins complex and diverse. In this study we explore the continuum of erosion, transport and sedimentation processes taking place in fault-controlled canyon-fan systems by using physical experiments and a morphodynamic model. Based on morphometric analyses we show how Hack's scaling relationships exist in submarine canyons and fans. The DEM of differences (DoDs) demonstrate the growth patterns and allow to establish relevant relationships between volumes of canyons and their corresponding fans. We reveal strong self-similarities on canyon-fan long profiles and, through a new morphodynamic model, we capture their evolution over time, including the trajectory of internal moving boundaries. We observe that fault slip rate controls the merging speed of coalescent submarine canyon-fan systems and, when coupling fault slip rate with inflow discharge, a competitive influence arises. In this study we also uncover scaling relationships spanned from laboratory to field-scale. Overall, our findings are inspiring and valuable for field investigators and modelers to better interpret and predict the morphological evolution and sedimentary processes of submarine canyon-fan systems in active fault settings

Analysis of Radicals in Combustion Processes

This work reports on a variety of radical analysis applications in combustion that are performed in the laboratories of the Paul Scherrer Institute. Planar Laser-Induced Fluorescence and Resonant Holographic Interferometry is applied to the two-dimensional imaging of radicals in flames. The potential of Four-Wave Mixing Spectroscopy for non-perturbing combustion diagnostics is investigated and the method is applied to radicals in flames. Phase-Conjugation and the use of two different input frequencies are utilized to address typical problems in a combustion environment, i.e., lensing effects due to temperature and density gradients and congested spectra of the analyte due to significant thermal population of the ground state.More fundamentally, experiments are aimed to obtain detailed knowledge on the spectroscopy of many important radicals that are not yet characterized sufficiently for diagnostic purposes. A molecular beam apparatus has been set up where the collisionless and cold environment provides well defined experimental conditions to produce and investigate the relevant radicals. Finally, temporally and spectrally resolved fluorescence decays in the picosecond time domain are measured in an atmospheric pressure flame. These experiments yield results on vibrational and rotational energy transfer that are required for quantitative laser-induced fluorescence measurements

2-(2-Benzyl­phen­yl)propan-2-ol

There are two mol­ecules in the asymmetric unit of the title compound, C16H18O, a tertiary alcohol featuring a 2-benzyl­phenyl substituent. Co-operative O—H⋯O hydrogen bonds connect the mol­ecules into tetra­mers

Transient erosion in the Valencia Trough turbidite systems, NW Mediterranean Basin

12 pages, 9 figuresSubmarine canyons can efficiently drain sediments from continental margins just as river systems do in subaerial catchments. Like in river systems, submarine canyons are often arranged as complex drainage networks that evolve from patterns of erosion and deposition. In the present paper we use a morphometric analysis of submarine canyon-channel long-profiles to study the recent sedimentary history of the Valencia Trough turbidite system (VTTS) in the NW Mediterranean Sea. The VTTS is unique in that it drains sediment from margins with contrasting morphologies through a single “trunk” conduit, the Valencia Channel. The Valencia Channel has been active since the late Miocene, evolving in response to Plio-Quaternary episodes of erosion and deposition. The integrated analysis of long-profiles obtained from high-resolution bathymetric data across the entire turbidite system shows evidence for transient canyon incision in the form of knickpoints and hanging tributaries. Multiple factors appear to have triggered these periods of incision. These include a large debris flow at 11,500 yr BP that disrupted the upper reaches of the VTTS and glacio-eustatic lowstands that forced shifting of sediment input to the VTTS. Based on these inferences, long-term time-averaged incision rates for the Valencia Channel have been estimated. The evidence we present strongly suggests that Foix Canyon has played a key role in the drainage dynamics of the VTTS in the past. This study builds conceptually on a recent modeling study that provides a morphodynamic explanation for the long-term evolution of submarine canyon thalweg profiles. The procedure and results from this work are of potential application to other submarine sediment drainage systems, past and present, including those containing mid-ocean type valleys like the Valencia ChannelThis research was supported by the HERMIONE project, EC contract 226354-HERMIONE, funded by the European Commission's Seventh Framework Programme, and the HERMES Project, EC contract GOCE-CT-2005-511234, funded by the European Commission's Sixth Framework Programme under the priority “Sustainable Development, Global Change and Ecosystems”. It has also benefited from inputs by the PROMETEO (CTM2007-66316-C02-01/MAR), EDINSED3D (CTM2007-64880/MAR), and the GRACCIE CONSOLIDER (CSD2007-00067) projects, funded by the Spanish RTD Programme. GRC Geociències Marines is supported by Generalitat de Catalunya “Grups de Recerca Consolidats” grant 2009 SGR 1305Peer reviewe

Crystal isomorphisms in Fock spaces and Schensted correspondence in affine type A

We are interested in the structure of the crystal graph of level $l$ Fock spaces representations of $\mathcal{U}_q (\widehat{\mathfrak{sl}_e})$. Since the work of Shan [26], we know that this graph encodes the modular branching rule for a corresponding cyclotomic rational Cherednik algebra. Besides, it appears to be closely related to the Harish-Chandra branching graph for the appropriate finite unitary group, according to [8]. In this paper, we make explicit a particular isomorphism between connected components of the crystal graphs of Fock spaces. This so-called "canonical" crystal isomorphism turns out to be expressible only in terms of: - Schensted's classic bumping procedure, - the cyclage isomorphism defined in [13], - a new crystal isomorphism, easy to describe, acting on cylindric multipartitions. We explain how this can be seen as an analogue of the bumping algorithm for affine type $A$. Moreover, it yields a combinatorial characterisation of the vertices of any connected component of the crystal of the Fock space

Financing Direct Democracy: Revisiting the Research on Campaign Spending and Citizen Initiatives

The conventional view in the direct democracy literature is that spending against a measure is more effective than spending in favor of a measure, but the empirical results underlying this conclusion have been questioned by recent research. We argue that the conventional finding is driven by the endogenous nature of campaign spending: initiative proponents spend more when their ballot measure is likely to fail. We address this endogeneity by using an instrumental variables approach to analyze a comprehensive dataset of ballot propositions in California from 1976 to 2004. We find that both support and opposition spending on citizen initiatives have strong, statistically significant, and countervailing effects. We confirm this finding by looking at time series data from early polling on a subset of these measures. Both analyses show that spending in favor of citizen initiatives substantially increases their chances of passage, just as opposition spending decreases this likelihood

Disease, activity and schoolchildren's health (DASH) in Port Elizabeth, South Africa: a study protocol

BACKGROUND: An in-depth epidemiological investigation on intestinal parasite infections in an impoverished area of Port Elizabeth, South Africa provides a unique opportunity for research on its impact on children's physical fitness, cognitive performance and psychosocial health. Additionally, we will screen risk factors for the development of diabetes and hypertension in adulthood. METHODS/DESIGN: A 2-year longitudinal cohort study will be conducted, consisting of three cross-sectional surveys (baseline and two follow-ups), in eight historically black and coloured (mixed race) primary schools located in different townships in Port Elizabeth, South Africa. Approximately 1000 Grade 4 primary schoolchildren, aged 8 to 12 years, will be enrolled and followed. At each survey, disease status, anthropometry and levels of physical fitness, cognitive performance and psychosocial health will be assessed. After each survey, individuals diagnosed with parasitic worm infections will be treated with anthelminthic drugs, while children with other infections will be referred to local clinics. Based on baseline results, interventions will be tailored to the local settings, embedded within the study and implemented in half of the schools, while the remaining schools will serve as controls. Implementation of the interventions will take place over two 8-week periods. The effect of interventions will be determined with predefined health parameters. DISCUSSION: This study will shed new light on the health burden incurred by children in deprived urban settings of South Africa and provide guidance for specific health interventions. Challenges foreseen in the conduct of this study include: (i) difficulty in obtaining written informed consent from parents/guardians; (ii) administration of questionnaires in schools where three languages are spoken (Afrikaans, Xhosa and English); (iii) challenges in grasping concepts of psychosocial health among schoolchildren using a questionnaire; and (iv) loss to follow-up due to the study setting where illiteracy, mobility and violence are common. Finally, designing the health interventions together with local principals and teachers will allow all concerned with the research to bolster a sense of community ownership and sustained use of the interventions after the study has ceased

Agricultural climate change mitigation : Carbon calculators as a guide for decision making

This is an Accepted Manuscript of an article published by Taylor & Francis Group in International Journal of Agricultural Sustainability on 9 November 2017, available online: https://doi.org/10.1080/14735903.2017.1398628. Under embargo. Embargo end date: 9 November 2018.The dairy industry is receiving considerable attention in relation to both its significant greenhouse gas (GHG) emissions, and it’s potential for reducing those emissions, contributing towards meeting national targets and driving the industry towards sustainable intensification. However, the extent to which improvements can be made is dependent on the decision making processes of individual producers, so there has been a proliferation of carbon accounting tools seeking to influence those processes. This paper evaluates the suitability of such tools for driving environmental change by influencing on-farm management decisions. Seven tools suitable for the European dairy industry were identified, their characteristics evaluated, and used to process data relating to six scenario farms, emulating process undertaken in real farm management situations. As a result of the range of approaches taken by the tools, there was limited agreement between them as to GHG emissions magnitude, and no consistent pattern as to which tools resulted in the highest/lowest results. Despite this it is argued, that as there was agreement as to the farm activities responsible for the greatest emissions, the more complex tools were still capable of performing a ‘decision support’ role, and guiding management decisions, whilst others could merely focus attention on key issues.Peer reviewe