A W:B4C multilayer phase retarder for broadband polarization analysis of soft x-ray radiation \ud

A W:B4C multilayer phase retarder has been designed and characterized which shows a nearly constant phase retardance between 640 and 850 eV photon energies when operated near the Bragg condition. This freestanding transmission multilayer was used successfully to determine, for the first time, the full polarization vector at soft x-ray energies above 600 eV, which was not possible before due to the lack of suitable optical elements. Thus, quantitative polarimetry is now possible at the 2p edges of the magnetic substances Fe, Co, and Ni for the benefit of magnetic circular dichroism spectroscopy employing circularly polarized synchrotron radiatio

Mn valence instability in La2/3Ca1/3MnO3 thin films

A Mn valence instability on La2/3Ca1/3MnO3 thin films, grown on LaAlO3 (001)substrates is observed by x-ray absorption spectroscopy at the Mn L-edge and O K-edge. As-grown samples, in situ annealed at 800 C in oxygen, exhibit a Curie temperature well below that of the bulk material. Upon air exposure a reduction of the saturation magnetization, MS, of the films is detected. Simultaneously a Mn2+ spectral signature develops, in addition to the expected Mn3+ and Mn4+ contributions, which increases with time. The similarity of the spectral results obtained by total electron yield and fluorescence yield spectroscopy indicates that the location of the Mn valence anomalies is not confined to a narrow surface region of the film, but can extend throughout the whole thickness of the sample. High temperature annealing at 1000 C in air, immediately after growth, improves the magnetic and transport properties of such films towards the bulk values and the Mn2+ signature in the spectra does not appear. The Mn valence is then stable even to prolonged air exposure. We propose a mechanism for the Mn2+ ions formation and discuss the importance of these observations with respect to previous findings and production of thin films devices.Comment: Double space, 21 pages, 6 figure

Development of Advanced Magnet Structures for Cryogenic In Vacuum Permanent Magnet Undulators

Short period undulators and in particular in vacuum cryogenic permanent magnet undulators are the upcoming technique for FEL radiators, because they permit a significant reduction of linac and undulator length. For achieving high photon energies with low electron energies short period lengths, e.g. below lOmm permanent magnet structures are superior, due to their high surface current density of 16 kA cm as compared to electromagnetic or even superconducting devices. The geom.etrical to1erances scale with the period length. This requires new fabrication techniques and structure designs, particularly for sub cm period lengths. Salutions for these demands will be presented and results from a first prototype using various new technologies such as compound poles will be discussed and compared with common approache

Hall Probe Bench for Cryogenic In Vacuum Undulator

The Helmholtz Zentrum Berlin HZB builds a 2m long in vacuum Hall probe measuring bench for the characterization of several in vacuum cryogenic undulators currently under development. Aceurate local magnetic measurements need a positioning control of about 5 Jlll. Fabrication tolerances and potentially strong temperature gradients require an active correction of the Hall probe movement along a straight line. The HZBbench employs a system of Iaser interferometers and positionsensitive detectors, which are used in a feed back loop for the Hall probe position and orientatio

Interfacial effects in La2/3Sr1/3MnO3 thin films with different complex oxide capping layers

Interfacialeffects in sputtered La2/3Sr1/3MnO3thin films with different capping layers (MgO, LaAlO3, SrTiO3, NdGaO3, and Au) have been locally investigated by means of x-ray absorption spectroscopy and x-ray magnetic circular dichroism at the Mn L3,2-edge. Data were acquired by using the total electron yield detection mode thus guaranteeing maximum sensitivity to the interface. The data show that LaAlO3 capping almost does not modify the bulklike Mn valence at the interface. In case of SrTiO3 and Au, the presence of divalent Mn is detected, whereas MgO and NdGaO3 capping lead to an increase of the Mn valence oxidation state. The modification of the nominal Mn valence state leads to depressed surfacemagnetization.We acknowledge financial support from the Spanish MEC (MAT2009-08024 and MAT2008-04931/NAN), CONSOLIDER (CSD2007-00041) and FEDER program. The research leading to these results has received funding from the European Community’s Seventh Framework Program (FP7/2007-2013) under Grant No. 226716. Z.K. thanks the Spanish MEC for the financial support through the RyC program.Peer reviewe

The risk and consequences of multiple breadbasket failures: an integrated copula and multilayer agent-based modeling approach

Climate shocks to food systems have been thoroughly researched in terms of food security and supply chain management. However, sparse research exists on the dependent nature of climate shocks on food-producing breadbasket regions and their subsequent cascading impacts. In this paper, we propose that a copula approach, combined with a multilayer network and an agent-based model, can give important insights on how tail-dependent shocks can impact food systems. We show how such shocks can potentially cascade within a region through the behavioral interactions of various layers. Based on our suggested framework, we set up a model for India and show that risks due to drought events multiply if tail dependencies during extremes drought is explicitly taken into account. We further demonstrate that the risk is exacerbated if displacement also takes place. In order to quantify the spatial–temporal evolution of climate risks, we introduce a new measure of multilayer vulnerability that we term Vulnerability Rank or VRank. We find that with higher food production losses, the number of agents that are affected increases nonlinearly due to cascading effects in different network layers. These effects spread to the unaffected regions via large-scale displacement causing sudden changes in production, employment and consumption decisions. Thus, demand shifts also force supply-side adjustments of food networks in the months following the climate shock. We suggest that our framework can provide a more accurate picture of food security-related systemic risks caused by multiple breadbasket failures which, in turn, can better inform risk management and humanitarian aid strategies

Impact of the Histidine‐Containing Phosphocarrier Protein HPr on Carbon Metabolism and Virulence in Staphylococcus aureus

Carbon catabolite repression (CCR) is a common mechanism pathogenic bacteria use to link central metabolism with virulence factor synthesis. In gram‐positive bacteria, catabolite control protein A (CcpA) and the histidine‐containing phosphocarrier protein HPr (encoded by ptsH) are the predominant mediators of CCR. In addition to modulating CcpA activity, HPr is essential for glucose import via the phosphotransferase system. While the regulatory functions of CcpA in Staphylococcus aureus are largely known, little is known about the function of HPr in CCR and infectivity. To address this knowledge gap, ptsH mutants were created in S. aureus that either lack the open reading frame or harbor a ptsH variant carrying a thymidine to guanosine mutation at position 136, and the effects of these mutations on growth and metabolism were assessed. Inactivation of ptsH altered bacterial physiology and decreased the ability of S. aureus to form a biofilm and cause infections in mice. These data demonstrate that HPr affects central metabolism and virulence in S. aureus independent of its influence on CcpA regulation