3,686 research outputs found
7.2% efficient polycrystalline silicon photoelectrode
After etching, n-type cast polycrystalline silicon photoanodes immersed in a solution of methanol and a substituted ferrocene reagent exhibit photoelectrode efficiencies of 7.2%±0.7% under simulated AM2 illumination. Scanning laser spot data indicate that the grain boundaries are active; however, the semiconductor/liquid contact does not display the severe shunting effects which are observed at a polycrystalline Si/Pt Schottky barrier. Evidence for an interfacial oxide on the operating polycrystalline Si photoanode is presented. Some losses in short circuit current can be ascribed to bulk semiconductor properties; however, despite these losses, photoanodes fabricated from polycrystalline substrates exhibit efficiencies comparable to those of single crystal material. Two major conclusions of our studies are that improved photoelectrode behavior in the polycrystalline silicon/methanol system will primarily result from changes in bulk electrode properties and from grain boundary passivation, and that Fermi level pinning by surface states does not prevent the design of efficient silicon-based liquid junctions
A 14% efficient nonaqueous semiconductor/liquid junction solar cell
We describe the most efficient semiconductor/liquid junction solar cell reported to date. Under Wâhalogen (ELH) illumination, the device is a 14% efficient twoâelectrode solar cell fabricated from an nâtype silicon photoanode in contact with a nonaqueous electrolyte solution. The cellâČs central feature is an ultrathin electrolyte layer which simultaneously reduces losses which result from electrode polarization, electrolyte light absorption, and electrolyte resistance. The thin electrolyte layer also eliminates the need for forced convection of the redox couple and allows for precise control over the amount of water (and other electrolyte impurities) exposed to the semiconductor. After one month of continuous operation under ELH light at 100 mW/cm^2, which corresponds to the passage of over 70â000 C/cm^2, thinâlayer cells retained over 90% of their efficiency. In addition, when made with Wacker Silso cast polycrystalline Si, cells yield an efficiency of 9.8% under simulated AMl illumination. The thinâlayer cells employ no external compensation yet surpass their corresponding experimental (threeâelectrode) predecessors in efficiency
Solar energy conversion
If solar energy is to become a practical alternative to fossil fuels, we must have efficient ways to convert photons into electricity, fuel, and heat. The need for better conversion technologies is a driving force behind many recent developments in biology, materials, and especially nanoscience
Constraints in Quantum Geometrodynamics
We compare different treatments of the constraints in canonical quantum
gravity. The standard approach on the superspace of 3--geometries treats the
constraints as the sole carriers of the dynamic content of the theory, thus
rendering the traditional dynamical equations obsolete. Quantization of the
constraints in both the Dirac and ADM square root Hamiltonian approaches leads
to the well known problems of time evolution. These problems of time are of
both an interpretational and technical nature. In contrast, the geometrodynamic
quantization procedure on the superspace of the true dynamical variables
separates the issues of quantization from the enforcement of the constraints.
The resulting theory takes into account states that are off-shell with respect
to the constraints, and thus avoids the problems of time. We develop, for the
first time, the geometrodynamic quantization formalism in a general setting and
show that it retains all essential features previously illustrated in the
context of homogeneous cosmologies.Comment: 36 pages, no figures, submitted to IJMPA, Rewording, Fixed Typo
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Magnetic Levitation as a Platform for Competitive ProteinâLigand Binding Assays
This paper describes a method based on magnetic levitation (MagLev) that is capable of indirectly measuring the binding of unlabeled ligands to unlabeled protein. We demonstrate this method by measuring the affinity of unlabeled bovine carbonic anhydrase (BCA) for a variety of ligands (most of which are benzene sulfonamide derivatives). This method utilizes porous gel beads that are functionalized with a common aryl sulfonamide ligand. The beads are incubated with BCA and allowed to reach an equilibrium state in which the majority of the immobilized ligands are bound to BCA. Since the beads are less dense than the protein, protein binding to the bead increases the overall density of the bead. This change in density can be monitored using MagLev. Transferring the beads to a solution containing no protein creates a situation where net protein efflux from the bead is thermodynamically favorable. The rate at which protein leaves the bead for the solution can be calculated from the rate at which the levitation height of the bead changes. If another small molecule ligand of BCA is dissolved in the solution, the rate of protein efflux is accelerated significantly. This paper develops a reaction-diffusion (RD) model to explain both this observation, and the physical-organic chemistry that underlies it. Using this model, we calculate the dissociation constants of several unlabeled ligands from BCA, using plots of levitation height versus time. Notably, although this method requires no electricity, and only a single piece of inexpensive equipment, it can measure accurately the binding of unlabeled proteins to small molecules over a wide range of dissociation constants (Kd values within the range from 10 nM to 100 ÎŒM are measured easily). Assays performed using this method generally can be completed within a relatively short time period (20 minâ2 h). A deficiency of this system is that it is not, in its present form, applicable to proteins with molecular weight greater than approximately 65 kDa.Chemistry and Chemical Biolog
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