Prediction of estuarine morphological evolution

Estuaries are vital environmental and economic resources, providing habitat for thousands of species, absorbing runoff, and supporting recreation and commerce. Yet, despite their importance, estuaries are threatened by human activities. Empirical Orthogonal Function (EOF) analysis and Cross Spectral techniques were used in the analysis and prediction of estuarine morphology. The estuaries selected for study were Suisun Bay, CA and Mobile Bay, AL. It was found that EOF is an effective and efficient technique to analyze morphology, a coupling with cross spectral methods such as Fourier Transformation (FFT) resulted in determination of forcing functions responsible for imparting variance to the bathymetry. In both the estuaries it was found that the first two eigenvalues represented almost 80% of the morphological/bathymetric dataset. The second eigenfunction was found to be closely dependent on the freshwater inflows to the estuaries. EOF analysis on Suisun Bay revealed that the bay is depositional particularly in the shallow bays of Honker and Grizzly, whereas the main channels as well as Carquinez Straits maintained their depths throughout the period studied. Utilizing a Cross spectral technique, Amplitude Response Function (ARF), temporal eigenfunctions for the bay were determined for year 2100. The temporal eigenfunctions were predicted for cases where river inflows to the bay were varied by 1 standard deviation unit. These predicted eigenfunction values combined with the eigenvalues resulted in the recovery of predicted depths for year 2100. It was found that Suisun Bay remains depositional through the year 2100 and maintains depths in the main channels as well as Carquinez Straits. This depositional behavior results in the decrease of bay volume to almost 40% of the volume in 1989. EOF analysis on Mobile Bay revealed that the bay is predominantly depositional except in the navigation channel and the shoreline of the Bay. The navigation channel maintaining it depth is attributed to the regular dredging carried to facilitate shipping. The second temporal eigenfunction showed a close correlation with river inflows as in the case of Suisun Bay. However, a cross correlation performed on the second temporal eigenfunction and inflows revealed that the response of the eigenfunction is perturbed by almost 9 years, as opposed to 6 to 9 years for Suisun Bay. An ARF on the temporal eigenfunctions combined with a reverse EOF resulted in the formation of bathymetric datasets for the year 2100 for inflows variation of 1 standard deviation. It was revealed that increasing the flows results in an increase of bay volume by approximately 30% and a decrease in flows results in a loss of volume by approximately 20%

Combined Ozone and Ultraviolet Inactivation of Escherichia Coli

The kinetics of Escherichia coli inactivation were studied using ultraviolet (UV) radiation, ozone, and UV and ozone (UVO) in combination in a batch reactor at varying pH levels (6, 7, and 8) and at a constant temperature of 25°C. The inactivation kinetics for all three treatment processes was pseudo first order, and the reaction rate constants were considered to be additive such that a combined reaction rate could be obtained by adding the kinetic rates of the processes applied and numerically small rates could be neglected in the computation of the combined rate. Statistical tests (ANOVA and student\u27s t-test) performed on the inactivation data indicated no apparent effect of pH on the kinetics of the processes. It was found that the UVO process was the most efficient in inactivating E. coli. The increase in the inactivation rate with the UVO process is attributed to synergetic activity of UV and ozone which results in the generation of hydroxyl radicals from ozone decomposition

Tidal Hydrodynamics in the Lower Columbia River Estuary through Depth Averaged Adaptive Hydraulics Modeling

The adaptive hydraulics (AdH) numerical code was applied to study tidal propagation in the Lower Columbia River (LCR) estuary. The results demonstrate the readiness of this AdH model towards the further study of hydrodynamics in the LCR. The AdH model accurately replicated behavior of the tide as it propagated upstream into the LCR system. Results show that the MSf tidal component and the M4 overtidal component are generated in the middle LCR and contain a substantial amount of tidal energy. An analysis was performed to determine the causes of MSf tide amplification, and it was found that approximately 80% of the amplification occurs due to nonlinear interaction between the M2 and the S2 tidal components

Evaluation of Sterculia foetida Gum as Controlled Release Excipient

The purpose of the research was to evaluate Sterculia foetida gum as a hydrophilic matrix polymer for controlled release preparation. For evaluation as a matrix polymer; characterization of Sterculia foetida gum was done. Viscosity, pH, scanning electronmicrographs were determined. Different formulation aspects considered were: gum concentration (10–40%), particle size (75–420 μm) and type of fillers and those for dissolution studies; pH, and stirring speed were considered. Tablets prepared with Sterculia foetida gum were compared with tablets prepared with Hydroxymethylcellulose K15M. The release rate profiles were evaluated through different kinetic equations: zero-order, first-order, Higuchi, Hixon-Crowell and Korsemeyer and Peppas models. The scanning electronmicrographs showed that the gum particles were somewhat triangular. The viscosity of 1% solution was found to be 950 centipoise and pH was in range of 4–5. Suitable matrix release profile could be obtained at 40% gum concentration. Higher sustained release profiles were obtained for Sterculia foetida gum particles in size range of 76–125 μm. Notable influences were obtained for type of fillers. Significant differences were also observed with rotational speed and dissolution media pH. The in vitro release profiles indicated that tablets prepared from Sterculia foetida gum had higher retarding capacity than tablets prepared with Hydroxymethylcellulose K15M prepared tablets. The differential scanning calorimetry results indicated that there are no interactions of Sterculia foetida gum with diltiazem hydrochloride. It was observed that release of the drug followed through surface erosion and anomalous diffusion. Thus, it could be concluded that Sterculia foetida gum could be used a controlled release matrix polymer